Citation: Yingchun ZHANG, Yiwei SHI, Ruijie YANG, Xin WANG, Zhiguo SONG, Min WANG. Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078 shu

Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction

College of Chemistry and Materials Engineering, Bohai University, Jinzhou, Liaoning 121013, China

Corresponding author: Min WANG, wangmin@qymail.bhu.edu.cn
Received Date: 11 March 2024
Revised Date: 18 June 2024

Figures(11)

Two supramolecular complexes of [Mn₂(2, 2′-bipy)₄(H₂O)Cl₃](L₁)·6H₂O (1) and [Mn(2, 2′-bipy)₂(H₂O)Cl](L₂)·3H₂O (2) (L₁^-=p-methylbenzenesulfonate anion, L₂^-=m-nitrobenzenesulfonate anion, 2, 2′-bipy=2, 2′-bipyridine) were synthesized by solvothermal method. The complexes were characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, and nitrogen adsorption-desorption test. Using the Mannich reaction as a probe, the catalytic properties of the two complexes were studied, and the effects of the structure of the complexes on their catalytic properties were analyzed by comparing the results of scanning electron microscopy and powder X-ray diffraction. Finally, density functional theory was used to predict the active sites of the complexes, and X-ray photoelectron spectroscopy was used to prove the activation of the active sites. Then the mechanism of Mannich reaction catalyzed by the complexes was clarified.
- supramolecular complex,
- crystal structure,
- Mannich reaction,
- theoretical calculation,
- catalytic mechanism
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