Advanced Search

Citation: Huaihao CHEN, Lingwen ZHANG, Yukun CHEN, Jianjun ZHANG. A water-stable metal-organic framework probe for Al3+/Ga3+/In3+ detection[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(12): 2601-2608. doi: 10.11862/CJIC.20250184 shu

A water-stable metal-organic framework probe for Al3+/Ga3+/In3+ detection

  • 1.

    Jiangsu Yichu ZR and HF New Material Co., Ltd., Xuzhou, Jiangsu 221400, China

  • 2.

    School of Chemistry, Dalian University of Technology, Dalian, Liaoning 116024, China

  • Corresponding author: Jianjun ZHANG, zhangjj@dlut.edu.cn
  • Received Date: 2 June 2025
    Revised Date: 15 September 2025

Figures(4)

  • The residues of Al3+, Ga3+, and In3+ in the environment pose an increasingly serious threat to human health and ecosystems. However, their specific and rapid detection remains challenging. In this study, we present a water-stable cadmium metal-organic framework (Cd-MOF) based luminescence probe, which can detect Al3+, Ga3+, and In3+ ions in aqueous solutions via a luminescence "turn-on" mode. The corresponding detection limits for the Al3+, Ga3+, and In3+ ions were 2.31, 3.06, and 2.78 μmol·L-1, respectively. This probe operated effectively within a pH range of 3-10 in an all-aqueous environment. Investigations into the detection mechanism revealed that this "turn-on" recognition is attributed to the formation of new structures upon ion interaction.
  • 加载中
    1. [1]

      JANG H J, KANG J H, YUN D, KIM C. A multifunctional selective "turn-on" fluorescent chemosensor for detection of group Ⅲ A ions Al3+, Ga3+ and In3+[J]. Photochem. Photobiol. Sci., 2018, 17(9): 1247-1125  doi: 10.1039/c8pp00171e

    2. [2]

      LI R F, CHEN X Y, ZHANG H, WANG Y R, LV Y, JIANG H P, GUO B W, FENG X. Co-based metal-organic framework nanosheets for robust hydrogen evolution in alkaline media[J]. Inorg. Chem., 2024, 63(4): 2282-2288  doi: 10.1021/acs.inorgchem.3c04291

    3. [3]

      WANG H Y, MIAO L, ZHANG B L, SUN Y J, CHEN J, LIU S Q, ZHANG W Q, WANG T, ZHANG J J. Coordinated solvent molecules enable the excellent capabilities of two Zn2+-based complexes in detecting L-arginine via long-lived luminescence recovery[J]. Adv. Funct. Mater., 2024, 34(40): 2403734  doi: 10.1002/adfm.202403734

    4. [4]

      YUAN J Y, DONG J, LEI S B, HU W P. Long afterglow MOFs: A frontier study on synthesis and applications[J]. Mater. Chem. Front., 2021, 5(18): 6824-6849  doi: 10.1039/D1QM00689D

    5. [5]

      ZHANG W Q, ZHANG B L, WANG T, CHEN J, LI ZY, WANG R H, LIU S Q, ZHANG J J. Two new Cd-based metal-organic frameworks for afterglow detection of Fe3+ and NH3[J]. J. Mater. Chem. A, 2024, 12(13): 7732-7741  doi: 10.1039/D4TA00356J

    6. [6]

      ASSEN A H, YASSINE O, SHEKHAH O, EDDAOUDI M, SALAMA K N. MOFs for the sensitive detection of ammonia: Deployment of fcu MOF thin films as effective chemical capacitive sensors[J]. ACS Sens., 2017, 2(9): 1294-1301  doi: 10.1021/acssensors.7b00304

    7. [7]

      WANG T, ZHANG P P, LIU S Q, WANG R H, ZHANG J J. A Bi‐CP‐based solid‐state thin‐film sensor: Preparation and luminescence sensing for bioamine vapors[J]. Chinese J. Inorg. Chem., 2024, 40(8): 1615-1621

    8. [8]

      DING Y, HU Y Y, ZHAO Y Y, LI Y R, HUANG Z T, CHAKIR S, XU Y F, SUN D S, LIU S Q, WANG H T, WANG X B. Plasma tailoring of NH2-MIL-53 with enhanced fluorescence emission for simultaneous detection of multiple heavy metals in water[J]. ACS Appl. Mater. Interfaces, 2024, 16(45): 62497-62508  doi: 10.1021/acsami.4c09330

    9. [9]

      LI J, ZHU Y L, XU H, ZHENG T F, LIU S J, WU Y Q, CHEN J L, CHEN Y Q, WEN H R. A benzothiadiazole-based Eu3+ metal-organic framework as the turn-on luminescent sensor toward Al3+ and Ga3+ with potential bioimaging application[J]. Inorg. Chem., 2022, 61(8): 3607-3615  doi: 10.1021/acs.inorgchem.1c03661

    10. [10]

