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Citation: Leyu DING, Ying HE, Zhihe WEI, Yang PENG, Zhao DENG. Conductive polypyrrole-confined Co-MOF-74 for high-performance lithium metal anodes[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(12): 2491-2502. doi: 10.11862/CJIC.20250176 shu

Conductive polypyrrole-confined Co-MOF-74 for high-performance lithium metal anodes

  • Soochow Institute of Energy and Material Innovations, Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, College of Energy, Soochow University, Suzhou, Jiangsu 215006, China

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  • Conductive polypyrrole (PPy) with a lithiophilic site was confined to Co-MOF-74 pores by in situ polymerization strategy to prepare PPy@Co-MOF-74 (PPM), which was used for Cu electrode modification. This architecture achieves dual synergy. PPy effectively suppresses lithium dendrite growth via reduced lithium nucleation overpotential. Meanwhile, the 3D porous framework of Co-MOF-74 provides spatial buffering for lithium deposition to significantly alleviate volume expansion. Electrochemical test results demonstrated remarkable performance enhancements, with the modified PPM@Cu electrode achieving 250 stable cycles at 1 mA·cm-2 and 1 mAh·cm-2 in half-cell configuration. When it was paired with LiFePO4 (LFP) cathodes in full-cell tests, the system maintained 89% capacity retention after 350 cycles.
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