Citation: Junying LI, Xinyan CHEN, Xihui DIAO, Muhammad Yaseen, Chao CHEN, Hao WANG, Chuansong QI, Wei LI. Chiral fluorescent sensor Tb³⁺@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(12): 2497-2504. doi: 10.11862/CJIC.20240084 shu

Chiral fluorescent sensor Tb³⁺@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol

Junying LI ¹ ,
Xinyan CHEN ¹ ,
Xihui DIAO ¹ ,
Muhammad Yaseen ² ,
Chao CHEN ¹ ,
Hao WANG ^1,, ,
Chuansong QI ¹ ,
Wei LI ^1,,

1.
Beijing Key Lab of Special Elastomer Composite Materials, College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
2.
Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, Pakistan

Corresponding author: Hao WANG, wangh@bipt.edu.cn Wei LI, liwei77@bipt.edu.cn
Received Date: 17 March 2024
Revised Date: 1 September 2024

Figures(7)

Herein, a layered chiral coordination polymer, [Cd₂(D-cam)₂(2, 2'-bipy)₂]_n (Cd-CP), was synthesized using a solvothermal method with camphoric acid (D-H₂cam), 2, 2'-bipyridine (2, 2'-bipy) and Cd²⁺, and Tb³⁺@Cd-CP was in-situ synthesized introducing Tb³⁺ ions. The fluorescence experiments revealed that compared to Cd-CP, Tb³⁺@Cd-CP exhibited ultra-high fluorescence performance. The luminescence sensing performance demonstrated that Tb³⁺@Cd-CP could distinguish R/S-propylene glycol (R/S-PG) by fluorescence responses, with fluorescence quenching constant of 5.3×10³ and 2.0×10³ L·mol^-1 respectively and the enantioselectivity factor (α) of 2.65. Moreover, Tb³⁺@Cd-CP demonstrated limits of detection of 9.3 and 19.0 μmol·L^-1 for R-PG and S-PG, respectively, and showed good reproducibility.
- camphoric acid,
- coordination polymer,
- enantioselectivity,
- propylene glycol
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沈阳化工大学材料科学与工程学院沈阳 110142

Chiral fluorescent sensor Tb3+@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol

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通讯作者: 陈斌, bchen63@163.com

Chiral fluorescent sensor Tb³⁺@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol