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Citation: Zhi FANG, Liang SUN, Mingze ZHENG, Wenhao SHENG, Hongliang HUANG, Chongli ZHONG. An aluminum-based metal-organic framework with slit pores for the efficient separation and recovery of electronic specialty gas C3F8[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(10): 2054-2062. doi: 10.11862/CJIC.20250096 shu

An aluminum-based metal-organic framework with slit pores for the efficient separation and recovery of electronic specialty gas C3F8

  • 1.

    State Key Laboratory of Advanced Separation Membrane Materials, Tiangong University, Tianjin 300387, China

  • 2.

    School of Materials Science and Engineering, Tiangong University, Tianjin 300387, China

Figures(6)

  • In this study, an aluminium-based porphyrin metal-organic framework (Al-TCPP) with slit-shaped pores was prepared by a solvothermal method, and its adsorptive separation and recovery properties of electronic specialty gas C3F8 were investigated. The synthesized Al-TCPP has a narrow slit pore structure with a pore size of 0.6 nm×1.1 nm, which is slightly larger than the molecular size of C3F8 (0.57 nm×0.52 nm). Meanwhile, the densely packed C—H bonds and μ-OH groups in the Al-TCPP pores can form multiple hydrogen bonding sites with the F atoms of C3F8, which further enhances the affinity for C3F8. Adsorption experiments showed that the adsorption amount of C3F8 in Al-TCPP was up to 96.1 cm3·g-1 at 298 K and 100 kPa, while the N2 adsorption amount was only 6.1 cm3·g-1, affording a record C3F8/N2 selectivity of 244.8, which exceeded that of all the adsorbents reported so far. Meanwhile, the heat of adsorption of C3F8 in the low-pressure region was 50.6 kJ·mol-1, which was much higher than that of N2 (16.5 kJ·mol-1). Density functional theory (DFT) calculations also showed that multiple H atoms in the adjacent porphyrin units of Al-TCPP can form strong interactions with the F atoms of C3F8 by hydrogen bonding. Breakthrough experiments confirmed that Al-TCPP could achieve the effective separation of C3F8/N2 mixtures, and high-purity C3F8 could be recovered by the desorption process.
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