Citation: CHEN Zhan-Ying, LIU Shu-Jiang, WANG Jian-Long, CHANG Yin-Zhong. Determination of Atmospheric Krypton and Xenon by Gas Chromatography-Mass Spectrometry in Direct Injection Mode[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(3): 468-473. doi: 10.11895/j.issn.0253-3820.150750 shu

Determination of Atmospheric Krypton and Xenon by Gas Chromatography-Mass Spectrometry in Direct Injection Mode

1.
¹ Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;
2.
² CTBT Beijing National Data Centre & Beijing Radionuclide Laboratory, Beijing 100085, China;
3.
³ Beijing Key Laboratory of Radioactive Waste Treatment, Tsinghua University, Beijing 100084, China

Corresponding author: WANG Jian-Long,
Received Date: 22 September 2015
Available Online: 4 January 2016
Fund Project: 本文系教育部博士点基金(No.20130002130012) (No.20130002130012)长江学者和创新团队发展计划资助(IRT-13026)项目 (IRT-13026)

Volume concentration determination for atmospheric krypton and xenon is very important for krypton-85 and radioactive xenon isotopes monitoring. An injection setup integrated adjustable quantity sample injection and quantitative dilution function was designed. The effects of EI source parameters on the sensitivity of MS detector were studied. The optimized values were as following: ionization energy of 70 eV, emission current of 40 mA, cathode voltage of 27 mV, focus voltage of 85 mV and lens compensation of 20 V, respectively. A GC-MS method for the determination of krypton and xenon in atmosphere without of sample pretreatment was developed. The minimal detected concentrations for krypton and xenon were 3.3×10^-8(V/V) and 2.6×10^-9(V/V). Moreover, the krypton and xenon concentrations in the ground level air around our laboratory were measured with the results of 1.1×10^-6 (V/V) and 9.3×10^-8 (V/V). The related combined standard uncertainties for krypton and xenon results were 2.38% and 3.15%, respectively.
- Gas ghromatography-mass spectrometry,
- Atmosphere,
- Krypton,
- Xenon
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沈阳化工大学材料科学与工程学院沈阳 110142