Citation: Yanfen PENG, Xinyue WANG, Tianbao LIU, Xiaoshuo WU, Yujing WEI. Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(7): 1416-1426. doi: 10.11862/CJIC.20250018 shu

Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene

College of Materials and Environmental Engineering, Key Laboratory of Micro‐Nano Powder and Advanced Energy Materials of Anhui Higher Education Institutes, Chizhou University, Chizhou, Anhui 247000, China

Corresponding author: Yanfen PENG, pengyanfen1978@126.com
Received Date: 15 January 2025
Revised Date: 18 April 2025

Figures(9)

Four new coordination polymers, {[Cd(mbtx)(4OHphCOO)]NO₃}_n (1), {[Zn(mbtx)(1, 4‐bdc)_0.5(H₂O)₂]·(1, 4‐bdc)_0.5·4H₂O}_n (2), {[Cd₂(mbtx)(5NO₂‐bdc)₂(H₂O)₃]·4.5H₂O}_n (3), and {[Zn(H₂O)₆][Zn₂(mbtx)₂(btc)₂(H₂O)₄]·2H₂O}_n (4) (mbtx=1, 3‐bis(4H‐1, 2, 4‐triazole)benzene, 4OHphCOO^-=p‐hydroxybenzoate, 1, 4‐bdc^2-=1, 4‐benzenedicarboxylate, 5NO₂‐bdc^2-=5‐nitro‐isophthalate, btc^3-=1, 3, 5‐benzenetricarboxylate), were synthesized under room temperature condition and characterized by single‐crystal X‐ray diffraction, elemental analyses, and powder X‐ray diffraction. Single‐crystal X‐ray structural analysis shows that complexes 1 and 3 are 2D networks. In 1, the adjacent 2D networks are linked to a 3D network by π‐π stacking interaction. 2 and 4 exhibit 1D chains, and the 1D chains are connected into a 3D network by π‐π stacking interaction and intermolecular hydrogen bond. Luminescence and thermogravimetric analysis of the four complexes were discussed.
- 1, 3‐bis(4H‐1, 2, 4‐triazole)benzene,
- π‐π stacking interaction,
- luminescence,
- aromatic carboxylic acid,
- hydrogen bond
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