Citation: ZHAO Xiao-Jie, HUANG Long, SONG Xu-Yan, XING Jun. Separation Performance of Ionic Liquid/Cellulose Mixture as Gas Chromatographic Stationary Phase[J]. Chinese Journal of Analytical Chemistry, ;2018, 46(8): 1289-1296. doi: 10.11895/j.issn.0253-3820.181052 shu

Separation Performance of Ionic Liquid/Cellulose Mixture as Gas Chromatographic Stationary Phase

1.
Key Laboratory of Analytical Chemistry for Biology and Medicine(Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China;
2.
Technology Center of Hubei Branch of China Tobacco Industry Corporation, Wuhan 430051, China

Received Date: 24 January 2018
Revised Date: 24 April 2018

A cellulose derivative (C-C4) synthesized by "click" reaction and methylation reaction in sequence was mixed with ionic liquid bonded polysilxoane (PIL-C12-NTf2) to prepare a capillary column (C-C4@PIL-C12) for gas chromatography. The prepared column has a column efficiency of 2778 plates/m (for naphthalene k=6.20, 100℃) and exhibits satisfying durability. Abraham's solvation parameter model was used to reveal the interaction characteristics and some representative compounds were employed to investigate the separation selectivity. It was resulted that compared with the two commercially available polar stationary phases of Elite-waxetr and TG-17ms, C-C4@PIL-C12 possessed moderate strength of the hydrogen bond basicity, dipolarity/polarizability and hydrogen bond acidity, and displayed better separation selectivity for the tested analytes, such as aromatic isomers, substituted alkanes, aliphatic acid esters, n-alkanes and phthalic acid esters.
- Cellulose derivative,
- Ionic liquids,
- Stationary phase,
- Gas chromatography
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1.
沈阳化工大学材料科学与工程学院沈阳 110142