Citation: SHI Yufang, SUN Jinyu, LIU Chengqi, ZHAO Minggen. Synthesis and Third-order Nonlinear Optical Property of 1-(Pyrene-1-yl)-3-(4-methoxyphenyl)acrylic Ketone[J]. Chinese Journal of Applied Chemistry, ;2016, 33(2): 149-154. doi: 10.11944/j.issn.1000-0518.2016.02.150216 shu

Synthesis and Third-order Nonlinear Optical Property of 1-(Pyrene-1-yl)-3-(4-methoxyphenyl)acrylic Ketone

1.
Shanxi Province Key Laboratory for Materials and ComputationalChemistry, Department of Chemistry, Xinzhou Teachers University, Xinzhou, Shanxi 034000, China

Corresponding author: ZHAO Minggen,
Received Date: 29 June 2015
Available Online: 13 November 2015
Fund Project:

A new nonlinear optical(NLO) organic material 1-(pyrene-1-yl)-3-(4-methoxyphenyl)acrylic ketone(PMPAK) was synthesized and characterized with ¹H NMR, IR, HR-MS and elemental analysis. The three order NLO properties of PMPAK was tested by 4f phase-coherent imaging system which utilized Nd:YAG-Laser System as the light source. The laser pulse was set at the wavelength of 450 nm with the pulse duration of 4 ns(FWHM), thus the relevant parameters were determined as: the nonlinear refractive index n₂=-1.84×10^-16 m²/W, the nonlinear absorption coefficient β=2.53×10^-9 m/W and the third-order nonlinear polarizability χ⁽³⁾=1.137×10^-10 esu.
- pyrene derivatives,
- Chalcone,
- (pyrene-yl)-(methoxyphenyl)acrylic ketone,
- synthesis,
- nonlinear optical properties
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