Citation: Laiyang ZHU, Xuze PAN, Xiaoying ZHANG, Xinyu XU, Shiheng LI, Fajin CAI, Yifan WANG, Qingxia YAO, Yi QIU, Jie SU. Synthesis of stable and porous bimetallic Ti-MOF for photocatalytic oxidation of aromatic sulfides to sulfoxides[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(10): 2115-2126. doi: 10.11862/CJIC.20250139 shu

Synthesis of stable and porous bimetallic Ti-MOF for photocatalytic oxidation of aromatic sulfides to sulfoxides

Laiyang ZHU ¹ ,
Xuze PAN ¹ ,
Xiaoying ZHANG ¹ ,
Xinyu XU ¹ ,
Shiheng LI ¹ ,
Fajin CAI ¹ ,
Yifan WANG ¹ ,
Qingxia YAO ^1,, ,
Yi QIU ² ,
Jie SU ^2,,

1.
School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252000, China
2.
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Qingxia YAO, yaoqingxia@lcu.edu.cn Jie SU, jie.su@pku.edu.cn
Received Date: 22 April 2025
Revised Date: 25 August 2025

Figures(6)

In the paper, we report a highly robust and porous bimetallic Ti-MOF (designated Mg₂Ti-ABTC) by utilizing a trinuclear [Mg₂TiO(COO)₆] cluster and a tetradentate H₄ABTC (3, 3′, 5, 5′-azobenzene tetracarboxylic acid) ligand. Mg₂Ti-ABTC exhibited permanent porosity for N₂, CO₂, CH₄, C₂H₂, C₂H₄, and C₂H₆ gas adsorption. Furthermore, Mg₂Ti-ABTC exhibited outstanding photocatalytic activity in the oxidation of aromatic sulfides to the corresponding sulfoxides under ambient air conditions. Mechanism studies reveal that photoinduced holes (h⁺), the superoxide radical (•O₂^-), and singlet oxygen (¹O₂) are pivotal species involved in the photocatalytic oxidation reaction.
- trinuclear heterometal-oxo cluster,
- bimetallic Ti-MOF,
- photocatalytic oxidation
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