Citation: Peng ZHOU, Xiao CAI, Qingxiang MA, Xu LIU. Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047 shu

Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster

Peng ZHOU ¹ ,
Xiao CAI ² ,
Qingxiang MA ^1,, ,
Xu LIU ^2,,

1.
School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China
2.
School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Qingxiang MA, maqx@nxu.edu.cn; Xu LIU, xuliu@nju.edu.cn
Received Date: 2 February 2024
Revised Date: 29 May 2024

Figures(5)

An alloy nanocluster of Au_11-xCu_x(dppf)₄Cl₂ (x=1, 2; dppf=1, 1'-bis(diphenylphosphine) ferrocene) was synthesized via a one -pot reduction method. X-ray crystallography shows that this nanocluster has a defective icosahedral core, which is analog to that of Au₁₁(dppf)₄Cl₂. The difference lies in that Cu atoms replace the inner shell Au atoms that are coordinated with the Cl atom. Therefore, Au_11-xCu_x(dppf)₄Cl₂ can be regarded as Cu-doped Au₁₁(dppf)₄Cl₂. The introduction of Cu atoms exerts an influence on the electronic property of the template nanocluster with the structural framework maintained, further resulting in a red shift of the optical absorption.
- nanocluster,
- metal,
- doping,
- structure,
- optical absorption
1. [1]
  Jin R C, Jiang D E. Atomically precise nanochemistry. West Sussex: John Wiley & Sons Ltd.,2023: 1-56
2. [2]
  Jin R C, Zeng C J, Zhou M, Chen Y X. Atomically precise colloidal metal nanoclusters and nanoparticles: Fundamentals and opportunities[J]. Chem. Rev., 2016,116(18):10346-10413. doi: 10.1021/acs.chemrev.5b00703
3. [3]
  Chakraborty I, Pradeep T. Atomically precise clusters of noble metals: Emerging link between atoms and nanoparticles[J]. Chem. Rev., 2017,117(12):8208-8271. doi: 10.1021/acs.chemrev.6b00769
4. [4]
  Zhu M Z, Aikens C M, Hollander F J, Schatz G C, Jin R C. Correlating the crystal structure of a thiol-protected Au₂₅ cluster and optical properties[J]. J. Am. Chem. Soc., 2008,130:5883-5885. doi: 10.1021/ja801173r
5. [5]
  Crasto D, Malola S, Brosofsky G, Dass A, Hakkinen H. Single crystal XRD structure and theoretical analysis of the chiral Au₃₀S (S-t-Bu)₁₈ cluster[J]. J. Am. Chem. Soc., 2014,136(13):5000-5005. doi: 10.1021/ja412141j
6. [6]
  Aikens C M. Electronic and geometric structure, optical properties, and excited state behavior in atomically precise thiolate-stabilized noble metal nanoclusters[J]. Acc. Chem. Res., 2018,51(12):3065-3073. doi: 10.1021/acs.accounts.8b00364
7. [7]
  Liu X, Cai X, Zhu Y. Catalysis synergism by atomically precise bimetallic nanoclusters doped with heteroatoms[J]. Acc. Chem. Res., 2023,56(12):1528-1538. doi: 10.1021/acs.accounts.3c00118
8. [8]
  Gao Z H, Wei K C, Wu T, Dong J, Jiang D E, Sun S H, Wang L S. A heteroleptic gold hydride nanocluster for efficient and selective electrocatalytic reduction of CO₂ to CO[J]. J. Am. Chem. Soc., 2022,144(12):5258-5262. doi: 10.1021/jacs.2c00725
