Citation: CHEN Bo, LIU Yang, ZHAO Xue-Song, PAN Xue-Jun. Fabrication of Polyethylenimine Functionalized Magnetic Nanoparticles and Its Adsorption and Separation Performance for Anionic Dyes with Anthraquinone Structure[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(2): 205-211. doi: 10.11895/j.issn.0253-3820.150549 shu

Fabrication of Polyethylenimine Functionalized Magnetic Nanoparticles and Its Adsorption and Separation Performance for Anionic Dyes with Anthraquinone Structure

1.
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China

Corresponding author: CHEN Bo,
Received Date: 8 July 2015
Available Online: 24 November 2015
Fund Project: 本文系国家自然科学基金(No.21307048) (No.21307048)云南省应用基础研究计划(No.2013FB011)资助项目 (No.2013FB011)

In this paper, polyethylenimine functionalized magnetic nanoadsorbents (Fe₃O₄-PEI) were prepared based on the chemical crosslinking reaction using glutaraldehyde as the crosslinker at room temperature. The structure of the nanomaterial was characterized by TEM, XRD, FT-IR, VSM, TGA and so on. Three anionic dyes (alizarin red, nuclear fast red and alizarin green) with anthraquinone structures were chosen as the target adsorbates. The parameters (such as solution pH, adsorption time, initial concentration of dyes and operating temperature) probably affecting the adsorption behaviour as well as the adsorption kinetics and isotherms were investigated by static adsorption experiments. The results indicated that under the experimental pH of 3.0, the q_max of alizarin red, nuclear fast red and alizarin green at 303 K was 256.1, 138.8 and 134.6 mg/g, respectively; initial dye concentration and contact time had significant effect on adsorption efficiency of target dyes; the adsorption equilibrium could reach within 60 min, the pseudo-secon-dorder kinetics model and the Langmuir isotherm equations could better describe the adsorption process; and the thermodynamics suggested an endothermic and spontaneous process for the adsorption of anthraquinone dyes. In addition, the remarkable stability and reusability of Fe₃O₄-PEI makes it a promising adsorbent for treatment of dye-bearing wastewater.
- Magnetic nanoparticles,
- Polyethylenimine,
- Adsorption,
- Anthraquinone dye
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沈阳化工大学材料科学与工程学院沈阳 110142