Citation: Lu LIU, Huijie WANG, Haitong WANG, Ying LI. Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489 shu

Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline

School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China

Corresponding author: Lu LIU, liululiulu2012@126.com Ying LI, hnliy0412@126.com
Received Date: 30 December 2023
Revised Date: 11 April 2024

Figures(14)

A Cd(Ⅱ) complex, formulated as {(H₂dbim)_0.5[Cd(Hbptc)]·H₂O}_n (1), where dbim=1-(4-((2, 6-dimethyl-2H-benzo[d]imidazol-3(3H)-yl)methyl)benzyl)-2, 7-dihydro-2, 5-dimethyl-1H-benzo[d]imidazole, H₄bptc=3, 3', 4, 4'-benzophenone tetracarboxylic acid, has been obtained by hydrothermal reactions and structurally characterized. Complex 1 exhibits a 2D layer with a point symbol of {4⁴·6⁶}. Complex 1 was used for fluorescence identification of some common environmental pollutants. The result of the research shows that complex 1 can effectively detect p-nitrophenol, tetracycline, and 2, 6-dichloro-4-nitroaniline. The calculated quenching constants for p-nitrophenol, tetracycline, and 2, 6-dichloro-4-nitroaniline were 2×10², 5.4×10⁴, and 2×10⁴ L·mol^-1, respectively.
- Cd (Ⅱ) complex,
- crystal structure,
- topology structure,
- fluorescence recognition
1. [1]
  Wang Y B, Wu P, Wang Y N, He H, Huang L Z. Dendritic mesoporous nanoparticles for the detection, adsorption, and degradation of hazardous substances in the environment: State-of-the-art and future prospects[J]. J. Environ. Manage., 2023,345118629. doi: 10.1016/j.jenvman.2023.118629
2. [2]
  Wan K J, Satyanarayana M, Surendar T. Magnetically responsive SnFe₂O₄/g-C₃N₄ hybrid photocatalysts with remarkable visible-light-induced performance for degradation of environmentally hazardous substances and sustainable hydrogen production[J]. Appl. Surf. Sci., 2020,506144939. doi: 10.1016/j.apsusc.2019.144939
3. [3]
  Mario C, Elza B. New trajectories of technologies for the removal of pollutants and emerging contaminants in the environment[J]. Environ. Res., 2023,229115938. doi: 10.1016/j.envres.2023.115938
4. [4]
  Raynard C S, You S J, Wang Y F. Degradation of contaminants in plasma technology: An overview[J]. J. Hazard. Mater., 2022,424127390. doi: 10.1016/j.jhazmat.2021.127390
5. [5]
  Su H L, Azadeh N, Liu D, Rashid M, Charles C S, Li J L. Degradation of phenolic pollutants by persulfate-based advanced oxidation processes: Metal and carbon-based catalysis[J]. Rev. Chem. Eng., 2023,39(8):1269-1298. doi: 10.1515/revce-2022-0037
6. [6]
  Zhao X X, Liu Y Q, Zhu Q M, Gong W T. Catechol-based porous organic polymers for effective removal of phenolic pollutants from water[J]. Polymers, 2023,15(11)2565. doi: 10.3390/polym15112565
7. [7]
  Olalla G S, Pablo B S, Bego a G, ngeles D. Removal of phenolic pollutants from wastewater streams using ionic liquids[J]. Sep. Purif. Technol., 2020,236116310. doi: 10.1016/j.seppur.2019.116310
8. [8]
  Cao T T, Xu T F, Deng F X, Qiao W W, Cui C W. Reactivity and mechanism between OH and phenolic pollutants: Efficiency and DFT calculation[J]. J. Photochem. Photobiol. A, 2021,407113025. doi: 10.1016/j.jphotochem.2020.113025
9. [9]
  Wang H W, Zhang C, Wang Y N, Sun Y J, Fu Y X, Gong Z G, Liu K Q. Simultaneous degradation of refractory organics, antibiotics and antibiotic resistance genes from landfill leachate concentrate by GAC/O₃[J]. J. Clean. Prod., 2022,380135016. doi: 10.1016/j.jclepro.2022.135016
10. [10]
  Sandra B, Lidija Ć, Davor L, Mirta Č. TiO₂ assisted photocatalytic degradation of macrolide antibiotics[J]. Curr. Opin. Green Sust., 2017,6:34-41. doi: 10.1016/j.cogsc.2017.05.004
11. [11]
  Leder C, Suk M, Lorenz S, Rastogi T, Peifer C, Kietzmann M, Jonas D, Buck M, Pahl A, Kümmerer A. Reducing environmental pollution by antibiotics through design for environmental degradation[J]. ACS Sustain. Chem. Eng., 2021,9(28):9358-9368. doi: 10.1021/acssuschemeng.1c02243
12. [12]
  Wu S Q, Hu Y H. A comprehensive review on catalysts for electrocatalytic and photoelectrocatalytic degradation of antibiotics[J]. Chem. Eng. J., 2021,409127739. doi: 10.1016/j.cej.2020.127739
13. [13]
  Banjar M F, Abedin F N J, Fizal A N S, Sarih N M, Hossain M S, Osman H, Khalil N A, Yahaya A N A, Zulkifli M. Synthesis and characterization of a novel nanosized polyaniline[J]. Polymers, 2023,15(23)4565. doi: 10.3390/polym15234565
