Citation: GUO Hui, ZHANG KeYao, LI Na, ZHANG Shuan. Synthesis and Crystal Structure of N,N',N''-Tris(2-hydroxypropyl)-1,4,7-triazacyclodecane Co(Ⅱ) Complex[J]. Chinese Journal of Applied Chemistry, ;2016, 33(2): 200-205. doi: 10.11944/j.issn.1000-0518.2016.02.150236 shu

Synthesis and Crystal Structure of N,N',N''-Tris(2-hydroxypropyl)-1,4,7-triazacyclodecane Co(Ⅱ) Complex

1.
College of Pharmacy, Shaanxi University of Chinese Medicine, Xianyang, Shaanxi 712046, China

Corresponding author: GUO Hui,
Received Date: 8 July 2015
Available Online: 17 November 2015
Fund Project:

One novel macrocyclic triamine derived ligand N,N',N''-tris(2-hydroxypropyl)-1,4,7-triazacyclodecane and its transition metal complexes, [CoL] [ClO₄]₂ were synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structure of [CoL][ClO₄]₂ was determined. The complex belongs to crystallographic system of monoclinic and space group:P2/N(1). The complex is hexacoordinate and the center Co atom exists in a distortion three prism coordination environment. The six coordinating atoms come from three nitrogen atoms and three oxygen atoms of the ligand. The average Co-N bond length and Co-O bond length are 0.2114(6) nm and 0.2097(6) nm, respectively. A regular supramolecular network structure are formed through the hydrogen bonding O…H-O between three oxygen atoms of the perchlorate with three oxygen atoms of the neighboring ligands.
- m-acrocyclic triamine derivative,
- synthesis,
- crystal structure,
- Co(Ⅱ) complex
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