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Citation: ZHOU Yun, LIU Hui, HE Yan, LI Aitao, TAO Liming. Copper Acetate Catalyzed Oxidative Coupling of Disulfides with Tetrahydrofuran[J]. Chinese Journal of Applied Chemistry, ;2015, 32(11): 1253-1258. doi: 10.11944/j.issn.1000-0518.2015.11.150124 shu

Copper Acetate Catalyzed Oxidative Coupling of Disulfides with Tetrahydrofuran

1.
Hu'nan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds Research and Application, Department of Chemistry and Life Science, Xiangnan University, Chenzhou, Hu'nan 423000, China

Corresponding author: TAO Liming,
Received Date: 7 April 2015
Available Online: 13 July 2015
Fund Project: 湖南省重点建设学科(湘教发[2011]76) (湘教发[2011]76)湖南省科技厅计划项目(2012TP4021-3) (2012TP4021-3)郴州市科技计划项目(CZ2014038) (CZ2014038)

A new Cu(OAc)₂-catalyzed oxidative coupling of disulfides with tetrahydrofuran for the synthesis of etherified sulfides has been developed. In the presence of Cu(OAc)₂(10% molar fraction) and H₂O₂(35%,2 equiv),a variety of disulfides(0.5 mmol) were treated with tetrahydrofuran(2 mL) at 120℃ to afford the corresponding etherified sulfides in moderate to high yields. This method employs 35% aqueous H₂O₂ as the green oxidant,and provides an efficient way for the formation of the C-S bonds.
- copper acetate,
- disulfides,
- tetrahydrofuran,
- oxidative coupling reaction,
- H₂O₂
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