Citation: Aoran LIU, Rui LI, Zongyao WANG, Penghui SHANG, Jiawei WAN, Dan WANG. Hollow multi-shelled structure materials for catalytic applications[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(10): 2039-2053. doi: 10.11862/CJIC.20250036 shu

Hollow multi-shelled structure materials for catalytic applications

Aoran LIU ^{1, 2} ,
Rui LI ^{1, 2} ,
Zongyao WANG ^{1, 2} ,
Penghui SHANG ^{1, 2} ,
Jiawei WAN ^{1, 2,,} ,
Dan WANG ^{1, 2, 3,,}

1.
Key Laboratory of Biopharmaceutical Preparation and Delivery, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
College of Chemistry and Environment Engineering, Shenzhen University, Shenzhen, Guangdong 518071, China

Corresponding author: Jiawei WAN, jwwan@ipe.ac.cn Dan WANG, danwang@ipe.ac.cn; danwang@szu.edu.cn
Received Date: 5 February 2025
Revised Date: 27 August 2025

Figures(5)

Hollow multi-shelled structure (HoMS) is the novel multifunctional structural system, which are constructed with nanoparticles as structural units, featuring two or more shells, multiple interfaces, and numerous channels and demonstrating outstanding properties in energy conversion and mass transfer. In recent years, owing to the breakthroughs in synthetic methods, the diversity of composition and structure of HoMS has been greatly enriched, showing broad application prospects in energy, catalysis, environment and other fields. This review focuses on the research status of HoMS for catalytic applications. Firstly, the new synthesis method for HoMS, namely the sequential templating approach, is introduced from both practical and theoretical perspectives. Then, it summarizes and discusses the structure-performance relationship between the shell structure and catalytic performance. The unique temporal-spatial ordering property of mass transport in HoMS and the major breakthroughs it brings in catalytic applications are discussed. Finally, it looks forward to the opportunities and challenges in the development of HoMS.
- hollow multi-shelled structure,
- catalyst,
- sequential templating approach,
- temporal-spatial order,
- mass transfer
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沈阳化工大学材料科学与工程学院沈阳 110142