9. [9]
  Krishnadas K R, Baksi A, Ghosh A, Natarajan G, Pradeep T. Structure-conserving spontaneous transformations between nanoparticles[J]. Nat. Commun., 2016,713447. doi: 10.1038/ncomms13447
10. [10]
  Yuan S F, He R L, Han X S, Wang J Q, Guan Z J, Wang Q M. Robust gold nanocluster protected with amidinates for electrocatalytic CO₂ reduction[J]. Angew. Chem. Int. Ed., 2021,60(26):14345-14349. doi: 10.1002/anie.202103060
11. [11]
  Huang R W, Wei Y S, Dong X Y, Wu X H, Du C X, Zang S Q, Mark T C W. Hypersensitive dual-function luminescence switching of a silverchalcogenolate clusterbased metalorganic framework[J]. Nat. Chem., 2017,9(7):689-697. doi: 10.1038/nchem.2718
12. [12]
  Sun Y N, Pei W, Xie M C, Xu S, Zhou S, Zhao J J, Xiao K, Zhu Y. Excitonic Au₄Ru₂(PPh₃)₂(SC₂H₄Ph)₈ cluster for lightdriven dinitrogen fixation[J]. Chem. Sci., 2020,11(9):2440-2447. doi: 10.1039/C9SC06424A
13. [13]
  Negishi Y, Iwai T, Ide M. Continuous modulation of electronic structure of stable thiolate-protected Au₂₅ cluster by Ag doping[J]. Chem. Commun., 2010,46(26):4713-4715. doi: 10.1039/c0cc01021a
14. [14]
  Li W L, Liu C, Abroshan H, Ge Q J, Yang X J, Xu H Y, Li G. Catalytic CO oxidation using bimetallic M_xAu_25-x clusters: A combined experimental and computational study on doping effects[J]. J. Phys. Chem. C, 2016,120(19):10261-10267. doi: 10.1021/acs.jpcc.6b00793
15. [15]
  Qian H F, Jiang D E, Li G, Gayathri C, Das A, Gil R R, Jin R C. Monoplatinum doping of gold nanoclusters and catalytic application[J]. J. Am. Chem. Soc., 2012,134(39):16159-16162. doi: 10.1021/ja307657a
16. [16]
  Kwak K, Tang Q, Kim M, Jiang D E, Lee D. Interconversion between superatomic 6-electron and 8-electron configurations of M@Au₂₄(SR)₁₈ clusters (M=Pd, Pt)[J]. J. Am. Chem. Soc., 2015,137(33):10833-10840. doi: 10.1021/jacs.5b06946
17. [17]
  Ito E, Takano S, Nakamura T, Tsukuda T. Controlled dimerization and bonding scheme of icosahedral M@Au₁₂(M=Pd, Pt) superatoms[J]. Angew. Chem. Int. Ed., 2021,60(2):645-649. doi: 10.1002/anie.202010342
18. [18]
  Kim M, Tang Q, Kumar A V N, Kwak K, Choi W, Jiang D E, Lee D. Dopant-dependent electronic structures observed for M₂Au₃₆(SC₆H₁₃)₂₄ clusters (M=Pt, Pd)[J]. J. Phys. Chem. Lett., 2018,9(5):982-989. doi: 10.1021/acs.jpclett.7b03261
19. [19]
  Kwak K, Choi W, Tang Q, Kim M, Lee Y, Jiang D E, Lee D. A molecule-like PtAu₂₄(SC₆H₁₃)₁₈ nanocluster as an electrocatalyst for hydrogen production[J]. Nat. Commun., 2017,814723. doi: 10.1038/ncomms14723
20. [20]
  Kang X, Xiang J, Lv Y, Du W J, Yu H Z, Wang S X, Zhu M Z. Synthesis and structure of self-assembled Pd₂Au₂₃(PPh₃)₁₀Br₇ nanocluster: Exploiting factors that promote assembly of icosahedral nano-building-blocks[J]. Chem. Mater., 2017,29(16):6856-6862. doi: 10.1021/acs.chemmater.7b02015
21. [21]