14. [14]
  Lu S L, Zhao B, Chen M X, Wang L, Fu X Z, Luo J L. Electrolysis of waste water containing aniline to produce polyaniline and hydrogen with low energy consumption[J]. Int. J. Hydrog. Energy, 2020,45(43):22419-22426. doi: 10.1016/j.ijhydene.2020.06.116
15. [15]
  Li Z, Zhu M S. Detection of pollutants in water bodies: Electrochemical detection or photo-electrochemical detection?[J]. Chem. Commun., 2020,56:14541-14552. doi: 10.1039/D0CC05709F
16. [16]
  HUANG Y, ZHAO N J, MENG D S, ZUO Z L, WANG X, MA M J, YANG R F, YIN G F, LIU J G, LIU W Q. Advance in the detection techniques of persistent organic pollutants by using fluorescence spectrometry[J]. Spectrosc. Spectr. Anal., 2017,39(7):2107-2113.
17. [17]
  Imran A, Mohd S, Omar M, Iqbal H. Advances in sample preparation in chromatography for organic environmental pollutants analyses[J]. J. Liq. Chromatogr. Relat. Technol., 2019,42(5):137-160.
18. [18]
  Guo Y M, Zhang Y J, Li T, Tao T. ZnO quantum dots for fluorescent detection of environmental contaminants[J]. J. Environ. Chem. Eng., 2021,9(6)106800. doi: 10.1016/j.jece.2021.106800
19. [19]
  Claudio P, Fabio M, Nello M, Giovanni T, Andrei D. Application of metal-organic frameworks[J]. Polym. Int., 2017,66(6):731-744. doi: 10.1002/pi.5315
20. [20]
  Chen Z M, Li X L, Yang C Q, Cheng K P, Tan T W, Lv Y Q, Liu Y. Hybrid porous crystalline materials from metal organic frameworks and covalent organic frameworks[J]. Adv. Sci., 2021,8(20)2101883. doi: 10.1002/advs.202101883
21. [21]
  WANG X Q, MA X H, FENG D D, TANG J, WU D. Synthesis of a water-stable Zn(Ⅱ)-based metal-organic framework for luminescence detecting Fe³⁺ and 2, 6-dichloro-4-nitroaniline[J]. Chinese J. Inorg. Chem., 2022,38(1):137-144.
22. [22]
  WANG G F, SUN S W, SONG S F, LÜ M. Synthesis of a Cd(Ⅱ)-based coordination polymer for luminescence detecting 2, 4, 6-trinitrophenol[J]. Chinese J. Inorg. Chem., 2023,39(12):2407-2414.
23. [23]
  ZHAO P R, LIU Y Q, HE C, DUAN C Y. A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene[J]. Chinese J. Inorg. Chem., 2024,40(4):713-724.
24. [24]
  Wu Z F, Huang X Y. A mechanoresponsive fluorescent mg-zn bimetallic MOF with luminescent sensing properties[J]. ChemistrySelect, 2018,3(17):4884-4888.
25. [25]
  Liu Q Q, Yue K F, Weng X J, Wang Y Y. Luminescence sensing and supercapacitor performances of a new (3, 3)-connected Cd-MOF[J]. CrystEngComm, 2019,21(41):6186-6195.
26. [26]
  Bronisz R. 1, 4-Di(1, 2, 3-triazol-1-yl) butane as building block for the preparation of the iron(Ⅱ) spin-crossover 2D coordination polymer[J]. Inorg. Chem., 2005,44:4463-4465.
27. [27]
  Sheldrick G M. A short history of SHELX[J]. Acta Crystallogr. Sect. A, 2008,A64:112-122.
1. [1]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
2. [2]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
3. [3]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
4. [4]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
5. [5]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
6. [6]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
7. [7]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
8. [8]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
9. [9]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
10. [10]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
11. [11]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
12. [12]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
13. [13]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
14. [14]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
15. [15]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
16. [16]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
17. [17]
  Tiantian Li , Ruochen Jin , Bin Wu , Dongming Lan , Yunjian Ma , Yonghua Wang . A novel insight of enhancing the hydrogen peroxide tolerance of unspecific peroxygenase from Daldinia caldariorum based on structure. Chinese Chemical Letters, 2024, 35(4): 108701-. doi: 10.1016/j.cclet.2023.108701
18. [18]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
19. [19]
  Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu₂Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu²⁺ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698
20. [20]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(55)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142