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Citation: WANG Min-Dai, GUO Qing-Hai, GUO Wei, PENG Yue-E, ZHAO Qian. Synthesis, Identification and Quantitative Analysis of Aqueous Thioarsenates[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(11): 1715-1720. doi: 10.11895/j.issn.0253-3820.160167 shu

Synthesis, Identification and Quantitative Analysis of Aqueous Thioarsenates

State Key Laboratory of Biogeology and Environmental Geology & School of Environmental Studies, China University of Geosciences, Wuhan 430074, China

Received Date: 18 March 2016
Revised Date: 30 August 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 41572335, 21305130) and the Research Program of State Key Laboratory of Biogeology and Environmental Geology of China (No. GBL11505)

Four kinds of thioarsenates, H_nAsSO₃^n-3, H_nAsS₂O₂^n-3, H_nAsS₃O^n-3 and H_nAsS₄^n-3, were synthesized and identified by electrospray ionization-high resolution mass spectrometry (ESI-HR-MS). With the synthetic thioarsenates as standards, a quantitative analytical method based on ion chromatograph-inductively coupled plasma mass spectrometry (IC-ICP-MS) was set up to simultaneously determine the concentrations of arsenite, arsenate, mono-thioarsenate, di-thioarsenate, tri-thioarsenate, and tetra-thioarsenate in water. The linear range of the method was from 3.3 μg/L to 833 μg/L with the correlation coefficients higher than 0.99, and the detection limits were between 0.4 μg/L and 25 μg/L. The synthetic standard materials of thioarsenates and the quantitative analysis method established in this study are of great significance for future investigations on the environmental transportation and transformation of various arsenic species derived from natural sulfidic waters.
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