Citation: Lulu DONG, Jie LIU, Hua YANG, Yupei FU, Hongli LIU, Xiaoli CHEN, Huali CUI, Lin LIU, Jijiang WANG. Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171 shu

Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology

School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy & New Function Materials, Yanan University, Yan'an, Shaanxi 716000, China

Corresponding author: Hua YANG, yanghua_08@163.com

Received Date: 14 May 2024
Revised Date: 21 December 2024

Figures(9)

A cadmium-based coordination polymer [Cd₄(L)₄(1,4-bib)₄]·2DMA (CP1) was synthesized under solvothermal conditions, where H₂L=2 hydroxyterephthalic acid, 1, 4 bib=1, 4 bis(imidazol1 ylmethyl) benzene, and DMA=N,N-dimethylacetamide. The structure was characterized by thermogravimetric analysis, elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction. The single crystal structure shows that CP1 belongs to the orthorhombic system, the space group Pna2₁, Cd(Ⅱ) forms a 2D plane structure through L^2-, and the 2D plane structure forms a 3D network with pcu topology through 1,4-bib. CP1 shows good fluorescence sensing performance and thermal stability and realizes efficient and sensitive detection of 2,4,6-trinitrophenol (TNP), Fe³⁺, and fluridine (FLU). The detection limits were 0.051 μmol·L^-1 (TNP), 0.65 μmol·L^-1 (Fe³⁺), and 0.14 μmol·L^-1 (FLU), respectively. In addition, the mechanism of fluorescence detection of pollutant detection was explored and a portable test paper was successfully prepared. A portable test paper could not only selectively detect FLU, but also showed different fluorescence colors in different concentrations of FLU.
- complex,
- crystal structure,
- fluorescence quenching
1. [1]
  CHEN D S, LU T, CHEN Y, YANG L. Two anthracene-based zirconium metal-organic frameworks with fcu and hcp topologies as versatile fluorescent sensors for detection of inorganic ions and nitroaromatics[J]. Spectroc. Acta Pt. A‒Molec. Biomolec. Spectr., 2023,300122916. doi: 10.1016/j.saa.2023.122916
2. [2]
  YIN H Q, WANG X Y, YIN X B. Rotation restricted emission and antenna effect in single metal-organic frameworks[J]. J. Am. Chem. Soc., 2019,141(38):15166-15173. doi: 10.1021/jacs.9b06755
3. [3]
  MOHAN B, KAMBOJ A, VIRENDER , SINGH K, PRIYANKA , SINGH G, POMBEIRO A J L, REN P. Metal-organic frameworks (MOFs) materials for pesticides, heavy metals, and drugs removal: Environmental safety[J]. Sep. Purif. Technol., 2023,310123175. doi: 10.1016/j.seppur.2023.123175
4. [4]
  BAUZA A, TIDDO J, MOOIBROEK , FRONTERA A. Towards design strategies for anion-π interactions in crystal engineering[J]. CrystEngComm, 2016,18(1):10-23. doi: 10.1039/C5CE01813G
5. [5]
  CALVO R, ZHANG K, PASSERA A, KATAYEV D. Facile access to nitroarenes and nitroheteroarenes using N-nitrosaccharin[J]. Nat. Commun., 2019,10(1)3410. doi: 10.1038/s41467-019-11419-y
6. [6]
  LENG H R, LV Z Y, TAN H L, JIA Y H, YOU H. Degradation of nitrobenzene in 3D stack Z-scheme photoelectrocatalytic system: Degradation condition, pathway analysis and synergistic mechanism[J]. Process Saf. Environ. Protect., 2023,169:34-47. doi: 10.1016/j.psep.2022.10.075
7. [7]
  XU N, ZHANG Q H, ZHANG G A. A carbazole-functionalized metal-organic framework for efficient detection of antibiotics, pesticides, and nitroaromatic compounds[J]. Dalton Trans., 2019,48(8):2683-2691. doi: 10.1039/C8DT04558E
8. [8]
  NAGARKAR S S, DESAI A V, GHOSH S K. Engineering metal-organic frameworks for aqueous phase 2,4,6-trinitrophenol (TNP) sensing[J]. CrystEngComm, 2016,18(17):2994-3007. doi: 10.1039/C6CE00244G
9. [9]
  MUKHERJEE D, PAL S C, DAS G, GORE K R, DAS M C. Devising robust hydrophobic MOFs and its membrane for ultra-sensitive aqueous phase detection of antibiotics and toxic nitro-explosives and adsorption of TNP[J]. J. Environ. Chem. Eng., 2023,11(5)110528. doi: 10.1016/j.jece.2023.110528
10. [10]
  SUN N, ZHANG Y J, YIN L, XIONG G, YOU L X, HE Y K, SUN Y G. A water-stable Tb-MOF as a multifunctional luminescent sensor for Fe³⁺ and Cr₂O₇^2- in water[J]. Inorg. Chim. Acta, 2023,555121581. doi: 10.1016/j.ica.2023.121581
11. [11]
