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Citation: Fangfang WANG, Jiaqi CHEN, Weiyin SUN. CuBi@Cu-MOF composite catalysts for electrocatalytic CO2 reduction to HCOOH[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350 shu

CuBi@Cu-MOF composite catalysts for electrocatalytic CO2 reduction to HCOOH

  • State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

  • Corresponding author: Weiyin SUN, sunwy@nju.edu.cn
  • Received Date: 25 September 2024
    Revised Date: 15 November 2024

Figures(5)

  • Two kinds of CuBi double perovskite modified Cu-metal-organic framework (CuBi@Cu-MOF) were prepared using a simple stirring method. The product selectivity and Faraday efficiency (FE) of the two composite materials as electrocatalysts for CO2 reduction were systematically evaluated in an alkaline system. The results demonstrated that CuBi@Cu-MOFs exhibited significantly enhanced HCOOH selectivity, the maximum FE of CuBi-MOF reached 56% which was better than the FE of Cu MOF catalyst itself (15%). The surface modification reduces the charge transfer resistance and increases the active sites, thus improving the electrocatalytic performance.
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