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Citation: Huaihao CHEN, Lingwen ZHANG, Yukun CHEN, Jianjun ZHANG. A water-stable metal-organic framework probe for Al3+/Ga3+/In3+ detection[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(12): 2601-2608. doi: 10.11862/CJIC.20250184 shu

A water-stable metal-organic framework probe for Al3+/Ga3+/In3+ detection

  • 1.

    Jiangsu Yichu ZR and HF New Material Co., Ltd., Xuzhou, Jiangsu 221400, China

  • 2.

    School of Chemistry, Dalian University of Technology, Dalian, Liaoning 116024, China

  • Corresponding author: Jianjun ZHANG, zhangjj@dlut.edu.cn
  • Received Date: 2 June 2025
    Revised Date: 15 September 2025

Figures(4)

  • The residues of Al3+, Ga3+, and In3+ in the environment pose an increasingly serious threat to human health and ecosystems. However, their specific and rapid detection remains challenging. In this study, we present a water-stable cadmium metal-organic framework (Cd-MOF) based luminescence probe, which can detect Al3+, Ga3+, and In3+ ions in aqueous solutions via a luminescence "turn-on" mode. The corresponding detection limits for the Al3+, Ga3+, and In3+ ions were 2.31, 3.06, and 2.78 μmol·L-1, respectively. This probe operated effectively within a pH range of 3-10 in an all-aqueous environment. Investigations into the detection mechanism revealed that this "turn-on" recognition is attributed to the formation of new structures upon ion interaction.
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