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Citation: Hengyi ZHU, Liyun JU, Haoyue ZHANG, Jiaxin DU, Yutong XIE, Li SONG, Yachao JIN, Mingdao ZHANG. Efficient regeneration of waste LiNi0.5Co0.2Mn0.3O2 cathode toward high-performance Li-ion battery[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358 shu

Efficient regeneration of waste LiNi0.5Co0.2Mn0.3O2 cathode toward high-performance Li-ion battery

  • Jiangsu Innovation Platform of Lithium Composite-Materials for Battery R&D, Institute of Energy Supply Technology or High-end Equipment, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China

  • Corresponding author: Mingdao ZHANG, matchlessjimmy@163.com
  • Received Date: 7 October 2024
    Revised Date: 21 February 2025

Figures(5)

  • An efficient interlocking process was developed, including acid leaching, co-precipitation, and heat treatment, to regenerate waste LiNi0.5Co0.2Mn0.3O2 (NCM523) materials. DL-tartaric acid and formic acid were used as leaching systems, and the leaching efficiencies of Li, Ni, Co, and Mn reached about 98%. The leaching solution was added to the oxalic acid solution for a co-precipitation reaction, and then the regeneration of the material was realized through heat treatment. The regenerated NCM523 material exhibited an excellent layered structure and uniform elemental distribution. When employed as a cathode material for LIBs, the regenerated NCM523 exhibited a discharge-specific capacity of 168.5 mAh·g-1 at 0.1C (18 mA·g-1), which is comparable to the performance of fresh NCM523. Furthermore, the regenerated NCM523 demonstrated a capacity retention of 93.09% after 100 cycles at 0.5C.
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