Citation: Lixing LU, Shaoxian LIU, Jian XU, Ziqi JIN, Jiongjia CHENG, Jiyang ZHAO, Fubo WANG, Haiying WANG. [FeFe]-hydrogenase-containing compound and its photocatalytic H₂-production performance[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(12): 2584-2590. doi: 10.11862/CJIC.20250200 shu

[FeFe]-hydrogenase-containing compound and its photocatalytic H₂-production performance

Lixing LU ^{1, 2} ,
Shaoxian LIU ¹ ,
Jian XU ¹ ,
Ziqi JIN ¹ ,
Jiongjia CHENG ¹ ,
Jiyang ZHAO ¹ ,
Fubo WANG ¹ ,
Haiying WANG ^{1, 3,,}

1.
School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China
2.
Gaofu New Energy Co., Ltd., Wuxi, Jiangsu 214000, China
3.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: Haiying WANG, wanghaiying@nju.edu.cn
Received Date: 12 June 2025
Revised Date: 11 July 2025

Figures(6)

A compound containing [FeFe]-hydrogenase, [Fe₂((SCH₂)₂R)(CO)₆] (1) (R=4-{(1H-benzo[d]imidazol-1-yl)methyl}-anilino), was prepared and thoroughly characterized by infrared spectroscopy, single-crystal X-ray diffraction, and density functional theory calculations. Its performance as a photocatalyst for hydrogen production via water splitting was evaluated under simulated sunlight. Within 3 h, the amount of H₂ produced was 386.5 μmol, achieving a catalytic efficiency of 25.26 μmol·mg^-1·h^-1 and a turnover number (TON) of 0.45.
- [FeFe]-hydrogenase,
- photocatalysis,
- water splitting,
- hydrogen production
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沈阳化工大学材料科学与工程学院沈阳 110142

[FeFe]-hydrogenase-containing compound and its photocatalytic H2-production performance

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通讯作者: 陈斌, bchen63@163.com

[FeFe]-hydrogenase-containing compound and its photocatalytic H₂-production performance