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Citation: Shaohua YANG, Na'na GAO, Yaqiong GONG. Metal-organic framework-templated construction of FeOOH@CoMoO4/nickel foam heterostructure for enhanced oxygen evolution reaction[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(10): 2175-2185. doi: 10.11862/CJIC.20250218 shu

Metal-organic framework-templated construction of FeOOH@CoMoO4/nickel foam heterostructure for enhanced oxygen evolution reaction

  • School of Chemistry and Chemical Engineering, North University of China, Taiyuan 030051, China

  • Corresponding author: Yaqiong GONG, gyq@nuc.edu.cn
  • Received Date: 29 June 2025
    Revised Date: 2 September 2025

Figures(7)

  • Through employing zeolitic imidazolate framework-67 (ZIF-67) templates, the straightforward hydrothermal and electrodeposition methods were applied to synthesize FeOOH@CoMoO4 heterostructure attached to the surface of nickel foam (NF). The specific structure of the as-prepared FeOOH@CoMoO4/NF-400s provided pronounced porosity and extensive surface area, enhancing rapid electron transport and exposing abundant active sites to improve catalytic reactions. Furthermore, the introduction of FeOOH, which induces electron transfer from FeOOH to CoMoO4, confirms their strong electronic interaction, thereby leading to an accelerated surface catalytic reaction. Consequently, the constructed FeOOH@CoMoO4/NF-400s heterostructure demonstrated exceptional oxygen evolution reaction (OER) activity, requiring an overpotential of 199 mV to deliver the current density of 10 mA·cm-2, coupled with the superior Tafel slope value of 49.56 mV·dec-1 and outstanding stability over 20 h under the current densities of both 10 and 100 mA·cm-2.
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