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Citation: Yuying JIANG, Jia LUO, Zhan GAO. Development status and prospects of solid oxide cell high entropy electrode catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(9): 1719-1730. doi: 10.11862/CJIC.20250124 shu

Development status and prospects of solid oxide cell high entropy electrode catalysts

  • School of Chemical Engineering and Technology, Xi′an Jiaotong University, Xi′an 710049, China

  • Corresponding author: Zhan GAO, zhangao18@xjtu.edu.cn
  • Received Date: 13 April 2025
    Revised Date: 30 June 2025

Figures(6)

  • Solid oxide cells (SOCs), as efficient and clean energy conversion devices, enable reversible transformation between chemical and electrical energy, and hold strategic value in distributed power generation, industrial waste heat recovery, and low-carbon energy systems. However, conventional electrode materials face trade-offs between electrocatalytic activity and structural stability. Elemental segregation and interfacial degradation at high temperatures severely reduce efficiency and lifespan. In recent years, high-entropy engineering has offered new pathways for overcoming performance bottlenecks in electrode materials by leveraging high configurational entropy-induced effects: configurational entropy effect, lattice distortion effect, sluggish diffusion effect, and the cocktail effect. This review summarizes recent progress in high-entropy SOC electrodes and explains how the four major entropy-driven effects improve catalytic activity, ion/electron transport, and long-term structural stability. Building on this foundation, this review identifies multi-principal element design as the key to synchronizing interfacial reaction kinetics and thermo-mechanical durability. This review systematically consolidates recent advances in high-entropy electrode materials for enhancing critical SOC performance, highlighting their potential in improving electrode activity, poisoning resistance, and thermal stability. Core challenges and emerging opportunities for future research are also discussed.
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