  PAL S C, MUKHERJEE D, DAS M C. pH-Stable luminescent metal-organic frameworks for the selective detection of aqueous-phase Fe^Ⅲ and Cr^Ⅵ Ions[J]. Inorg. Chem., 2022,61(31):12396-12405. doi: 10.1021/acs.inorgchem.2c01793
12. [12]
  YU C Y, SUN X D, ZOU L F, LI G H, ZHANG L R, LIU Y L. A pillar-layered Zn-LMOF with uncoordinated carboxylic acid sites: High performance for luminescence sensing Fe³⁺ and TNP[J]. Inorg. Chem., 2019,58(6):4026-4032. doi: 10.1021/acs.inorgchem.9b00204
13. [13]
  XU H, DONG Y Y, WU Y H, REN W J, ZHAN T, WANG S L, GAO J K. An —OH group functionalized MOF for ratiometric Fe³⁺ sensing[J]. J. Solid State Chem., 2018,258:441-446. doi: 10.1016/j.jssc.2017.11.013
14. [14]
  ALEXANDRINO D A M, ALMEIDA C M R, MUCHA A P, ALEXANDRINO M F C. Revisiting pesticide pollution: The case of fluorinated pesticides[J]. Environ. Pollut., 2022,292118315. doi: 10.1016/j.envpol.2021.118315
15. [15]
  SARGENT R D, CARRILLO J, KREMEN C. Common pesticides disrupt critical ecological interactions[J]. Trends Ecol. Evol., 2023,38(3):207-210. doi: 10.1016/j.tree.2022.12.002
16. [16]
  STRA E A, KELLY E, STANLEY D A. Self-reported assessment of compliance with pesticide rules[J]. Ecotox. Environ. Safe., 2023,254114692. doi: 10.1016/j.ecoenv.2023.114692
17. [17]
  WANG Z P, WANG Y, LI X Y, JIA L F, YANG A Z, ZHAO W T, JIA Y, XU B Y, ZHAO H Q. Water-stable mixed-ligand Cd(Ⅱ) metal-organic frameworks as bis-color excited fluorescent sensors for the detection of vitamins and pesticides in aqueous solutions[J]. J. Mol. Struct., 2024,1305137699. doi: 10.1016/j.molstruc.2024.137699
18. [18]
  YANG N, PU H, SUN D W. Developing a magnetic SERS nanosensor utilizing aminated Fe-based MOF for ultrasensitive trace detection of organophosphorus pesticides in apple juice[J]. Food Chem., 2024,446138846. doi: 10.1016/j.foodchem.2024.138846
19. [19]
  DERBYSHIRE M, GARDINER P H E. Optimization of the simultaneous determination of Cr(Ⅲ) and Cr􀃱 by ion chromatography with chemiluminescence detection[J]. Anal. Chem., 1999,71(19):4203-4207. doi: 10.1021/ac9902751
20. [20]
  NGUYEN V L, DARMAN M, IRELAND A, MICHEAL F. A high performance liquid chromatography fluorescence method for the analysis of both pyridoxal-5-phosphate and thiamine pyrophosphate in whole blood[J]. Clin. Chim. Acta, 2020,506:129-134. doi: 10.1016/j.cca.2020.03.026
21. [21]
  WEN B, SHAN X Q, LIAN J. Separation of Cr(Ⅲ) and Cr􀃱 in river and reservoir water with 8-hydroxyquinoline immobilized polyacrylonitrile fiber for determination by inductively coupled plasma mass spectrometry[J]. Talanta, 2002,56(4):681-687. doi: 10.1016/S0039-9140(01)00632-4
22. [22]
  ZHAO Y Z, HAO H Y, WANG H B, SUN L H, ZHANG N, ZHANG X, LIANG J. Antibiotic quantitative fluorescence chemical sensor based on Zn-MOF aggregation-induced emission characteristics[J]. Microchem. J., 2023,190108626. doi: 10.1016/j.microc.2023.108626
23. [23]
  XUE J J, YANG F, JIN J, LI Y, WU D, YANGg G P, WANG Y Y. Design and synthesis of four newly water-stable Pb-based heterometallic organic frameworks: How do the second metals (Zn, Cd, Co, and Mn) optimize their fluorescent and catalytic properties[J]. Cryst. Growth Des., 2022,22(4):2628-2636. doi: 10.1021/acs.cgd.2c00073
24. [24]
  ZHAN Y J, LIU M Y, ZHOU S, YAN Z Y, TIAN J S, ZHANG Q J, YAO Z Y. Smartphone-assisted ratiometric sensing platform for on-site tetracycline determination based on europium functionalized luminescent Zr-MOF[J]. Food Chem., 2023,425136449. doi: 10.1016/j.foodchem.2023.136449
25. [25]
  LI S, ZHENG Y, LIU G C, LI X H, ZHANG Z, WANG X L. New two fold interpenetrating 3D polyoxovanadate-based metal-organic framework as bifunctional catalyst for the removal of 2-chloroethyl ethyl sulfide and phenolic compounds[J]. Polyoxometalates, 2024,3(3)9140061.
26. [26]
  CHONGDAR S, MONDAL U, CHAKRABORTY T, BANERJEE P, BHAUMIK A. A Ni-MOF as fluorescent/electrochemical dual probe for ultrasensitive detection of picric acid from aqueous media[J]. ACS Appl. Mater. Interfaces, 2023,15(11):14575-14586.
27. [27]
  HAO G N W, PENG L P, CHEN Y, LIU Y S, LI C L, ZHANG H, YANG W. A novel ratiometric fluorescence sensor based on lanthanide-functionalized MOF for Hg²⁺ detection[J]. Talanta, 2022,250123710. doi: 10.1016/j.talanta.2022.123710
