Citation: Zhongxin YU, Wei SONG, Yang LIU, Yuxue DING, Fanhao MENG, Shuju WANG, Lixin YOU. Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304 shu

Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands

School of Science, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: Shuju WANG, shujuwang@syuct.edu.cn Lixin YOU, youlx@syuct.edu.cn
Received Date: 14 August 2024
Revised Date: 17 October 2024

Figures(10)

A 1D Zn-based coordination polymer, {[Zn(L)(Phen)]·H₂O}_n (Zn-CP), was synthesized by the solvothermal method using 2, 2'-thiodiisonicotinic acid (H₂L) and 1, 10-phenanthroline (Phen) as ligands. The structure of ZnCP was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared analysis, elemental analysis, and thermogravimetric analysis. The results of the fluorescence studies demonstrated that Zn-CP exhibited a fluorescence quenching response to the chlortetracycline (CTC). In addition, Zn-CP exhibited excellent sensitivity and a rapid response time of 30 s, while maintaining a high detection efficacy after five cycles. A strong linear relationship was observed within the detection range of 5.0-40.0 μmol·L^-1, with a detection limit of 72.9 μmol·L^-1. The fluorescence mechanism studies indicate that the quenching sensing effect of Zn-CP on CTC is a consequence of energy competition absorption.
- coordination polymer,
- fluorescence sensing,
- chlortetracycline,
- 2, 2'-thiodiisonicotinic acid,
- 1, 10-phenanthroline
1. [1]
  Qiao M, Ying G G, Singer A C, Zhu Y G. Review of antibiotic resistance in China and its environment[J]. Environ. Int., 2018,110:160-172. doi: 10.1016/j.envint.2017.10.016
2. [2]
  Zhou Y T, Niu L L, Zhu S Y, Lu H J, Liu W P. Occurrence, abundance, and distribution of sulfonamide and tetracycline resistance genes in agricultural soils across China Sci[J]. Total Environ., 2017,599:1977-1983.
3. [3]
  Wang C J, Sun Q, Yang M, Liu E Z, Xue W M, Fan J. Preparation of highly luminescent nitrogen-doped carbon quantum dots and their detection of tetracycline antibiotics[J]. Colloid Surf. A-Physicochem. Eng. Asp., 2022,653129982. doi: 10.1016/j.colsurfa.2022.129982
4. [4]
  Zhao F K, Yang L, Chen L D, Li S J, Sun L. Bioaccumulation of antibiotics in crops under long-term manure application: Occurrence, biomass response and human exposure[J]. Chemosphere, 2019,219:882-895. doi: 10.1016/j.chemosphere.2018.12.076
5. [5]
  Girmatsion M, Mahmud A, Abraha B, Xie Y F, Cheng Y L, Yu H, Yao W R, Guo Y H, Qian H. Rapid detection of antibiotic residues in animal products using surface-enhanced Raman spectroscopy: A review[J]. Food Control, 2021,126108019. doi: 10.1016/j.foodcont.2021.108019
6. [6]
  Zhang X P, Wang J J, Wu Q H, Li L, Wang Y, Yang H L. Determination of kanamycin by high performance liquid chromatography[J]. Molecules, 2019,24(10)1902. doi: 10.3390/molecules24101902
7. [7]
  Ding Y F, Zhang X, Yin H J, Meng Q Y, Zhao Y M, Liu L, Wu Z L, Xu H J. Quantitative and sensitive detection of chloramphenicol by surface-enhanced Raman scattering[J]. Sensors, 2017,17(12)2962. doi: 10.3390/s17122962
8. [8]
  Long C J, Deng B Y, Sun S J, Meng S. Simultaneous determination of chlortetracycline, ampicillin and sarafloxacin in milk using capillary electrophoresis with electrochemiluminescence detection[J]. Food Addit. Contam. Part A-Chem., 2017,34(1):24-31. doi: 10.1080/19440049.2016.1254820
9. [9]
  Huang W J, Tang S F, Xiao W, Chen Y F, Li J J, Li J P. A molecularly imprinted photoelectrochemical sensor based on an rGO/MoSSe heterojunction for the detection of chlortetracycline[J]. Analyst, 2024,149(7):2023-2033. doi: 10.1039/D4AN00172A
10. [10]
  Li Z, Li S Y, Jiang L S, Xiao J P, Niu J W, Zhang Y, Chen C M, Zhou Q X. Construction of nitrogen-doped carbon dots-based fluorescence probe for rapid, efficient and sensitive detection of chlortetracycline[J]. Chemosphere, 2024,361142535. doi: 10.1016/j.chemosphere.2024.142535
11. [11]
  Deng R, Wang Z L, Chen J, Zhu L Q, Shi Y Q, Xue W L. Rapid detection and differentiation of chlortetracycline and tetracycline by N, P-Ti₃C₂ QDs[J]. Microchem. J., 2024,203110854. doi: 10.1016/j.microc.2024.110854
12. [12]
