Citation: NIE Dong-Xia, SHI Guo-Yue, YU Yan-Yan. Fe₃O₄ Magnetic Nanoparticles as Peroxidase Mimetics Used in Colorimetric Determination of 2,4-Dinitrotoluene[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(2): 179-185. doi: 10.11895/j.issn.0253-3820.150319 shu

Fe₃O₄ Magnetic Nanoparticles as Peroxidase Mimetics Used in Colorimetric Determination of 2,4-Dinitrotoluene

1.
¹ Institute of Agro-food Standards and Testing Technologies, Shanghai Academy of Agricultural Sciences, Shanghai 201403, China;
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² Department of Chemistry, East China Normal University, Shanghai 200062, China;
3.
³ Department of Pharmaceutical Analysis, Xuzhou Medical College, Xuzhou 221004, China

Corresponding author: SHI Guo-Yue,
Received Date: 20 April 2015
Available Online: 15 October 2015
Fund Project: 本文系国家自然科学基金(No.31301494)项目资助 (No.31301494)

Fe₃O₄ magnetic nanoparticles (Fe₃O₄ MNPs) were prepared by co-precipitation method, which possessed intrinsic peroxidase-like activity. It was found that the as-prepared Fe₃O₄ MNPs could not only catalyze the oxidation of peroxidase substrate, diammonium 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS) by H₂O₂ to produce the colored product with maximum absorbance at 417 nm, but also catalyze the oxidation of 2,4-dinitrotoluene (DNT) by H₂O₂ and thus consume H₂O₂ in the reaction system. On the basis of the reaction described above, a novel colorimetric reaction system based on Fe₃O₄ MNPs-ABTS-H₂O₂-DNT was established for determination of trace amount of DNT. Some key influencing factors of the proposed Fe₃O₄ MNPs-ABTS-H₂O₂-DNT system were systematically discussed and optimized. Under the optimal conditions, the absorbance of the system at 417 nm displayed a good linear response with DNT concentration in the range from 5×10^-7 to 2.0×10^-5 mol/L with a detection limit of 1.5×10^-7 mol/L (S/N=3). These results demonstrated that the constructed colorimetric method was simple, rapid and sensitive enough for colorimetric detection of DNT, which would have a great potential in the application of on-line monitoring of DNT in environmental water samples.
- 2,4-Dinitrotoluene,
- Ferroferric oxide magnetic nanoparticles,
- Peroxidase mimetics,
- Colorimetric method
1. [1]
  1 HUANG Hua-Bin, ZHUANG Zhi-Xia, YANG Chao-Yong, WANG Xiao-Ru. Chinese J. Anal. Chem., 2014, 42(11): 1598-1603 黄华斌, 庄峙厦, 杨朝勇, 王小如. 分析化学, 2014, 42(11): 1598-1603
2. [2]
  2 CHEN Shuai, YAO Jian-Lin, GUO Qing-Hua, GU Ren-Ao. Spectroscopy and Spectral Analysis, 2011, 31(12): 3169-3174 陈帅, 姚建林, 郭清华, 顾仁敖. 光谱学与光谱分析, 2011, 31(12): 3169-3174
3. [3]
  3 Liu Y, Yuan M, Qiao L J, Guo R. Biosens. Bioelectron., 2014, 52(1): 391-396
4. [4]
  4 WEI Xiao-Ping, TAN Yan-Ji, LI Jian-Ping. Chinese J. Anal. Chem., 2015, 43(3): 424-428 魏小平, 谭艳季, 李建平. 分析化学, 2015, 43(3): 424-428
5. [5]
  5 Gao L Z, Zhuang J, Nie L, Zhang J B, Zhang Y, Gu N, Wang T H, Feng J, Yang D L, Perrett S, Yan X Y. Nat. Nanotechnol., 2007, 2(9): 577-583
6. [6]
  6 Wei H, Wang E. Anal. Chem., 2008, 80(6): 2250-2254
7. [7]
  7 Ding N, Yan N, Ren C L, Chen X G. Anal. Chem., 2010, 82(13): 5897-5899
8. [8]
  8 Liang M M, Fan K L, Pan Y, Jiang H, Wang F, Yang D L, Lu D, Feng J, Zhao J J, Yang L, Yan X Y. Anal. Chem., 2013, 85(1): 308-312
9. [9]
  9 Yang M Z, Guan Y P, Yang Y, Xia T T, Xiong W B, Wang N, Guo C. J. Colloid Interface Sci., 2013, 405(1): 291-295
10. [10]
  10 Shi G Y, Qu Y H, Zhai Y Y, Liu, Y, Sun Z Y, Yang J G, Jin L T. Electrochem. Commun., 2007, 9(7): 1719-1724
11. [11]
  11 Chen X, Cheng X Y, Gooding J J. Anal. Chem., 2012, 84(20): 8557-8563
12. [12]
  12 Sablok K, Bhalla V, Sharma P, Kaushal R, Chaudhary S, Suri C R. J. Hazard. Mater., 2013, 248-249(1): 322-328
13. [13]
  13 GAO Song, LIU Yuan-Yuan, LIU Na, LÜ Chun-Xin, WANG Lin, ZHANG Lan-Ying, PANG Ying-Ming. Chinese J. Anal. Chem., 2012, 40(9): 1353-1359 高松, 刘园园, 刘娜, 吕春欣, 王琳, 张兰英, 庞英明. 分析化学, 2012, 40(9): 1353-1359
14. [14]
  14 Gingras A, Sarette J, Shawler E, Lee T, Freund S, Holwitt E, Hicks B W. Biosens. Bioelectron., 2013, 48(1): 251-257
15. [15]
  15 Liang Y, Gu L, Liu X Q, Yang Q Y, Kajiura H, Li Y M, Zhou T S, Shi G Y. Chem. Eur. J., 2011, 17(21): 5989-5997
16. [16]
  16 Preiss A, Bauer A, Berstermann H M, Gerling S, Haas R, Joos A, Lehmann A, Schmalz L, Stinbach K. J. Chromatogr. A, 2009, 1216(25): 4968-4975
17. [17]
  17 Chen W S, Juan C N, Wei K M. Chemosphere., 2005, 60(8): 1072-1079
18. [18]
  18 Matta R, Hanna K, Chiron S. Sci. Total Environ., 2007, 385(1-3): 242-251
19. [19]
  19 Lee K B, Gu, M B, Moon S H. Water Res., 2003, 37(5): 983-992
20. [20]
  20 Yang Q Y, Liang Y, Zhou, T S, Shi G Y, Jin L T. Electrochem. Commun., 2008, 10(8): 1176-1179
21. [21]
  21 Wang N, Zhu L H, Wang M Q, Wang D L, Tang H Q. Ultrason. Sonochem., 2010, 17(1): 78-83
22. [22]
  22 Fierke M A, Olson E J, Bühlmann P, Stein A. Appl. Mater. Interfaces, 2012, 4(9): 4731-4739
23. [23]
  23 Apodaca D C, Pernites R B, Del Mundo F R, Advincula R C. Langmuir., 2011, 27(11): 6768-6779
24. [24]
  24 Zhang, S X, Zhao X L, Niu H Y, Shi Y L, Cai Y Q, Jiang G B. J. Hazard. Mater., 2009, 167(1-3): 560-566
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Fe3O4 Magnetic Nanoparticles as Peroxidase Mimetics Used in Colorimetric Determination of 2,4-Dinitrotoluene

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Fe₃O₄ Magnetic Nanoparticles as Peroxidase Mimetics Used in Colorimetric Determination of 2,4-Dinitrotoluene