Citation: DAI Meng-Ning, BAO Zhi-An, CHEN Kai-Yun, YUAN Hong-Lin. In Situ Analysis of Mg Isotopic Compositions of Basalt Glasses by Femtosecond Laser Ablation Multi-collector Inductively Coupled Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(2): 173-178. doi: 10.11895/j.issn.0253-3820.150602 shu

In Situ Analysis of Mg Isotopic Compositions of Basalt Glasses by Femtosecond Laser Ablation Multi-collector Inductively Coupled Mass Spectrometry

1.
State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Collaborative Innovation Center of Continental Tectonics, Xi'an 710069, China

Corresponding author: YUAN Hong-Lin,
Received Date: 29 July 2015
Available Online: 30 October 2015
Fund Project: 本文系国家自然科学基金(Nos. 41427804,41421002,41373004) (Nos. 41427804,41421002,41373004)长江学者和创新团队发展计划(IRT1281)资助项目 (IRT1281)

A method was developed for the in situ analysis of magnesium isotopes by femtosecond laser ablation multi-collector inductively coupled mass spectrometry (fsLA-MC-ICP-MS). Concentration matching experiment revealed that the Mg isotopic composition could be measured accurately when Mg concentration difference between sample and standard was in the range of 0.4-3.0. The Mg isotopic composition was affected by the femtosecond laser conditions, including laser spot size and scanning speed, due to mass discrimination changing which was caused by different mass loading into mass spectrometer. The amount of ablated aerosol was correlated with laser frequency, laser ablation spot size, scanning speed. However, the laser energy density showed negligible effect on the accuracy of Mg isotope measurement due to the high energy output of femtosecond which was higher than the ablation threshold. To obtain reliable Mg isotopic compositions, the laser ablation spot size, laser frequency and scanning speed should be consistent during one analytical section and the difference of Mg concentration between standard and samples should be in 3 times. The analytical results of two reference materials agreed well with the published values within 2 s analytical uncertainties. The developed method is simple, reliable and accurate, and can be used for the Mg isotope analysis of volcanic glasses and silicate minerals.
- Femtosecond laser ablation,
- Multi-collector inductively coupled mass spectrometry,
- Magnesium isotope,
- Basalt glasses
1. [1]
  1 Teng F Z, Li W Y, Rudnick R L, Gardner L R. Earth Planetary Sci. Lett., 2010, 300: 63-71
2. [2]
  2 Liu S B, Teng F Z, He Y S Ke S, Li S G. Earth Planetary Sci. Lett., 2010, 297: 646-654
3. [3]
  3 Yang W, Teng F Z, Zhang H F. Earth Planetary Sci. Lett., 2009, 288: 475-482
4. [4]
  4 Li W Y, Teng F Z, Ke S, Rudnick R L, Gao S, Wu F Y, Chappell B W. Geochim. Cosmochim. Acta, 2010, 74: 6867-6884
5. [5]
  5 Richter F M, Watson E B,Mendybaev R A, Teng F Z, Janney P E. Geochim. Cosmochim. Acta, 2008, 72: 206-220
6. [6]
  6 Huang F, Glessner J, Ianno A, Lundstrom C, Zhang Z F. Chem. Geol., 2009, 268: 16-23
7. [7]
  7 Higgins J A,Schrag D P. Geochim. Cosmochim. Acta, 2010, 74: 5039-5053
