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Citation: Zhifang SU, Zongjie GUAN, Yu FANG. Process of electrocatalytic synthesis of small molecule substances by porous framework materials[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290 shu

Process of electrocatalytic synthesis of small molecule substances by porous framework materials

  • College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

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  • Small molecules, including inorganic compounds such as hydrogen, oxygen, ammonia, hydrocarbons, and hydrogen peroxide that can serve as energy sources, as well as organic compounds like urea and amino acids used in the biochemical industry, are assuming an increasingly pivotal role in daily life and production. The industrial synthesis of small molecule substances still faces challenges, such as the extensive utilization of precious metal catalysts and significant energy inefficiency. Electrochemical synthesis offers several advantages over traditional processes, including reduced catalyst costs, enhanced environmental sustainability, and superior performance. Porous material catalysts based on metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and porous coordination cages (PCCs) have attracted extensive attention due to their unique morphology, adjustable structure, high catalytic activity, and excellent chemical stability. Therefore, a key area of future research on the electrocatalytic synthesis of small molecules lies in advancing porous framework materials as electrocatalysts for synthesizing small molecule substances. This review provides a comprehensive overview of the utilization of these materials in electrocatalysis.
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