Citation: Jiahe LIU, Gan TANG, Kai CHEN, Mingda ZHANG. Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023 shu

Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries

Jiangsu Innovation Platform of Lithium Composite-Materials for Battery R&D, Institute of Energy Supply Technology for High-end Equipment, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China

Corresponding author: Mingda ZHANG, matchlessjimmy@163.com
Received Date: 18 January 2025
Revised Date: 13 March 2025

Figures(8)

To solve the problem of poor low-temperature performance of lithium-ion batteries (LIBs), an effective method was proposed to improve the low-temperature performance of batteries by adjusting the electrolyte additive formulation. Among them, the additive formulation of lithium tetrafluoroborate (LiBF₄)+vinylidene carbonate (VC)+1, 3-propane sulfonate lactone (PS)+fluorinated ethylene carbonate (FEC) had a better protection effect on the electrode. It can improve the electrochemical performance of the battery. The results showed that the target electrolyte had good low-temperature performance, with 0.2C first discharge specific capacities of 144.65 and 133.05 mAh·g^-1 for the electrode at -20 and -40 ℃, respectively, and good cycling stability. It is shown that the use of multifunctional additives can significantly improve the diffusion rate of lithium ions and promote the release of lithium ions on the electrode surface. Meanwhile, the better film-forming performance can also reduce the polarization of the battery and ultimately achieve high-capacity and high-stability battery performance under low-temperature conditions.
- electrolyte additive,
- lithium cobaltate battery,
- low-temperature performance
1. [1]
  HARPER G, SOMMERVILLE R, KENDRICK E, DRISCOLL L, SLATER P, STOLKIN R, WALTON A, CHRISTENSEN P, HEIDRICH O, LAMBERT S, ABBOTT A, RYDER K, GAINES L, ANDERSON P. Recycling lithium-ion batteries from electric vehicles[J]. Nature, 2019,575(7781):75-86.
2. [2]
  LU Y, HOU X S, MIAO L C, LI L, SHI R J, LIU L J, CHEN J. Cyclohexanehexone with ultrahigh capacity as cathode materials for lithiumion batteries[J]. Angew. Chem.-Int. Edit., 2019,58(21):7020-7024.
3. [3]
  XIE J, LU Y C. A retrospective on lithiumion batteries[J]. Nat. Commun., 2020,11(1)2499.
4. [4]
  SHI J L, EHTESHAMI N, MA J L, ZHANG H, LIU H D, ZHANG X, LI J, PAILLARD E. Improving the graphite/electrolyte interface in lithium ion battery for fast charging and low temperature operation: Fluorosulfonyl isocyanate as electrolyte additive[J]. J. Power Sources, 2019,429:67-74.
5. [5]
  WANG C S. Electrolyte design for ultra-stable, low-temperature lithium-ion batteries[J]. Matter, 2023,6(8):2610-2612. doi: 10.1016/j.matt.2023.07.006
6. [6]
  MENG F B, XIONG X Y, TAN L, YUAN B, HU R Z. Strategies for improving electrochemical reaction kinetics of cathode materials for subzero temperature Liion batteries: A review[J]. Energy Storage Mater., 2022,44:390-407.
7. [7]
  WANG B, YAN M Y. Research on the improvement of lithium ion battery performance at low temperatures based on electromagnetic induction heating technology[J]. Energies, 2023,16(23)7780. doi: 10.3390/en16237780
8. [8]
  ZHANG C H, HUO S D, SU B, BI C J, ZHANG C, XUE W D. Challenges of film-forming additives in low-temperature lithium-ion batteries: A review[J]. J. Power Sources, 2024,606234559. doi: 10.1016/j.jpowsour.2024.234559
9. [9]
  ASSAT G, TARASCON J M. Fundamental understanding and practical challenges of anionic redox activity in Li ion batteries[J]. Nat. Energy, 2018,3(5):373-386. doi: 10.1038/s41560-018-0097-0
10. [10]
  KOLETI U R, ZHANG C, MALIK R, DINH T Q, MARCO J. The development of optimal charging strategies for lithium-ion batteries to prevent the onset of lithium plating at low ambient temperatures[J]. J. Energy Storage, 2019,24100798. doi: 10.1016/j.est.2019.100798
11. [11]
  XIAO P, YUN X R, CHEN Y F, GUO X W, GAO P, ZHOU G M, ZHENG C M. Insights into the solvation chemistry in liquid electrolytes for lithium based rechargeable batteries[J]. Chem. Soc. Rev., 2023,52(15):5255-5316. doi: 10.1039/D3CS00151B
12. [12]
  HUBBLE D, BROWN D E, ZHAO Y Z, FANG C, LAU J, McCLOSKEY B D, LIU G. Liquid electrolyte development for lowtemperature lithium-ion batteries[J]. Energy Environ. Sci., 2022,15(2):550-578.
13. [13]
  MING J, CAO Z, WU Y Q, WAHYUDI W, WANG W X, GUO X R, CAVALLO L, HWANG J Y, SHAMIM A, LI L J, SUN Y K, ALSHAREEF H N. New insight on the role of electrolyte additives in rechargeable lithium ion batteries[J]. ACS Energy Lett., 2019,4(11):2613-2622.
14. [14]
