Citation: NIE Dong-Xia, SHI Guo-Yue, YU Yan-Yan. Fe₃O₄ Magnetic Nanoparticles as Peroxidase Mimetics Used in Colorimetric Determination of 2,4-Dinitrotoluene[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(2): 179-185. doi: 10.11895/j.issn.0253-3820.150319 shu

Fe₃O₄ Magnetic Nanoparticles as Peroxidase Mimetics Used in Colorimetric Determination of 2,4-Dinitrotoluene

1.
¹ Institute of Agro-food Standards and Testing Technologies, Shanghai Academy of Agricultural Sciences, Shanghai 201403, China;
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² Department of Chemistry, East China Normal University, Shanghai 200062, China;
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³ Department of Pharmaceutical Analysis, Xuzhou Medical College, Xuzhou 221004, China

Corresponding author: SHI Guo-Yue,
Received Date: 20 April 2015
Available Online: 15 October 2015
Fund Project: 本文系国家自然科学基金(No.31301494)项目资助 (No.31301494)

Fe₃O₄ magnetic nanoparticles (Fe₃O₄ MNPs) were prepared by co-precipitation method, which possessed intrinsic peroxidase-like activity. It was found that the as-prepared Fe₃O₄ MNPs could not only catalyze the oxidation of peroxidase substrate, diammonium 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS) by H₂O₂ to produce the colored product with maximum absorbance at 417 nm, but also catalyze the oxidation of 2,4-dinitrotoluene (DNT) by H₂O₂ and thus consume H₂O₂ in the reaction system. On the basis of the reaction described above, a novel colorimetric reaction system based on Fe₃O₄ MNPs-ABTS-H₂O₂-DNT was established for determination of trace amount of DNT. Some key influencing factors of the proposed Fe₃O₄ MNPs-ABTS-H₂O₂-DNT system were systematically discussed and optimized. Under the optimal conditions, the absorbance of the system at 417 nm displayed a good linear response with DNT concentration in the range from 5×10^-7 to 2.0×10^-5 mol/L with a detection limit of 1.5×10^-7 mol/L (S/N=3). These results demonstrated that the constructed colorimetric method was simple, rapid and sensitive enough for colorimetric detection of DNT, which would have a great potential in the application of on-line monitoring of DNT in environmental water samples.
- 2,4-Dinitrotoluene,
- Ferroferric oxide magnetic nanoparticles,
- Peroxidase mimetics,
- Colorimetric method
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Fe3O4 Magnetic Nanoparticles as Peroxidase Mimetics Used in Colorimetric Determination of 2,4-Dinitrotoluene

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Fe₃O₄ Magnetic Nanoparticles as Peroxidase Mimetics Used in Colorimetric Determination of 2,4-Dinitrotoluene