Citation: Huafeng SHI. Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378 shu

Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance

Huafeng SHI

Anhui Police College, Hefei 230000, China

Received Date: 21 October 2024
Revised Date: 3 June 2025

Figures(7)

The nickel foam (NF)-supported MnCoNi layered double hydroxide (LDH) nano-needle array was used as a substrate. Through a three-step wet-chemical route, a Co-Ni-S polymetallic sulfide-supported MnCoNi LDH@Co-Ni-S/NF amorphous hollow-polyhedral nanocomposite was successfully synthesized, demonstrating outstanding electrocatalytic oxygen evolution performance. The results of electrochemical tests showed that the material could output a current density of 50 mA·cm^-2 with an overpotential of only 248 mV in a 1.0 mol·L^-1 KOH solution. In addition, the constructed MnCoNi LDH@Co-Ni-S hollow polyhedral electrode could operate continuously and stably for at least 20 h under different current densities of 40, 60, and 80 mA·cm^-2, fully demonstrating that this electrode had good long-term stability.
- electrocatalyst,
- MnCoNi layered double hydroxide,
- Co-Ni-S amorphous hollow polyhedron,
- oxygen evolution reaction
1. [1]
  FIORI G, BONACCORSO F, IANNACCONE G, PALACIOS T, NEUMAIER D, SEABAUGH A. Electronics based on two-dimensional materials[J]. Nat. Nanotechnol., 2014,9:768-779. doi: 10.1038/nnano.2014.207
2. [2]
  XU S J, LEI Z Y, WU P Y. Facile preparation of 3D MoS₂/MoSe₂ nanosheet-graphene networks as efficient electrocatalysts for the hydrogen evolution reaction[J]. J. Mater. Chem. A, 2015,3:16337-16347. doi: 10.1039/C5TA02637G
3. [3]
  DENG C, DING F, LI X Y, GUO Y F, NI W, YAN Y M. Templated-preparation of a three-dimensional molybdenum phosphide sponge as a high performance electrode for hydrogen evolution[J]. J. Mater. Chem. A, 2015,4:59-66.
4. [4]
  LIN H F, LI H Y, LI Y Y, LIU J L, WANG X, WANG L. Hierarchical CoS/MoS₂ and Co₃S₄/MoS₂/Ni₂P nanotubes for efficient electrocatalytic hydrogen evolution in alkaline media[J]. J. Mater. Chem. A, 2017,5:25410-25419. doi: 10.1039/C7TA08760H
5. [5]
  SUBRAMANI V, SONG C, ANPO M, ANDRESEN J M. Recent advances in catalytic production of hydrogen from renewable sources[J]. Catal. Today, 2007,129:263-264. doi: 10.1016/j.cattod.2007.08.016
6. [6]
  DINCER I, AYDIN M I. New paradigms in sustainable energy systems with hydrogen[J]. Energy Convers. Manag., 2023,283116950. doi: 10.1016/j.enconman.2023.116950
7. [7]
  CHEN J, ZHOU W J, JIA J, WAN B A, LU J, XIONG T L. Porous molybdenum carbide microspheres as efficient binder-free electrocatalysts for suspended hydrogen evolution reaction[J]. Int. J. Hydrog. Energy, 2017,42:6448-6454. doi: 10.1016/j.ijhydene.2016.12.048
8. [8]
  FANG S L, CHOU T C, SAMIREDDI S, CHEN K H, CHEN L C, CHEN W F. Enhanced hydrogen evolution reaction on hybrids of cobalt phosphide and molybdenum phosphide[J]. R. Soc. Open Sci., 2017,4161016. doi: 10.1098/rsos.161016
9. [9]
  PENG Z, ZHANG Q, QI G, ZHANG H, LIU Q, HU G. Nanostructured Pt@RuO catalyst for boosting overall acidic seawater splitting[J]. Chin. J. Struct. Chem., 2024,43100191.
10. [10]
  WANG M, CHEN L, SUN L C. Recent progress in electrochemical hydrogen production with earth- abundant metal complexes as catalysts[J]. Energy Environ. Sci., 2012,5:6763-6768. doi: 10.1039/c2ee03309g
11. [11]
  DONG C L, ZHANG X L, XU J, SI R, SHENG J, LUO J. Rutheniumdoped cobalt - chromium layered double hydroxides for enhancing oxygen evolution through regulating charge transfer[J]. Small, 2020,16:1-7.
12. [12]
  LIU S J, ZHU J, SUN M, MA Z X, HU K, NAKAJIMA T. Promoting the hydrogen evolution reaction through oxygen vacancies and phase transformation engineering on layered double hydroxide nanosheets[J]. J. Mater. Chem. A, 2020,8:2490-2497. doi: 10.1039/C9TA12768B
