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Citation: FU Yahong, SHI Hongli, ZHOU Guangpeng, HUI Yonghai, XIE Zhengfeng. One-step Oxidation of Benzene to Phenol Catalyzed by Sodium Metavanadate-Multinitrogen Heterocyclic Schiff Base Complex Immobilized on Mesoporous Molecular Sieve MCM-41[J]. Chinese Journal of Applied Chemistry, ;2015, 32(11): 1259-1267. doi: 10.11944/j.issn.1000-0518.2015.11.150144 shu

One-step Oxidation of Benzene to Phenol Catalyzed by Sodium Metavanadate-Multinitrogen Heterocyclic Schiff Base Complex Immobilized on Mesoporous Molecular Sieve MCM-41

1.
a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education, Xinjiang University, Urumqi 830046, China;
2.
b College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China

Corresponding author: HUI Yonghai, XIE Zhengfeng,
Received Date: 22 April 2015
Available Online: 1 July 2015
Fund Project: 新疆大学博士启动基金(BS110111)资助 (BS110111)石油天然气精细化工重点实验室开放课题(XJDX0908-2012-3)资助 (XJDX0908-2012-3)国家级大学生创新创业训练计划项目(201310755007)资助 (201310755007)

2-Phenyl-1,2,3-triazoledehyde and quinoxalin-2-carboxaldehyde immobilized on mesoporous MCM-41 by imine bond respectively. Six multinitrogen heterocyclic Schiff bases(L1~L6) modified MCM-41 were synthesized. These catalysts were characterized by Fourier transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD),thermogravimetric analysis(TG) and scanning electron microscopy(SEM). Na VO₃ and Schiff Base complex immobilized on MCM-41 was used for catalytic oxidation of benzene to phenol. The yield of phenol was determined by gas chromatography. Reaction conditions,such as ligand,metal salt,temperature,solvent,the catalyst amount,reaction time and oxidants were systematically investigated. Under optimized conditions,the yield of phenol is up to 23.9%(more than 90% selectivity). Scaled-up(5 times) reaction test using the current catalyst system gives a good yield(23%) and selectivity(up to 90%),while catalyst shows no significant decrease of catalytic activity after 3 times recycles.
- Schiff base,
- immobilization,
- mesoporous molecular sieve MCM-41,
- benzene,
- phenol,
- oxidation,
- sodium metavanadate
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