Citation: CHEN Bo, LIU Yang, ZHAO Xue-Song, PAN Xue-Jun. Fabrication of Polyethylenimine Functionalized Magnetic Nanoparticles and Its Adsorption and Separation Performance for Anionic Dyes with Anthraquinone Structure[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(2): 205-211. doi: 10.11895/j.issn.0253-3820.150549 shu

Fabrication of Polyethylenimine Functionalized Magnetic Nanoparticles and Its Adsorption and Separation Performance for Anionic Dyes with Anthraquinone Structure

1.
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China

Corresponding author: CHEN Bo,
Received Date: 8 July 2015
Available Online: 24 November 2015
Fund Project: 本文系国家自然科学基金(No.21307048) (No.21307048)云南省应用基础研究计划(No.2013FB011)资助项目 (No.2013FB011)

In this paper, polyethylenimine functionalized magnetic nanoadsorbents (Fe₃O₄-PEI) were prepared based on the chemical crosslinking reaction using glutaraldehyde as the crosslinker at room temperature. The structure of the nanomaterial was characterized by TEM, XRD, FT-IR, VSM, TGA and so on. Three anionic dyes (alizarin red, nuclear fast red and alizarin green) with anthraquinone structures were chosen as the target adsorbates. The parameters (such as solution pH, adsorption time, initial concentration of dyes and operating temperature) probably affecting the adsorption behaviour as well as the adsorption kinetics and isotherms were investigated by static adsorption experiments. The results indicated that under the experimental pH of 3.0, the q_max of alizarin red, nuclear fast red and alizarin green at 303 K was 256.1, 138.8 and 134.6 mg/g, respectively; initial dye concentration and contact time had significant effect on adsorption efficiency of target dyes; the adsorption equilibrium could reach within 60 min, the pseudo-secon-dorder kinetics model and the Langmuir isotherm equations could better describe the adsorption process; and the thermodynamics suggested an endothermic and spontaneous process for the adsorption of anthraquinone dyes. In addition, the remarkable stability and reusability of Fe₃O₄-PEI makes it a promising adsorbent for treatment of dye-bearing wastewater.
- Magnetic nanoparticles,
- Polyethylenimine,
- Adsorption,
- Anthraquinone dye
1. [1]
  1 Liu T H, Li Y H, Du Q J, Sun J K, Jiao Y Q, Yang G M, Wang Z H, Xia Y Z, Zhang W, Wang K L, Zhu H W, Wu D H. Colloids Surf. B, 2012, 90: 197-203
2. [2]
  2 Chen X W, Zhao Y R, Moutinho J, Shao J H, Zydeney A L, He Y L. J. Hazard. Mater., 2015, 284: 58-64
3. [3]
  3 SHI Yue-Jin, MA Nan. Chemical Industry Times, 2009, 23(6): 49-53 施跃锦, 马楠. 化工时刊, 2009, 23(6): 49-53
4. [4]
  4 ZHAO Jing, ZHANG Gai, MA Ai-Jie, ZHANG Wen-Zhi, ZHANG Qun. Water Purification Technology, 2014, 33(5): 48-52 赵菁, 张改, 马爱洁, 张文治, 张群. 净水技术, 2014, 33(5): 48-52
5. [5]
  5 GAO Shu-Ling, YANG Cui-Ling, LUO Xin-Sheng, ZHOU Peng-Xin, ZHANG Zhe. China Environmental Science, 2014, 34(1): 78-84 高淑玲, 杨翠玲, 罗鑫圣, 周鹏鑫, 张哲. 中国环境科学, 2014, 34(1): 78-84
6. [6]
  6 Mathieu-Denoncourt J, Martyniuk C J, de Solla S R, Balakrishnan V K, Langlois V S. Environ. Sci. Technol., 2014, 48(5): 2952-2961
7. [7]
  7 Jin Y J, Liu F, Tong M P, Hou Y L. J. Hazard. Mater., 2012, 227-228: 461-468
8. [8]
  8 Liu J F, Zhao Z S, Jiang G B. Environ. Sci. Technol., 2008, 42(18): 6949-6954
9. [9]
  9 Yan H, Yang L Y, Yang Z, Yang H, Li A M, Cheng R S. J. Hazard. Mater., 2012, 229-230: 371-380
10. [10]
  10 GAO Bao-Jiao, JIANG Peng-Fei, AN Fu-Qiang, ZHAO Shu-Ying. Acta Polym. Sinica, 2006, 1(1): 70-75 高保娇, 姜鹏飞, 安富强, 赵书英. 高分子学报, 2006, 1(1): 70-75
11. [11]
  11 Nayab S, Farrukh A, Oluz Z, Tuncel E, Tariq S R, Rahman H, Kirchhoff K, Duran H, Yameen B. ACS Appl. Mater. Interfaces, 2014, 6(6): 4408-4417
12. [12]
  12 Liu B, Huang Y M. J. Mater. Chem., 2011, 21(43): 17413-17418
13. [13]
  13 Wang L, Bao J, Wang L, Zhang F, Li Y. Chem. Eur. J., 2006, 12(24): 6341-6347
14. [14]
  14 Hong R Y, Li J H, Qu J M, Chen L L, Li H Z. Chem. Eng. J., 2009, 150(2): 572-580
15. [15]
  15 Sohrabi N, Rasouli N, Torkzadeh M. Chem. Eng. J., 2014, 240: 426-433
16. [16]
  16 Inbaraj B S, Chen B H. Biores. Technol., 2011, 102(19): 8868-8876
17. [17]
  17 Li D P, Zhang Y R, Zhao X X, Zhao B X. Chem. Eng. J., 2013, 232: 425-433
18. [18]
  18 Ma J, Yu F, Zhou L, Jin L, Yang M X, Luan J S, Tang Y H, Fan H B, Yuan Z W, Chen J H. ACS Appl. Mater. Interfaces, 2012, 4(11): 5749-5760
19. [19]
  19 Cai W Q, Tan L J, Yu J G, Jaroniec M, Liu X Q, Cheng B, Verpoort F. Chem. Eng. J., 2014, 239: 207-215
20. [20]
  20 Wang L, Liu W, Wang T, Ni J R. Chem. Eng. J., 2013, 225: 153-163
21. [21]
  21 Guo X Y, Du B, Wei Q, Yang J, Hu L H, Yan L G, Xu W Y. J Hazard. Mater., 2014, 278: 211-220
22. [22]
  22 Ghaedi M, Sadeghian B, Pebdani A A, Sahraei R, Daneshfar A, Duran C. Chem. Eng. J., 2012, 187: 133-141
1. [1]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Zhaoxin LI , Ruibo WEI , Min ZHANG , Zefeng WANG , Jing ZHENG , Jianbo LIU . Advancements in the construction of inorganic protocells and their cell mimic and bio-catalytical applications. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2286-2302. doi: 10.11862/CJIC.20240235
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
6. [6]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
7. [7]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
8. [8]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
9. [9]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
10. [10]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
11. [11]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
12. [12]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
13. [13]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
14. [14]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
15. [15]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
16. [16]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
17. [17]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
18. [18]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
19. [19]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
20. [20]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(523)
HTML views(99)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142