13. [13]
  YUAN F F, WEI J D, QIN G X, NI Y H. Carbon cloth supported hierarchical core-shell NiCo₂S₄@CoNi-LDH nanoarrays as catalysts for efficient oxygen evolution reaction in alkaline solution[J]. J. Alloy. Compd., 2020,830154658. doi: 10.1016/j.jallcom.2020.154658
14. [14]
  ZHANG J T, YU L, CHEN Y, LU X F, GAO S Y, LOU X W. Designed formation of double-shelled Ni-Fe layered-double-hydroxide nanocages for efficient oxygen evolution reaction[J]. Adv. Mater., 2020,32:6432-6438.
15. [15]
  HUANG Z F, SONG J J, DU Y H, XI S B, DOU S Y, LOU X W. Chemical and structural origin of lattice oxygen oxidation in Co-Zn oxyhydroxide oxygen evolution electrocatalysts[J]. Nat. Energy, 2019,4:329-338. doi: 10.1038/s41560-019-0355-9
16. [16]
  LIU Y Q, ZHANG M, HU D, LI R Q, HU K, YAN K. Ar plasma-exfoliated ultrathin NiCo - layered double hydroxide nanosheets for enhanced oxygen evolution[J]. ACS Appl. Energy Mater., 2019,2:1162-1168. doi: 10.1021/acsaem.8b01717
17. [17]
  DUTTA S, INDRA A, FENG Y, SONG T, PAIK U. Self-supported nickel iron layered double hydroxide-nickel selenide electrocatalyst for superior water splitting activity[J]. ACS Appl. Mater. Interfaces, 2017,9:33766-33774. doi: 10.1021/acsami.7b07984
18. [18]
  LIU J, WANG J S, ZHANG B, RUAN Y J, LV L, JIANG J J. Hierarchical NiCo ₂S₄@NiFe LDH heterostructures supported on nickel foam for enhanced overall - water - splitting activity[J]. ACS Appl. Mater. Interfaces, 2017,9:15364-15372. doi: 10.1021/acsami.7b00019
19. [19]
  CHEN L, CHEN H, WU L, LI G, TAO K, HAN L. Zeolitic imidazolate framework-derived Co₃S₄@NiFe-LDH core-shell heterostructure as efficient bifunctional electrocatalyst for water splitting[J]. ACS Appl. Mater. Interfaces, 2024,16:8751-8762. doi: 10.1021/acsami.3c16683
20. [20]
  HUANG S H, MENG Y Y, HE S M, WU M M. N-, O-, and S-tridoped carbon-encapsulated Co₉S₈ nanomaterials: Efficient bifunctional electrocatalysts for overall water splitting[J]. Adv. Funct. Mater., 2017,27:1-10.
21. [21]
  HAO J H, LUO W, YANG W S, LI L H, SHI W D. Origin of the enhanced oxygen evolution reaction activity and stability of a nitrogen and cerium co-doped CoS₂ electrocatalyst[J]. J. Mater. Chem. A, 2020,8:22694-22702. doi: 10.1039/D0TA07163C
22. [22]
  GUO Y N, TANG J, WANG Z L, KANG Y M, BANDO Y S, YAMAUCHI Y. Elaborately assembled core - shell structured metal sulfides as a bifunctional catalyst for highly efficient electrochemical overall water splitting[J]. Nano Energy, 2018,47:494-502. doi: 10.1016/j.nanoen.2018.03.012
23. [23]
  XU W C, WANG H X. Earth-abundant amorphous catalysts for electrolysis of water[J]. Chin. J. Catal., 2017,38:991-1005. doi: 10.1016/S1872-2067(17)62810-9
24. [24]
  LI B L, DAI L L, SU G L, XIA Z Q, YE Y X, LI Z S. Construction of defective MnCo-LDH nanoflowers with high activity for overall water splitting[J]. Fuel, 2024,364130961. doi: 10.1016/j.fuel.2024.130961
25. [25]
  FENG X T, JIAO Q Z, LIU T, LI Q, YIN M M, ZHAO Y. Facile synthesis of Co ₉S₈ hollow spheres as a high-performance electrocatalyst for the oxygen evolution reaction[J]. ACS Sustain. Chem. Eng., 2018,6:1863-1871. doi: 10.1021/acssuschemeng.7b03236
26. [26]
  ZHANG H, MENG G, WEI T, DING J Y, LIU Q, LUO J, LlU X J. Co doping promotes the alkaline overall seawater electrolysis performance over MnPSe3 nanosheets[J]. Chem. Commun., 2023,59:12144-12149. doi: 10.1039/D3CC03434H
27. [27]
  YUAN F, ZHANG E L, LIU Z H, YANG K, ZHA Q Q, NI Y H. Hollow CoS^x nanoparticles grown on FeCo - LDH microtubes for enhanced electrocatalytic performances for the oxygen evolution reaction[J]. ACS Appl. Energy Mater., 2021,4:12211-12223. doi: 10.1021/acsaem.1c01947
28. [28]