28. [28]
  WANDERLEY M M, WANG C, WU C D, LIN W B. A chiral porous metal-organic framework for highly sensitive and enantioselective fluorescence sensing of amino alcohols[J]. J. Am. Chem. Soc., 2012,134:9050-9053.
29. [29]
  HU D C, LIN X R, GAO Q, ZHANG J M, FENG H, LIU J C. Synthesis of novel coordination polymer Cd-MOF and fluorescence recognition of tryptophan[J]. J. Mol. Struct., 2023,1284135389. doi: 10.1016/j.molstruc.2023.135389
30. [30]
  RATH B B, KOTTILIL D, JI W, VITTAL J J. Enhancement in two-photon absorption and photoluminescence in single crystals of Cd(Ⅱ) metal organic frameworks[J]. ACS Appl. Mater. Interfaces, 2023,15(22):26939-26945.
31. [31]
  WANG L B, WANG J J, YUE E L, LI J F, BAI C, TANG L, WANG X, HOU X Y, ZHANG Y Q. Fluorescence sensing and anti-counterfeiting application based a heterometallic Cd(Ⅱ)-Na(Ⅰ)-MOF[J]. J. Solid State Chem., 2022,309123026.
32. [32]
  Li Y Z, KRISHN R, XU F, ZHANG W F, SUI Y W, HOU L, WANG Y Y, ZHU Z H. A novel C₂H₂-selective microporous Cd-MOF for C₂H₂/C₂H₄ and C₂H₂/CO₂ separation[J]. Sep. Purif. Technol., 2023,306122678.
33. [33]
  XIA J, ZHAO B, WANG H S, SHI W, MA Y, SONG H B, CHENG P, LIAO D Z, YAN S P. Two-and three-dimensional lanthanide complexes: Synthesis, crystal structures, and properties[J]. Inorg. Chem., 2007,46:3450-3458.
34. [34]
  ZHANG L Y, LIU G F, ZHENG S L, YE B H, ZHANG X M, CHEN X M. Helical ribbons of cadmium(Ⅱ) and zinc(Ⅱ) dicarboxylates with bipyridyl-like chelates-Syntheses, crystal structures and photoluminescence[J]. Eur. J. Inorg. Chem., 2003:2965-2971.
35. [35]
  AN Y Y, LU L P, ZHU M L. One Cd^Ⅱ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr􀃱[J]. Chinese J. Inorg. Chem., 2023,39(05):939-946.
36. [36]
  WU J, LI B H, ZHONG H R, QIU S W, LIANG Y W, ZHUANG X Y, SINGH A, KUMAR A. Fluorescence sensing and photocatalytic properties of a 2D stable and biocompatible Zn(Ⅱ)-based polymer[J]. J. Mol. Struct, 2018,1158:264-270.
37. [37]
  DANG S, MA E, SUN Z M, ZHANG H J. A layer-structured Eu-MOF as a highly selective fluorescent probe for Fe³⁺ detection through a cation-exchange approach[J]. J. Mater. Chem., 2012,22(33):16920-16926.
38. [38]
  CHEN Z, SUN Y W, ZHANG L L, SUN D, LIU F L, MENG Q G, WANG R M, SUN D F. A tubular europium-organic framework exhibiting selective sensing of Fe³⁺ and Al³⁺ over mixed metal ions[J]. Chem. Commun., 2013,49:11557-11559.
39. [39]
  LIN X Z, TIAN D, GAO Q, SUN H W, XU J, BU X H. A chiral lanthanide metal-organic framework for selective sensing of Fe(Ⅲ) ions[J]. Dalton Trans., 2016,45:1040-1046.
40. [40]
  LIU Y, LIU Y N, PARK S J, ZHANG Y F, KIM T, CHAE S, PARK M, KIM H Y. One-step synthesis of robust nitrogen-doped carbon dots: Acid-evoked fluorescence enhancement and their application in Fe³⁺ detection[J]. J. Mater. Chem. A, 2015,3:17747-17754.
41. [41]
  ORELMA H, TEERINEN T, JOHANSSON L S, HOLAPPA S, LAINE J. CMC-modified cellulose biointerface for antibody conjugation[J]. Biomacromolecules, 2012,13(4):1051-1058.
1. [1]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
4. [4]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
5. [5]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
6. [6]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
7. [7]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
8. [8]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
9. [9]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
10. [10]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
11. [11]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
12. [12]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
13. [13]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
14. [14]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
15. [15]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
16. [16]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
17. [17]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
18. [18]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
19. [19]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
20. [20]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(30)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142