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Citation: XIN Li, YANG Chao-He, FENG Xiang, LIU Yi-Bin, CHEN Xiao-Bo, SHAN Hong-Hong. A Method of Qualitative and Quantitative Analysis on Fluid Catalytic Cracking Full Range Gasoline by Comprehensive Two-Dimensional Gas Chromatography Coupled with Time-of-Flight Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(4): 489-494. doi: 10.11895/j.issn.0253-3820.160714 shu

A Method of Qualitative and Quantitative Analysis on Fluid Catalytic Cracking Full Range Gasoline by Comprehensive Two-Dimensional Gas Chromatography Coupled with Time-of-Flight Mass Spectrometry

State Key Laboratory of Heavy Oil Processing in China University of Petroleum, Qingdao 266580, China

Received Date: 23 September 2016
Revised Date: 8 February 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. U1462205, 21476263).

A method of qualitative and quantitative analysis on fluid catalytic cracking (FCC) full range gasoline by comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOF MS) was established. The results showed that paraffins, olefins, naphthenes and aromatics in FCC gasoline had regional and zonal distribution in two-dimensional contour plots. The distinctions of boiling points and polarity between different compounds were used to achieve the accurate separation and determination in GC×GC-TOF MS analysis, and consequently the co-current flow which was often present in the conventional GC analysis was greatly suppressed. The difference of ionizing efficiency between different compounds was modified by response factors, and moreover, a good quantitative dependency was found between the analysis results of GC and GC×GC-TOF MS on FCC gasoline. Due to the high separation resolution, GC×GC-TOF MS gave more accurate results about the group compositions of FCC gasoline. GC×GC-TOF MS provided an effective way with high precision for the characterization of FCC gasoline.
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