  Kauffman D R, Alfonso D, Matranga C, Qian H F, Jin R C. A quantum alloy: The ligand-protected Au_25-xAg_x(SR)₁₈ cluster[J]. J. Phys. Chem. C, 2013,117(15):7914-7923. doi: 10.1021/jp4013224
22. [22]
  Negishi Y, Munakata K, Ohgake W, Nobusada K. Effect of copper doping on electronic structure, geometric structure, and stability of thiolate-protected Au₂₅ nanoclusters[J]. J. Phys. Chem. Lett., 2012,3(16):2209-2214. doi: 10.1021/jz300892w
23. [23]
  Liu X, Wang E D, Zhou M, Wan Y, Zhang Y K, Liu H Q, Zhao Y, Li J, Gao Y, Zhu Y. Asymmetrically doping a platinum atom into a Au₃₈ nanocluster for changing the electron configuration and reactivity in electrocatalysis[J]. Angew. Chem. Int. Ed., 2022,61(31)e202207685. doi: 10.1002/anie.202207685
24. [24]
  Wang S X, Abroshan H, Liu C, Luo T Y, Zhu M Z, Kim H J, Rosi N L, Jin R C. Shuttling single metal atom into and out of a metal nanoparticle[J]. Nat Commun., 2017,8(1)848. doi: 10.1038/s41467-017-00939-0
25. [25]
  Yao C H, Lin Y J, Yuan J Y, Liao L W, Zhu M, Weng L H, Yang J L, Wu Z K. Mono-cadmium vs Mono-mercury doping of Au₂₅ nanoclusters[J]. J. Am. Chem. Soc., 2015,137(49):15350-15353. doi: 10.1021/jacs.5b09627
26. [26]
  Sun Y N, Liu X, Xiao K, Zhu Y, Chen M Y. Active-site tailoring of gold cluster catalysts for electrochemical CO₂ reduction[J]. ACS Catal., 2021,11(18):11551-11560. doi: 10.1021/acscatal.1c02193
27. [27]
  Li G J, Sui X, Cai X, Hu W G, Liu X, Chen M Y, Zhu Y. Precisely constructed silver active sites in gold nanoclusters for chemical fixation of CO₂[J]. Angew. Chem. Int. Ed., 2021,60(19):10573-10576. doi: 10.1002/anie.202100071
28. [28]
  Liu X, Yao G, Cheng X L, Xu J Y, Cai X, Hu W G, Xu W W, Zhang C F, Zhu Y. Cd-driven surface reconstruction and photodynamics in gold nanoclusters[J]. Chem. Sci., 2021,12(9):3290-3294. doi: 10.1039/D0SC05163B
29. [29]
  Xie S H, Tsunoyama H, Kurashige W, Negishi Y, Tsukuda T. Enhancement in aerobic alcohol oxidation catalysis of Au₂₅ clusters by single Pd atom doping[J]. ACS Catal., 2012,2(7):1519-1523. doi: 10.1021/cs300252g
30. [30]
  Sheldrick G M. Sheldrick G M. Crystal structure refinement with SHELXL[J]. Sect. C, 2015,C71:3-8.
31. [31]
  Dolomanov O V, Bourhis L J, Gildea R J, Howard J A K, Puschmann H. Olex2:A complete structure solution, refinement and analysis program[J]. J. Appl. Crystallogr., 2009,42:339-341. doi: 10.1107/S0021889808042726
32. [32]
  Yao L Y, Yam V W. Diphosphine-stabilized small gold nanoclusters: From crystal structure determination to ligation-driven symmetry breaking and anion exchange properties[J]. J. Am. Chem. Soc., 2016,138(48):15736-15742. doi: 10.1021/jacs.6b10168
33. [33]
  Frisch M J, Trucks G W, Schlegel H B, Scuseria G E, Robb M A, Cheeseman J R, Scalmani G, Barone V, Mennucci B, Petersson G J G I. Gaussian 09 E. 01. Wallingford, CT, Gaussian, Inc.,2009.
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Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster