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Citation: ZHANG Zhao-Hui, GU Zhi-Xin, LIU Jing-Jing, CHEN Ying-Zhuang, CHEN Bo, MA Ming. Simple and Rapid Differentiation of Mutong of Aristolochiaceae by Direct Spray Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(8): 1143-1148. doi: 10.11895/j.issn.0253-3820.170049 shu

Simple and Rapid Differentiation of Mutong of Aristolochiaceae by Direct Spray Mass Spectrometry

1.
Key Laboratory of Phytochemical R&D of Hunan Province and Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research, Ministry of Education of China, Hunan Normal University, Changsha 410081, China;2 Hunan Biological and Electromechanical Polytechnic, Changsha 410127, China

Received Date: 19 January 2017
Revised Date: 19 May 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos.21575040,21275052)

Direct spray mass spectrometry was used to simply and rapidly differentiate Mutong of Aristolochiaceae from other two kinds of Mutong medicinal materials (Lardizabalaceae and Ranunculacea) by analyzing the chemical profile of Mutong of Aristolochiaceae. A novel method for determination of magnoflorine content in Mutong of Aristolochiaceae was established. The results showed that Mutong of Aristolochiaceae could be identified according to the symbolic component, magnoflorine. Under positive ion mode, semi-quantitative result based on the signal strength ratio of magnoflorine and nuciferin was obtained by choosing nuciferin as an internal standard. The method showed good linear coefficient in the concentration range of 0.50-20.00 mg/L of magnoflorine. The limit of detection was 0.1 mg/L. The method was simple and fast, and could be used for direct and rapid in-situ analysis and identification of Mutong of Aristolochiaceae from other closely related Mutong herbal species without sample pre-treatment. The results were important for the quality control of Mutong herbal medicine.
- Direct spray mass spectrometry,
- Mutong of Aristolochiaceae,
- Magnoflorine,
- Aristolochic acid A
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