Citation: Xiaoning TANG, Shu XIA, Jie LEI, Xingfu YANG, Qiuyang LUO, Junnan LIU, An XUE. Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149 shu

Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries

Xiaoning TANG ^1,, ,
Shu XIA ¹ ,
Jie LEI ¹ ,
Xingfu YANG ¹ ,
Qiuyang LUO ¹ ,
Junnan LIU ¹ ,
An XUE ^2,,

1.
School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
2.
School of Materials and Architectural Engineering, Guizhou Normal University, Guiyang 550025, China

Corresponding author: Xiaoning TANG, xntang@gzu.edu.cn An XUE, xuean1129@163.com
Received Date: 29 April 2024
Revised Date: 22 July 2024

Figures(5)

Herein, F-doped MnO₂ with abundant oxygen vacancy (named F-MnO₂) was synthesized by an efficient and simple one-step hydrothermal method. The introduced oxygen vacancy and pre-intercalated F-doping play a vital role in improving the electrical conductivity of F-MnO₂ and facilitating ion diffusion, contributing to enhanced rate capability. In addition, the F doping results in the formation of F—Mn bonds, which can effectively inhibit the Jahn-Teller distortion of Mn³⁺ in the discharge product, thus improving the structural stability. Benefiting from these synergic effects, the assembled Zn||F-MnO₂ full battery exhibited a high capacity of 274 mAh·g^-1 at 0.5 A·g^-1, as well as a long cycle life and superior rate performance. Meanwhile, the energy storage mechanism was proved to be a H⁺ and Zn²⁺ co-insertion/extraction process by cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) tests.
- aqueous Zn-ion battery,
- MnO₂,
- F-doped,
- oxygen vacancy,
- cathode material
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沈阳化工大学材料科学与工程学院沈阳 110142

Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries

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通讯作者: 陈斌, bchen63@163.com

Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries