Citation: LI Jia-Ming, CHU Ying-Bo, ZHAO Nan, ZHOU Ran, YI Rong-Xing, GUO Lian-Bo, LI Jin-Yan, LI Xiang-You, ZENG Xiao-Yan, LU Yong-Feng. Detection of Trace Elements in Active Luminescent Glass Using Laser-induced Breakdown Spectroscopy Combined with Laser-induced Fluorescence[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(7): 1042-1046. doi: 10.11895/j.issn.0253-3820.160134
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In the preparation of active luminescent glass, trace elements are generally co-doped to improve the properties. To overcome the poor sensitivity of laser-induced breakdown spectroscopy (LIBS) on detecting trace elements in glass, this work utilized laser-induced breakdown spectroscopy combined with laser-induced fluorescence to detect trace Yb, Al and P. A wavelength-tunable laser was used to excited Yb ions, Al atoms and P atoms. The transition process in laser-induced fluorescence was described. The results showed that the spectral intensities of Yb, Al and P were enhanced by 23, 50 and 8 times, respectively. LIBS sensitivity was greatly improved by combining laser-induced fluorescence.
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