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Citation: LI Ke, ZHANG Jiaoqiang, KANG Shuanyan, SHI Huimin, ZHOU Hongyu, DOU Rongrong. 2-Acryloyloxyethyl Ferrocene Carboxylate:Synthesis and Optimization[J]. Chinese Journal of Applied Chemistry, ;2015, 32(7): 765-770. doi: 10.11944/j.issn.1000-0518.2015.07.140400 shu

2-Acryloyloxyethyl Ferrocene Carboxylate:Synthesis and Optimization

1.
Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi'an 710129, China

Corresponding author: ZHANG Jiaoqiang,
Received Date: 18 November 2014
Available Online: 19 January 2015
Fund Project: 陕西省自然基金资助项目(2014KA110035) (2014KA110035)

The main problems in the use and storage of ferrocene derivatives as burning rate catalysts are the migration and volatility of catalysts.A solution for the problems is to introduce polar groups on ferrocene.This paper reported the synthesis of 2-acryloyloxyethyl ferrocenecarboxylate (AEFC) from ferrocenecarboxylic acid (FCA) and 2-hydroxyethyl acrylate (HEA) with N,N'-dicyclohexylcarbodiimide (DCC) as the dehydration agent in the presence of 4-dimethylaminopyridine (DMAP).Under optimized reaction conditions,the synthesis was conducted with FCA,HEA,DMAP,and DCC in a molar ratio of 20:28:20:24 at 0℃ and addition of DCC solution in 60~75 min to give AEFC in 75.1% yield and 98% purity.
- esterification reaction,
- ferrocene derivatives,
- N,N'-dicyclohexylcarbodiimide/dimethylaminopyridine
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