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Citation: Wenjuan SHI, Yuke LU, Xiuyuan LI, Lei HOU, Yaoyu WANG. Mg(Ⅱ) metal-organic frameworks based on biphenyltetracarboxylic acid: Synthesis and CO2 adsorption and catalytic conversion performance[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(12): 2455-2463. doi: 10.11862/CJIC.20250220 shu

Mg(Ⅱ) metal-organic frameworks based on biphenyltetracarboxylic acid: Synthesis and CO2 adsorption and catalytic conversion performance

  • 1.

    Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi′an 710127, China

  • 2.

    School of Materials and Chemical Engineering, Xi′an Technological University, Xi′an 710021, China

  • Corresponding author: Lei HOU, lhou2009@nwu.edu.cn
  • Received Date: 1 July 2025
    Revised Date: 15 September 2025

Figures(4)

  • Under solvothermal synthetic conditions, this study employed the organic carboxylic acid ligand containing amino groups, 4, 4′-diamino-[1, 1′-biphenyl]-3, 3′, 5, 5′-tetracarboxylic acid (H4L), to react with Mg2+ ions, resulting in the preparation of a novel three-dimensional metal-organic framework: {[Mg2(L)(DMA)(H2O)2]·2DMA·H2O}n (Mg-MOF, DMA=N, N-dimethyl acetamide). The structure and stability of Mg-MOF were determined by single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and so on, and the CO2 adsorption and catalytic conversion properties were also deeply investigated. The results indicate that Mg-MOF crystallizes in the monoclinic system with space group P21/n, unit cell parameters a=1.399 88(15) nm, b=1.400 49(15) nm, c=1.768 57(19) nm, β=94.307(2)°. Mg-MOF shows a 4-connected (42·84)-ant topological net, possessing one-dimensional channels decorated with amino groups. It reveals excellent adsorption selectivity for CO2 over CH4 and CO (18.7-19.9 and 8.9-9.5, respectively), as well as highly efficient catalytic performance for the conversion of CO2 and epoxides into cyclic carbonates at the condition of 298 K and 100 kPa.
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