  LV W X, ZHU C J, CHEN J, OU C X, ZHANG Q, ZHONG S W. High performance of low-temperature electrolyte for lithium-ion batteries using mixed additives[J]. Chem. Eng. J., 2021,418129400.
15. [15]
  WANG Y K, LI Z M, HOU Y P, HAO Z M, ZHANG Q, NI Y X, LU Y, YAN Z H, ZHANG K, ZHAO Q, LI F J, CHEN J. Emerging electrolytes with fluorinated solvents for rechargeable lithium-based batteries[J]. Chem. Soc. Rev., 2023,52(8):2713-2763. doi: 10.1039/D2CS00873D
16. [16]
  FAN X L, JI X, CHEN L, CHEN J, DENG T, HAN F D, YUE J, PIAO N, WANG R X, ZHOU X Q, XIAO X Z, CHEN L X, WANG C S. All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents[J]. Nat. Energy, 2019,4(10):882-890.
17. [17]
  ZHENG J M, YAN P F, MEI D H, ENGELHARD M H, CARTMELL S S, POLZIN B J, WANG C M, ZHANG J G, XU W. Highly stable operation of lithium metal batteries enabled by the formation of a transient high-concentration electrolyte layer[J]. Adv. Energy Mater., 2016,6(8)1502151.
18. [18]
  YANG B W, ZHANG H, YU L, FAN W Z, HUANG D H. Lithium difluorophosphate as an additive to improve the low temperature performance of LiNi_0.5Co_0.2Mn_0.3O₂/graphite cells[J]. Electrochim. Acta, 2016,221:107-114.
19. [19]
  HEKMATFAR M, HASA I, EGHBAL R, CARVALHO D V, MORETTI A, PASSERINI S. Effect of electrolyte additives on the LiNi_0.5Mn_0.3Co_0.2O₂ surface film formation with lithium and graphite negative electrodes[J]. Adv. Mater. Interfaces, 2020,7(1)1901500.
20. [20]
  ZHENG J X, LU J, AMINE K, PAN F. Depolarization effect to enhance the performance of lithium ion batteries[J]. Nano Energy, 2017,33:497-507.
21. [21]
  PHAM H Q, CHUNG G J, HAN J, HWANG E H, KWON Y G, SONG S W. Interface stabilization via lithium bis (fluorosulfonyl) imide additive as a key for promoted performance of graphite||LiCoO₂ pouch cell under -20 ℃[J]. J. Chem. Phys., 2020,152(9)094709.
22. [22]
  LIN Y C, YUE X P, ZHANG H, YU L, FAN W Z, XIE T. Using phenyl methanesulfonate as an electrolyte additive to improve performance of LiNi_0.5Co_0.2Mn_0.3O₂/graphite cells at low temperature[J]. Electrochim. Acta, 2019,300:202-207.
1. [1]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
2. [2]
  Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106
3. [3]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
4. [4]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
5. [5]
  Rui Yang , Hui Li , Qingfei Meng , Wenjie Li , Jiliang Wu , Yongjin Fang , Chi Huang , Yuliang Cao . Influence of PC-based Electrolyte on High-Rate Performance in Li/CrO_x Primary Battery. Acta Physico-Chimica Sinica, 2024, 40(9): 2308053-0. doi: 10.3866/PKU.WHXB202308053
6. [6]
  Jiandong Liu , Zhijia Zhang , Kamenskii Mikhail , Volkov Filipp , Eliseeva Svetlana , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 2308048-0. doi: 10.3866/PKU.WHXB202308048
7. [7]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
8. [8]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
9. [9]
  Hao Chen , Dongyue Yang , Gang Huang , Xinbo Zhang . Progress on Liquid Organic Electrolytes of Li-O₂ Batteries. Acta Physico-Chimica Sinica, 2024, 40(7): 2305059-0. doi: 10.3866/PKU.WHXB202305059
10. [10]
  Da Wang , Xiaobin Yin , Jianfang Wu , Yaqiao Luo , Siqi Shi . All-Solid-State Lithium Cathode/Electrolyte Interfacial Resistance: From Space-Charge Layer Model to Characterization and Simulation. Acta Physico-Chimica Sinica, 2024, 40(7): 2307029-0. doi: 10.3866/PKU.WHXB202307029
11. [11]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
12. [12]
  Caiyun Jin , Zexuan Wu , Guopeng Li , Zhan Luo , Nian-Wu Li . Phosphazene-based flame-retardant artificial interphase layer for lithium metal batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100094-0. doi: 10.1016/j.actphy.2025.100094
13. [13]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
14. [14]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
15. [15]
  Yajie Li , Bin Chen , Yiping Wang , Hui Xing , Wei Zhao , Geng Zhang , Siqi Shi . Inhibiting Dendrite Growth by Customizing Electrolyte or Separator to Achieve Anisotropic Lithium-Ion Transport: A Phase-Field Study. Acta Physico-Chimica Sinica, 2024, 40(3): 2305053-0. doi: 10.3866/PKU.WHXB202305053
16. [16]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
17. [17]
  Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
18. [18]
  Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO₂ Reduction to C₂ Products and Superior Rechargeable Zn-CO₂ Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
19. [19]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
20. [20]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(1149)
HTML views(151)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142