  SHI H F, YANG K, WANG F F, NI Y H, ZHAI M H. Hierarchical MnCo₂O₄ nanowire@NiFe layered double hydroxide nanosheet heterostructures on Ni foam for overall water splitting[J]. CrystEngComm, 2021,23:7141-7150. doi: 10.1039/D1CE01037A
29. [29]
  LIU W J, LIU W X, HOU T, DING J Y, WANG Z G, YIN R L, SAN X Y, FENG L G, LUO J. Coupling Co-Ni phosphides for energy-saving alkaline seawater splitting[J]. Nano Res., 2024,17:4797-4806. doi: 10.1007/s12274-024-6433-8
30. [30]
  WANG M, WANG M, FU Y M, SHEN S H. Cobalt oxide and carbon modified hematite nanorod arrays for improved photoelectrochemical water splitting[J]. Chin. Chem. Lett., 2017,28:2207-2211. doi: 10.1016/j.cclet.2017.11.037
31. [31]
  WANG H T, LEE H W, DENG Y, LU Z Y, HUA P C, LIU Y Y. Bifunctional non - noble metal oxide nanoparticle electrocatalysts through lithium - induced conversion for overall water splitting[J]. Nat. Commun., 2015,6:7261-7269. doi: 10.1038/ncomms8261
32. [32]
  WANG F F, ZHANG K J, ZHA Q Q, NI Y H. Honeycomb-like Ni-Mo-S on Ni foam as superior bifunctional electrocatalyst for hydrogen evolution and urea oxidation[J]. J. Alloy. Compd., 2022,899163346. doi: 10.1016/j.jallcom.2021.163346
33. [33]
  LI X L, ZHA Q Q, NI Y H. Ni - Fe phosphate/Ni foam electrode: Facile hydrothermal synthesis and ultralong oxygen evolution reaction durability[J]. ACS Sustain. Chem. Eng., 2019,7:18332-18340. doi: 10.1021/acssuschemeng.9b03711
34. [34]
  LIU H, MA F X, XU C Y, YANG L, DU Y, WANG P P. Sulfurizing-induced hollowing of Co₉S₈ microplates with nanosheet units for highly efficient water oxidation[J]. ACS Appl. Mater. Interfaces, 2017,9:11634-11641. doi: 10.1021/acsami.7b00899
35. [35]
  ZHONG J, WU T, WU Q, DU S, CHEN D C, CHEN B. N-and S-codoped graphene sheet - encapsulated Co₉S₈nanomaterials as excellent electrocatalysts for the oxygen evolution reaction[J]. J. Power Sources, 2019,417:90-98. doi: 10.1016/j.jpowsour.2019.02.024
36. [36]
  ZHANG X P, SI C D, GUO X X, KONG R M, QU F L. A MnCo₂S₄ nanowire array as an earth- abundant electrocatalyst for an efficient oxygen evolution reaction under alkaline conditions[J]. J. Mater. Chem. A, 2017,5:17211-17215. doi: 10.1039/C7TA04804A
37. [37]
  JADHAV H S, ROY A, THORAT G M, CHUNG W J, SEO J G. Hierarchical free-standing networks of MnCo₂S₄ as efficient electrocatalyst for oxygen evolution reaction[J]. Ind. Eng. Chem., 2019,71:452-459. doi: 10.1016/j.jiec.2018.12.002
1. [1]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
2. [2]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
3. [3]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
4. [4]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
7. [7]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
8. [8]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
9. [9]
  Kai PENG , Xinyi ZHAO , Zixi CHEN , Xuhai ZHANG , Yuqiao ZENG , Jianqing JIANG . Progress in the application of high-entropy alloys and high-entropy ceramics in water electrolysis. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1257-1275. doi: 10.11862/CJIC.20240454
10. [10]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
11. [11]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
12. [12]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
13. [13]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
14. [14]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
15. [15]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
16. [16]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-. doi: 10.1016/j.actphy.2025.100104
17. [17]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
18. [18]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
19. [19]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
20. [20]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(7)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142