Citation: JIANG Jing-Jie, LIU Ying-Rong, LIU Ze-Long, TIAN Song-Bai. Paraffins Species Distribution Analysis in Petroleum Middle Fractions by GC Field Ionization Time-of-Flight Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(3): 416-422. doi: 10.11895/j.issn.0253-3820.150772 shu

Paraffins Species Distribution Analysis in Petroleum Middle Fractions by GC Field Ionization Time-of-Flight Mass Spectrometry

1.
Sinopec Research Institute of Petroleum Processing, Beijing 100083, China

Corresponding author: LIU Ze-Long,
Received Date: 30 September 2015
Available Online: 4 January 2016
Fund Project: 本文系国家重点基础研究发展计划"973"资助项目(No.2012CB224801)资助 (No.2012CB224801)

A gas chromalography field ionization time-of-flight mass spectrometric (GC-FI TOF MS) technology was used to characterize the carbon number distribution of paraffins with different levels of isomerization in petroleum middle fractions. Firstly, with GC-FI TOF MS, the paraffins with different levels of isomerization were identified. Secondly, the relative response factors of normal paraffins and iso-paraffins were determined and their quantitative analysis methods were established. Finally, the accuracy and precision of the method were examined. The results indicated that paraffins with the same carbon number could be divided into poly-substituted iso-paraffins, mono-substituted iso-paraffins and normal paraffins by GC-FI TOF MS. The quantitation of paraffins with different levels of isomerization could be obtained. The accuracy and precision were acceptable. The sample pre-separation was not required which greatly shortened the analysis time. The analysis provides the information for the carbon number distribution of iso-paraffins with different levels of isomerization.
- Gas chromalography,
- Petroleum middle fractions,
- Iso-paraffins,
- Normal paraffins,
- Quantified analysis
1. [1]
  1 LIANG Wen-Jie, QUE Guo-He, LIU Chen-Guang, YANG Qiu-Shui. Petroleum Chemistry. Dongying: China University of Petroleum Press, 2009: 200梁文杰, 阙国和, 刘晨光, 杨秋水. 石油化学. 东营: 中国石油大学出版社, 2009: 200
2. [2]
  2 ASTM D 5134-13, Standard Test Method for Detailed Hydrocarbon Analysis of Petroleum Naphthas Through n-Nonane by Capillary Gas Chromatography. ASTM Committee D02.04 on Petroleum Products and Lubricants
3. [3]
  3 Cookson D J, Rolls C L, Smith B E. Fuel, 1989, 68(6): 788-792
4. [4]
  4 JIANG Tao, ZHOUYun-Qi. Chinese J. Anal. Chem., 1998, 26(12): 1442-1446江涛, 周云琪. 分析化学, 1998, 26(12): 1442-1446
5. [5]
  5 Briker Y, Ring Z, Lacchelli A, Mclean N, Rahimi P M, Fairbridge C, Malhotra R, Coggiola M A, Young S E. Energ Fuel, 2001, 15(1): 23-37
6. [6]
  6 Briker Y, Ring Z, Lacchelli A, Mclean N, Rahimi P M, Fairbridge C, Malhotra R, Coggiola M A, Young S E. Energ Fuel, 2001, 15(4): 996-1002
7. [7]
  7 QI Bang-Feng, ZHANG Hui-Cheng, GENG Jing-Yuan, CHEN Li-Ren, LI Yong-Min. Journal of Petrochemical Universities, 2003, 16(2): 1-3齐邦峰, 张会成, 耿静远, 陈立仁, 李永民. 石油化工高等学校学报, 2003, 16(2): 1-3
8. [8]
  8 Mair B J, Hwang P T R, Ruberto R G. Anal. Chem., 1967, 39(7): 838-840
9. [9]
  9 ZHUXin-Yi, LIU Ze-Long, XU Yan-Qin, LIU Yin-Rong, TIAN Song-Bai. Acta Petrolei Sinica (Petroleum Processing Section), 2010, 26(2): 277-282祝馨怡, 刘泽龙, 徐延勤, 刘颖荣, 田松柏. 石油学报(石油加工), 2010, 26(2): 277-282
10. [10]
  10 WANGNai-Xin, LIU Ze-Long, ZHU Xin-Yi, TIAN Song-Bai. Petroleum Processing and Petrochemicals, 2014, 45(5): 94-100王乃鑫, 刘泽龙, 祝馨怡, 田松柏. 石油炼制与化工, 2014, 45(5): 94-100
11. [11]
  11 LIU Ying-Rong, JIANG Jing-Jie, LIU Ze-Long, TIAN Song-Bai. Chinese Journal of Chromatography, 2015, 34(2): 215-221刘颖荣, 蒋婧婕, 刘泽龙, 田松柏. 色谱, 2015, 34(2): 215-221
12. [12]
  12 SH/T 0606-2005, Standard Test Method for Hydrocarbon Types in Middle Distillates by Mass Spectrometry. Standards of the people's Republic of China Petrochemical Industry 中间馏分烃类组成测定法(质谱法). 中华人民共和国石油化工行业标准. SH/T 0606-2005
13. [13]
  13 LIU Wen-Qin, YUAN Cun-Guang. Instrumental Analysis. Dongying: China University of Petroleum Press, 2004: 357刘文钦, 袁存光. 仪器分析. 东营: 石油大学出版社, 2004: 357
1. [1]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
2. [2]
  Ling Bai , Limin Lu , Xiaoqiang Wang , Dongping Wu , Yansha Gao . Exploration and Practice of Teaching Reforms in “Quantitative Analytical Chemistry” under the Perspective of New Agricultural Science. University Chemistry, 2024, 39(3): 158-166. doi: 10.3866/PKU.DXHX202308101
3. [3]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
4. [4]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
5. [5]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
6. [6]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
7. [7]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
8. [8]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
9. [9]
  Min Gu , Huiwen Xiong , Liling Liu , Jilie Kong , Xueen Fang . Rapid Quantitative Detection of Procalcitonin by Microfluidics: An Instrumental Analytical Chemistry Experiment. University Chemistry, 2024, 39(4): 87-93. doi: 10.3866/PKU.DXHX202310120
10. [10]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
11. [11]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
12. [12]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
13. [13]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
14. [14]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
15. [15]
  Xiaolei Jiang , Fangdong Hu . Exploring the Mirror World in Organic Chemistry: the Teaching Design of “Enantiomers” from the Perspective of Curriculum and Ideological Education. University Chemistry, 2024, 39(10): 174-181. doi: 10.3866/PKU.DXHX202402052
16. [16]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
17. [17]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
18. [18]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
19. [19]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
20. [20]
  Zhilian Liu , Wengui Wang , Hongxiao Yang , Yu Cui , Shoufeng Wang . Ideological and Political Education Design for the Synthesis of Irinotecan Drug Intermediate 7-Ethyl Camptothecin. University Chemistry, 2024, 39(2): 89-93. doi: 10.3866/PKU.DXHX202306012

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(294)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142