8. [8]
  8 Ra K, Kitagawa H, Shiraiwa Y. Mar. Micropaleontol., 2010, 77: 119-124
9. [9]
  9 Ke S, Liu S A, Li W Y, Yang W, Teng F Z. Acta Petrologica Sinica, 2011, 27(2): 383-397
10. [10]
  10 Huang F. Acta Petrologica Sinica, 2011, 27(2): 365-382
11. [11]
  11 Teng F Z, Yang W. Rapid Commun. Mass Spectrom., 2014, 28: 19-24
12. [12]
  12 Huang F, Chen L J, Wu Z Q, Wang W. Earth Planetary Sci. Lett., 2013, 367: 61-70
13. [13]
  13 Xiao Y, Teng F Z, Zhang H F, Yang W. Geochim. Cosmochim. Acta, 2013, 115: 241-261
14. [14]
  14 Li W Q, Beard B L, Li C X, Xu H F, Johnson C M. Geochim. Cosmochim. Acta, 2015, 157: 164-181
15. [15]
  15 Galy A, Yoffe O, Janney P E, Williams R W, Cloquet C, Alard O, Halicz L, Wadhwa M,Hutcheon I D, Ramond E, Carignan J. J. Anal. At. Spectrom., 2003, 18: 1352-1356
16. [16]
  16 Tipper E T,Louvat P, Capmas F, Galy A, Gaillardet J. Chem. Geol., 2008, 257: 65-75
17. [17]
  17 Wang Z R, Hu P, Gaetani G, Liu C, Saenger C, Cohen A, Hart S. Geochim. Cosmochim. Acta, 2013, 102: 113-123
18. [18]
  18 Teng F Z, Wadhwa M, Helz R T. Earth Planetary Sci. Lett., 2007, 261: 84-92
19. [19]
  19 Chang V T C,Makishima A, Belshaw N S, O'Nions R K. J. Anal. At. Spectrom, 2003, 18: 296-301
20. [20]
  20 An Y J, Wu F, Xiang Y X, Nan X Y, Yu X, Yang J H, Yu H M, Xie L W, Huang F. Chem. Geol., 2014, 390: 9-21
21. [21]
  21 Young E D, Ash R D,Galy A, Belshaw N S. Geochim. Cosmochim. Acta, 2002, 66(4): 683-698
22. [22]
  22 Pearson N J, Griffin W L, Alard O, O'Reilly S Y. Chem. Geol., 2006, 226: 115-133
23. [23]
  23 Norman M D, McCulloch M T, O'Neill H S C, Yaxley G M. J. Anal. At. Spectrom., 2006, 21: 50-54
24. [24]
  24 Young E D,Tonui E, Manning C E, Schauble E, Macris C A. Earth Planetary Sci. Lett., 2009, 288: 524-533
25. [25]
  25 Janney P E, Richter F M, Mendybaev R A, Wadhwa M, Georg R B, Watson E B, Hines R R. Chem. Geol., 2011, 281: 26-40
26. [26]
  26 Xie L W, Yin Q Z, Yang J H, Wu F Y, Yang Y H. J. Anal. At. Spectrom., 2011, 26: 1773-1780
27. [27]
  27 Sio C K I, Dauphas N, TENG Fang-Zhen, Chaussidon M, Helz R T, Roskosz M. Geochim. Cosmochim. Acta, 2013, 123(15): 302-321
28. [28]
  28 Oeser M, Weyer S, Horn I, Schuth S. Geostandard Geoanal. Res., 2014, 38(9): 311-328
29. [29]
  29 Sun Y L, Dong W F, Niu L G, Jiang T, Liu D X, Zhang L, Wang Y S, Chen Q D, Kim D P, Sun H B. Light-Sci. Appl., 2014, 3(1): e129
30. [30]
  30 BIAN Chen-Guang, WANG Li, WANG Yan-Qiu, SONG Zhe, LIU Ben-Kang. Chinese J. Anal. Chem., 2015, 43(8): 1241-1246 边晨光, 王利, 王艳秋, 宋哲, 刘本康. 分析化学, 2015, 43(8): 1241-1246
31. [31]
  31 Wang G Q, Lin Y T, Liang X R, Liu Y, Xie L W, Yang Y H, Tu X L. J. Anal. At. Spectrom, 2011, 26: 1878-1886
32. [32]
  32 HE Xue-Xian, ZHU Xiang-Kun, LI Shi-Zhen, TANG Suo-Han. Acta Petrologica et Mineralogica, 2008, 27(5): 441-448 何学贤, 朱祥坤, 李世珍, 唐索寒. 岩石矿物学杂志, 2008, 27(5): 441-448
33. [33]
  33 Galy A, Belshaw N S, Halicz L, O'Nions R K. Inter. J. Mass Spectrom., 2001, 208: 89-98
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