  Liu J, Yang B, Niu S Y, Liu X, Wang Y T, Zhang F M, Bi S Y. Rapid detection of chlortetracycline and metacycline in food based on the fluorescence quenching effect of ZnS@CdS quantum dots[J]. Food Biosci., 2024,59104031. doi: 10.1016/j.fbio.2024.104031
13. [13]
  Goodenough K M, Wall F, Merriman D. The rare earth elements: Demand, global resources, and challenges for resourcing future generations[J]. Nat. Resour. Res., 2018,27(2):201-216. doi: 10.1007/s11053-017-9336-5
14. [14]
  Cong Z Z, Zhu M C, Zhang Y, Yao W, Kosinova M, Fedin V P, Wu S Y, Gao E J. Three novel metal-organic frameworks with different coordination modes for trace detection of anthrax biomarkers[J]. Dalton Trans., 2022,51(1):250-256. doi: 10.1039/D1DT03760A
15. [15]
  Wang S Q, Wang L, Zhu Y M, Song Y H. Fluorescent detection of S^2- based on ZnMOF-74 and CuMOF-74[J]. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr, 2020,236118327. doi: 10.1016/j.saa.2020.118327
16. [16]
  Farahani Y D, Safarifard V. Highly selective detection of Fe³⁺, Cd²⁺ and CH₂Cl₂ based on a fluorescent Zn-MOF with azine-decorated pores[J]. J. Solid State Chem., 2019,275:131-140. doi: 10.1016/j.jssc.2019.04.018
17. [17]
  ZHANG H, WANG J J, FAN G, TANG L, YUE E L, BAI C, WANG X, ZHANG Y Q. A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol[J]. Chinese J. Inorg. Chem., 2024,40(3):646-654.
18. [18]
  Hübschle C B, Sheldrick G M, Dittrich B. ShelXle: A Qt graphical user interface for SHELXL[J]. J. Appl. Crystallogr., 2011,44:1281-1284. doi: 10.1107/S0021889811043202
19. [19]
  You L X, Guo Y, Xie S Y, Wang S J, Xiong G, Dragutan I, Dragutan V, Ding F, Sun Y G. Synthesis, structure and luminescence of lanthanide coordination polymers based on the 1, 3-bis(carboxymethyl) imidazolium salt[J]. J. Solid State Chem., 2019,278120900.
20. [20]
  Ma L F, Meng Q L, Li C P, Li B, Wang L Y, Du M, Liang F P. Delicate substituent effect of benzene-1, 2, 3-tricarboxyl tectons on structural assembly of unusual self-penetrating coordination frameworks[J]. Cryst. Growth Des., 2010,10(3):3036-3043.
21. [21]
  Su Z, Fan J, Okamura T, Sun W Y. Synthesis, crystal structure and photoluminescent property of metal-organic frameworks with mixed carboxylate and imidazole-containing ligands[J]. Chin. J. Chem., 2012,30(9):2016-2022. doi: 10.1002/cjoc.201200715
22. [22]
  Idrees M, Hussain S, Salam A. Development of a sensitive and selective method for the determination of some selected aldehydes based on fluorescence quenching[J]. J. Fluoresc., 2023,33(6):2253-2256. doi: 10.1007/s10895-023-03219-x
23. [23]
  Wang S J, Song W, Liu Y, Li Q, You L X, Xiong G, Ding F, Sun Y G. A water stable europium coordination polymer based on mixed organic ligands as a luminescence sensor for the detection of an anthrax biomarker[J]. Inorg. Chem. Commun., 2024,163112364. doi: 10.1016/j.inoche.2024.112364
1. [1]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
2. [2]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
3. [3]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
4. [4]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
5. [5]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
6. [6]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
7. [7]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Yueyue WEI , Xuehua SUN , Hongmei CHAI , Wanqiao BAI , Yixia REN , Loujun GAO , Gangqiang ZHANG , Jun ZHANG . Two Ln-Co (Ln=Eu, Sm) metal-organic frameworks: Structures, magnetism, and fluorescent sensing sulfasalazine and glutaraldehyde. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2475-2485. doi: 10.11862/CJIC.20240193
10. [10]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
11. [11]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
12. [12]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
13. [13]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
14. [14]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
15. [15]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
16. [16]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
17. [17]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
18. [18]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
19. [19]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
20. [20]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(40)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142