Citation: HU Sanming, WEI Wei, YANG Tianbo, ZHENG Changmei, ZHENG Chunbai, DENG Pengyang. Properties of a New Type Heat-Resistant System of Epoxy Resin Cured at Room Temperature[J]. Chinese Journal of Applied Chemistry, ;2016, 33(2): 175-180. doi: 10.11944/j.issn.1000-0518.2016.02.150223 shu

Properties of a New Type Heat-Resistant System of Epoxy Resin Cured at Room Temperature

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a Wuhan Wuchuan Electromechanical Equipment Company, Wuhan 430000, China;
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b Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
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c Jilin University, Changchun 130025, China

Corresponding author: ZHENG Changmei, ZHENG Chunbai,
Received Date: 1 July 2015
Available Online: 17 November 2015
Fund Project:

Bisphenol-A epoxy resin E-51 was cured by [C₆mim]FeCl₄ and mixed amines at room temperature(20℃). Compared to other E-51 systems which were cured by aliphatic amine, E-51 systems cured by [C₆mim]FeCl₄/mixed amine have better mechanical properties, thermal properties, and aging properties. The effect of the amount of [C₆mim]FeCl₄ on the properties of the cured epoxy resin systems was also investigated. Tensile strength of the [C₆mim]FeCl₄/mixed amine cured E-51 system reaches 90 MPa, and the system maintains its excellent mechanical properties at high temperature(120℃). The TGA result shows that the decomposition temperature is 310℃ when the mass loss of epoxy system reaches 5%. Even after 7 days aging at 200℃, the tensile strength of the [C₆mim]FeCl₄/mixed amine cured epoxy resin system is 28 MPa. Therefore, the [C₆mim]FeCl₄/mixed amine cured epoxy resin system is a new type of epoxy resin cured system which can be applied under high temperature.
- hexyl-methylimidazole iron tetrachloride,
- bisphenol-a epoxy resin,
- room temperature curing agent,
- properties
1. [1]
  [1] SUN Manling,WU Liangyi. Application of The Principles and Techniques of Epoxy Resin[M]. Beijing:China Machine Press,2002:4-8(in Chinese).孙曼灵,吴良义. 环氧树脂应用原理及技术[M]. 北京:机械工业出版社,2002:4-8.
2. [2]
  [2] CHEN Ping,LIU Shengping,WANG Dezhong. Epoxy Resin and Its Application[M]. BeiJing:Chemical Industry Press,2011:1-5(in Chinese).陈平,刘胜平,王德中.环氧树脂及其应用[M]. 北京:化学工业出版社,2011:1-5.
3. [3]
  [3] SONG Junjun,ZHANG Jun. The Room Temperature Fast Curing Epoxy Adhesive Development Present Situation[J]. Heilongjiang Sci,2013,4(1):40-42(in Chinese).宋军军,张君. 室温快速固化环氧胶黏剂的发展现状[J]. 黑龙江科学,2013,4(1):40-42.
4. [4]
  [4] WU Yanfei,HUANG Ying. Research Progress of Room Temperature Cured Heat-Resistant Adhesive[J]. Mater Develop Appl,2010,6:88-93(in Chinese).吴燕飞,黄英. 室温固化耐温胶黏剂研究进展[J]. 材料开发与应用,2010,6:88-93.
5. [5]
  [5] DUAN Huajun,ZHANG Lianmeng,WANG Jun,et al. Study on the Properties of the Low Viscosity, Low Heat Liberation and High Toughening Curing Agent for Epoxy Resin[J]. Insulat Mater,2007,40(6):1-4(in Chinese).段华军,张联盟,王均,等. 低放热、低粘度、高韧性环氧树脂室温固化剂的性能研究[J]. 绝缘材料,2007,40(6):1-4.
6. [6]
  [6] GONG Yunjin. Preparing TG301 Epoxy Resin Room Temperature Curing Agent with Modifed Hexanediamine[J]. China Adhes,1999,4(1):35-38(in Chinese).龚云金. 改性己二胺制备TG301环氧树脂室温固化剂[J]. 中国胶黏剂,1999,4(1):35-38.
7. [7]
  [7] WANG Zhongyi,ZHANG Lianhong. Synthesis of Epoxy Resin Fast Curing Agent at Room Temperature[J]. Synth Resin Plast,2013,30(3):25-30(in Chinese).王钟熠,张连红. 环氧树脂室温快速固化剂的合成[J]. 合成树脂及塑料,2013,30(3):25-30.
8. [8]
  [8] Dodiuk H,Kenig S,Liran I. Room Temperature Curing Epoxy Adhesives for Elevated Temperature Service[J]. J Adhes,1987,22(3):227-251.
9. [9]
  [9] ZHANG Xiaobo,LIU Haiping. Study on Synthesis and Performance of Flexible Curing Agent for Room Temperature Curing Epoxy Resin Adhesive[J]. China Adhes,2008,17(5):1-4(in Chinese).张小博,刘海萍. 环氧树脂室温固化用柔性固化剂的制备与性能研究[J]. 中国胶黏剂,2008,17(5):1-4.
10. [10]
  [10] XIA Lanjun,LI Fuzhi,XIONG Hejian,et al. Performance of Silicone Modified Epoxy Resin Curable at Room Temperature[J]. Adhesion,2013,4(54):1-5(in Chinese).夏兰君,李福志,熊和建,等. 有机硅改性环氧树脂及其室温固化的性能研究[J]. 粘接,2013,4(54):1-5.
11. [11]
  [11] LI Xiaohua,YANG Fuming,ZHOU Qing,et al. Synthesis and Properties of 1-Methyl-3-Alkylimnida-zolium Tetrahalogenoferrate Magnetic Ionic Liquids[J]. Process Eng J,2010,10(4):789-794(in Chinese).李小华,杨富明,周清,等. 磁性离子液体1-甲基-3-烷基咪唑四氯化铁盐的合成及其物性表征[J]. 过程工程学报,2010,10(4):789-794.
12. [12]
  [12] MA Yuqin,WEI wei,ZHENG Changmei,et al. Reaction Characteristics of Epoxy Resins E-51 Cured by 1-Hexyl-3-methyl Imidazole Iron Tetrachloride Salt[J]. Chinese J Appl Chem,2015,32(6):636-640(in Chinese).马玉芹,魏巍,郑昌梅,等. 1-己基-3-甲基咪唑四氯化铁盐固化环氧树脂E-51的反应特性[J]. 应用化学,2015,32(6):636-640.
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