Citation: Yi DING, Peiyu LIAO, Jianhua JIA, Mingliang TONG. Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393 shu

Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates

Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Institute of Green Chemistry and Molecular Engineering, Sun Yat⁃Sen University, Guangzhou 510006, China

Corresponding author: Jianhua JIA, jiajh3@mail.sysu.edu.cn Mingliang TONG, tongml@mail.sysu.edu.cn
Received Date: 1 November 2024
Revised Date: 1 December 2024

Figures(4)

1, 1, 2, 2-Tetra(pyridin-4-yl)ethene (TEPE) was chosen as a bridging ligand to assemble with Ag(Ⅰ) ions to form the cationic frameworks. And, the pentafluoro-benzoate anions (PFB^-) and the benzoate (Bz^-) anions as guests were introduced respectively to generate two new coordination compounds: [Ag(TEPE)(H₂O)](PFB)·7H₂O·3EtOH (1) and [Ag(TEPE)](Bz)·4H₂O·2EtOH (2). The compositions and structures of complexes 1 and 2 were characterized using the thermogravimetric analysis, IR spectra, and single-crystal X-ray diffraction analysis. 1 possesses a 2D brick-like coordination layer structure with the classical hcb topology, each Ag(Ⅰ) center is coordinated with an aqua ligand and three N atoms from three TEPE ligands respectively, forming the distorted tetrahedral coordination geometry. The PFB^- guests are distributed between the 2D layers to form diverse interactions with the main framework. 2 presents a 3D coordination network structure with the sqc8116 topology, in which each Ag(Ⅰ) center is coordinated in a tetrahedral geometry with four N atoms from four TEPE ligands respectively, and Bz^- guests are located at the larger channels along the c-axis. Interestingly, two complexes showed the characteristic fluorescent properties regulated by photoactive guests. Excited by UV light, 1 exhibited a red emission while 2 showed a blue emission.
- 1, 1, 2, 2-tetra(pyridin-4-yl)ethene,
- benzoate,
- metal-organic framework,
- silver(Ⅰ),
- photoluminescence
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