      WANG M, GUO L, CAO D P. Metal-organic framework as luminescence turn-on sensor for selective detection of metal ions: Absorbance caused enhancement mechanism[J]. Sens. Actuator B‒Chem., 2018, 256: 839-845  doi: 10.1016/j.snb.2017.10.016

    11. [11]

      HAN Y X, WU X B, MA J C, WANG G. A post-modified metal- organic framework ZIF-90-AN as "turn-on" fluorescence probe for the highly selective and ultra-sensitive quantitative detection of common trivalent metal cations[J]. Mater. Today Chem., 2024, 36: 101984  doi: 10.1016/j.mtchem.2024.101984

    12. [12]

      HUANG J X, ZHAO H, ZHANG J J, ZHANG B L, NI J, SONG B, LI Y Q, LIU S Q, DUAN C Y. Diemissive dye@CP composites with full-spectrum tunable mechanoluminescence[J]. J. Mater. Chem. C, 2021, 9(42): 15165-15174  doi: 10.1039/D1TC02841C

    13. [13]

      ZHANG P P, ZHANG B L, SHI W J, CHEN J, SONG W T, ZHANG J J, LIU S Q, NI J. MOF-based probes for total content detection of Ca2+/Sr2+‒Regulating detection performance indicators of probes via "paramagnetic/diamagnetic heterometallic probes" strategy[J]. Sens. Actuator B‒Chem., 2024, 413: 135888  doi: 10.1016/j.snb.2024.135888

    14. [14]

      CHEN X, LI S Y, WANG Y, WU W N, CHEN Z. A Schiff base fluorescent probe for Al3+: Synthesis and application in living cells imaging[J]. Chinese J. Inorg. Chem., 2022, 38(10): 1993-1998

  • 加载中
    1. [1]

      Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310

    2. [2]

      Yanfen PENG , Xinyue WANG , Tianbao LIU , Xiaoshuo WU , Yujing WEI . Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1416-1426. doi: 10.11862/CJIC.20250018

    3. [3]

      Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291

    4. [4]

      Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448

    5. [5]

      Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134

    6. [6]

      Hongzhe GUO , Sen WANG , Lu YANG , Fucheng LIU , Jiongpeng ZHAO , Zhaoquan YAO . Highly selective acetylene capture by a pacs-type metal-organic framework constructed using metal-formate complexes as pore partition units. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2157-2164. doi: 10.11862/CJIC.20250179

    7. [7]

      Wanting CHEN , Chufei MIAO , Yan LIU , Bobi ZHENG , Xiaoyu ZHENG , Han XU , Jumei TIAN . Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1672-1680. doi: 10.11862/CJIC.20250013

    8. [8]

      Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320

    9. [9]

      Xinnan XIE , Boyu ZHANG , Jianxun YANG , Yi ZHONG , Younis Osama , Jianxiao YANG , Xinchun YANG . Ultrafine platinum clusters achieved by metal-organic framework derived cobalt nanoparticle/porous carbon: Remarkable catalytic performance in dehydrogenation of ammonia borane. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2095-2102. doi: 10.11862/CJIC.20250025

    10. [10]

      Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti4L6 cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177

    11. [11]

      Bangdi GE , Xiaowei SONG , Zhiqiang LIANG . A bifunctional three-dimensional Eu-MOF fluorescent probe for highly sensitive detection of 2, 4, 6-trinitrophenol and tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2165-2174. doi: 10.11862/CJIC.20250190

    12. [12]

      Shanqing YANG , Lulu WANG , Qiang ZHANG , Jiajia LI , Yilong LI , Tongliang HU . A propane-selective metal-organic framework for inverse selective adsorption propane/propylene separation. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2138-2148. doi: 10.11862/CJIC.20250154

    13. [13]

      Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co3O4/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298

    14. [14]

      Min ZHU , Yuxin WANG , Xiao LI , Yaxu XU , Junwen ZHU , Zihao WANG , Yu ZHU , Xiaochen HUANG , Dan XU , Monsur Showkot Hossain Abul . Construction of AgVO3/ZIF-8 composites for enhanced degradation of tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 994-1006. doi: 10.11862/CJIC.20240392

    15. [15]

      Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO2 cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415

    16. [16]

      Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb2+ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240

    17. [17]

      Ri PENG , Yingxiang BAI , Yuxin XIE , Dunru ZHU . cis/trans-Octahedral configuration induced topologically different MOFs: Syntheses, structures, and Hirshfeld surface analyses. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1650-1660. doi: 10.11862/CJIC.20250143

    18. [18]

      Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933

    19. [19]

      Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb3+-Eu3+ doped glass-ceramics containing Na8.12Y1.293Si6O18 crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137

    20. [20]

      Yuanyu YANG , Jianhua XUE , Yujia BAI , Lulu CUI , Dongdong YANG , Qi MA . Design, synthesis, and detection of Al3+ of two zinc complexes based on Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1207-1216. doi: 10.11862/CJIC.20250005

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(74)
  • HTML views(8)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return