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Citation: TANG Zilong, XIA Zanwen, WANG Hongqing, WANG Lian, JIAO Yinchun, CHEN Jinwen. Synthesis and Fungicidal Activities of 2,3-Diaryl-1,3-benzoxazines[J]. Chinese Journal of Applied Chemistry, ;2015, 32(2): 143-150. doi: 10.11944/j.issn.1000-0518.2015.02.140191 shu

Synthesis and Fungicidal Activities of 2,3-Diaryl-1,3-benzoxazines

TANG Zilong ^a,b,, ,
XIA Zanwen ^b ,
WANG Hongqing ^c ,
WANG Lian ^b ,
JIAO Yinchun ^a,b ,
CHEN Jinwen ^b

1.
a Key Laboratory of Theoretical Organic Chemistry and Function Molecules, Ministry of Education, Xiangtan, Hu'nan 411201, China;
2.
b School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hu'nan 411201, China;
3.
c School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hu'nan 421001, China

Corresponding author: TANG Zilong,
Received Date: 28 May 2014
Available Online: 21 July 2014
Fund Project: 国家自然科学基金(No.21372070) (No.21372070)国家科技支撑计划项目子课题(2011BAE06B01) (2011BAE06B01)湖南省高校创新平台开放基金(13K089) (13K089)理论有机化学与功能分子教育部重点实验室开放基金(LKF1302)资助项目 (LKF1302)

A series of 2,3-disubstituted-1,3-benzoxazines was synthesized by trimethyl chlorosilane-catalyzed aza-acetalization of 2-arylaminomethyl phenols with aromatic aldehydes. The structures of the prepared compounds were characterized by FT-IR,¹H NMR,¹³C NMR and elemental analysis. Fungicidal activities of these compounds were also evaluated. Most of them exhibit good activities. Compound 6e shows 79% and 77.9% activity against S. Scleratotiorum and B. Cinérea,respectively. Compounds 6a and 6d exhibit 74.8% activity against S. Scleratotiorum.
- diaryl-benzoxazine,
- fungicidal activity,
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