Citation: Dongdong YANG, Jianhua XUE, Yuanyu YANG, Meixia WU, Yujia BAI, Zongxuan WANG, Qi MA. Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266 shu

Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands

College of Chemistry and Chemical Engineering, Shanxi Datong University, Datong, Shanxi 037009, China

Corresponding author: Dongdong YANG, ddyang@sxdtdx.edu.cn Meixia WU, mwmxiccas@iccas.ac.cn Qi MA, maqihx@163.com
Received Date: 13 July 2024
Revised Date: 15 October 2024

Figures(6)

Two coordination polymers were synthesized by hydrothermal reaction, namely, [Cd(H₃cpbda)(2, 2'-bipy) (H₂O)]_n (1) and[Mn(H₃cpbda)(phen)(H₂O)]_n (2), where H₅cpbda=5, 5'-[(5-carboxy-1, 3-phenyl)bis(oxy)]triisophthalic acid, 2, 2'-bipy=2, 2'-bipyridine, phen=1, 10-phenanthroline. The two complexes were characterized by single-crystal X-ray diffraction, powder diffraction, infrared spectroscopy, and thermogravimetric analysis. Complexes 1 and 2 are "V"-shaped 1D chains, and the molecules form 2D (1) and 3D framework (2) structures through weak π…π stacking. Furthermore, complex 1 was dispersed in an aqueous solution and its fluorescence intensity demonstrated excellent stability. Complex 1 can specifically detect ciprofloxacin in urine with a detection limit of 1.91×10^-8 mol·L^-1.
- coordination polymer,
- flexible ligand,
- fluorescence,
- ciprofloxacin detection
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