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Citation: SUN Jinyu, SHI Yufang, WANG Guilin, ZHAO Minggen. Synthesis and Three-order Nonlinear Optical Property of Pyrenyl Chalcone[J]. Chinese Journal of Applied Chemistry, ;2015, 32(10): 1134-1138. doi: 10.11944/j.issn.1000-0518.2015.10.150061 shu

Synthesis and Three-order Nonlinear Optical Property of Pyrenyl Chalcone

1.
Department of Chemistry, Xinhhou Teachers University, Xinzhou, Shanxi 034000, China

Corresponding author: ZHAO Minggen,
Received Date: 9 February 2015
Available Online: 7 May 2015
Fund Project: 忻州师范学院重点学科专项课题(XK201205) (XK201205)

A new nonlinear optical (NLO) organic material,1-(pyrene-1-yl)-3-(4-dimethyl aminophenyl) acrylic ketone (PMAK),was synthesized and characterized with ¹H NMR,IR,MS and elemental analysis.Meanwhile,the three-order nonlinear optical property of PMAK was tested by the Nd:YAG powder laser technology and the relevant parameters were determined.Nanosecond results are as follows:the refractive index n₂=-3.5×10^-17m²/W,the absorption coefficient β=7.0×10^-10 m/W,the polarization rate χ⁽³⁾=2.54×10^-11 esu,the molecular hyperpolarizability γ=3.44×10^-30 esu.Picosecond results are as follows:n₂=-2.8×10^-18m₂/W,β=8.3×10^-11 m/W,χ⁽³⁾=2.49×10^-12 esu,γ=3.33×10^-31 esu.
- pyrene derivative,
- (pyrene-yl)-(dimethylaminophenyl) acrylic ketone,
- chalcone,
- nonlinear optical property,
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