Citation: Fan JIA, Wenbao XU, Fangbin LIU, Haihua ZHANG, Hongbing FU. Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473 shu

Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄

Fan JIA ^{1, #} ,
Wenbao XU ^{2, #} ,
Fangbin LIU ^1,, ,
Haihua ZHANG ^2,, ,
Hongbing FU ^{2, 3,,}

1.
School of Chemical and Environmental Engineering, Changchun University of Science and Technology, Changchun 130000, China
2.
Institute of Molecular Plus, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China
3.
Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: Fangbin LIU, liufangbin@cust.edu.cn Haihua ZHANG, zhanghaihua@tju.edu.cn Hongbing FU, hbfu@cnu.edu.cn
Received Date: 17 December 2023
Revised Date: 25 March 2024

Figures(6)

Mn²⁺-doped quasi-two-dimensional perovskite (PEA)₂Pb_yMn_1-yBr₄ (PEA is phenylethylamine, y is the fraction of Pb²⁺ in the total content of Mn²⁺ and Pb²⁺) thin films were prepared successfully with high photoluminescence quantum yield (PLQY). It constructed a dual-emissive excited state transfer system, while (PEA)₂PbBr₄ and impurity Mn²⁺ respectively act as the donor and acceptor. Mn²⁺ incorporation improved the luminescence properties and film morphologies. Using the femtosecond transient absorption (TA) measurement, we demonstrated the charge transfer processes between the host and the guest. To study the electroluminescence properties, (PEA)₂Pb_yMn_1-yBr₄ film was employed as the active layer to fabricate LED (light emitting diodes, LEDs) devices. The (PEA)₂Pb_yMn_1-yBr₄ LED device emitted a bright orange color, which demonstrated a maximum luminous intensity of 0.21 cd·m^-2 with an external quantum efficiency (EQE) of 0.002 5%.
- metal halide perovskite,
- doping,
- charge transfer,
- luminescence material,
- electroluminescence
1. [1]
  Li C W, Wang X M, Bi E B, Jiang F Y, Park S M, Li Y, Chen L, Wang Z W, Zeng L W, Chen H, Liu Y J, Grice C R, Abudulimu A, Chung J H, Xian Y M, Zhu T, Lai H G, Chen B, Ellingson R J, Fu F, Ginger D S, Song Z N, Sargent E H, Yan Y F. Rational design of Lewis base molecules for stable and efficient inverted perovskite solar cells[J]. Science, 2023,379(6633):690-694. doi: 10.1126/science.ade3970
2. [2]
  Shen X Y, Gallant B M, Holzhey P, Smith J A, Elmestekawy K A, Yuan Z C, Rathnayake P V G M, Bernardi S, Dasgupta A, Kasparavicius E, Malinauskas T, Caprioglio P, Shargaieva O, Lin Y H, McCarthy M M, Unger E, Getautis V, Widmer-Cooper A, Herz L M, Snaith H J. Chloride-based additive engineering for efficient and stable wide-bandgap perovskite solar cells[J]. Adv. Mater., 2023,35(30)2211742. doi: 10.1002/adma.202211742
3. [3]
  Yang R, Li R Z, Cao Y, Wei Y Q, Miao Y F, Tan W L, Jiao X C, Chen H, Zhang L D, Chen Q, Zhang H T, Zou W, Wang Y M, Yang M, Yi C, Wang N N, Gao F, McNeill C R, Qin T S, Wang J P, Hang W. Oriented quasi-2D perovskites for high performance optoelectronic devices[J]. Adv Mater., 2018,30(51)1804771. doi: 10.1002/adma.201804771
4. [4]
  Xue J J, Wang R, Chen X H, Yao C L, Jin X Y, Wang K L, Huang W C, Huang T Y, Zhao Y P, Zhai Y X, Meng D, Tan S, Liu R Z, Wang Z K, Zhu C H, Zhu K, Beard M C, Yan Y F, Yang Y. Reconfiguring the band-edge states of photovoltaic perovskites by conjugated organic cations[J]. Science, 2021,371(6529):636-640. doi: 10.1126/science.abd4860
5. [5]
  Lin K B, Xing J, Quan L N, de Arquer F P G, Gong X W, Lu J X, Xie L Q, Zhao W J, Zhang D, Yan C Z, Li W Q, Liu X Y, Lu Y, Kirman J, Sargent E H, Xiong Q H, Wei Z H. Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent[J]. Nature, 2018,562(7726):245-248. doi: 10.1038/s41586-018-0575-3
6. [6]
  Sun Y Q, Ge L S, Dai L J, Cho C S, Orri J F, Ji K Y, Zelewski S J, Liu Y, Mirabelli A J, Zhang Y C, Huang J Y, Wang Y S, Gong K, Lai M C, Zhang L, Yang D, Lin J D, Tennyson E M, Ducati C, Stranks S D, Cui L S, Greeham N C. Bright and stable perovskite light-emitting diodes in the near-infrared range[J]. Nature, 2023,615(7954):830-835. doi: 10.1038/s41586-023-05792-4
7. [7]
  Zhang J B, Zhang T K, Ma Z Z, Yuan F L, Zhou X, Wang H Y, Liu Z, Qing J, Chen H T, Li X J, Su S J, Xie J N, Shi Z F, Hou L T, Shan C X. A multifunctional "halide-equivalent" anion enabling efficient CsPb(Br/I)₃ nanocrystals pure-red light-emitting diodes with external quantum efficiency exceeding 23%[J]. Adv. Mater., 2023,35(8)2209002. doi: 10.1002/adma.202209002
8. [8]
  Karlsson M, Yi Z Y, Reichert S, Luo X Y, Lin W H, Zhang Z Y, Bao C X, Zhang R, Bai S, Zheng G H J, Teng P P, Duan L, Lu Y, Zheng K B, Pullerits T, Deibel C, Xu W D, Friend R, Gao F. Mixed halide perovskites for spectrally stable and high-efficiency blue light-emitting diodes[J]. Nat. Commun., 2021,12(1)361. doi: 10.1038/s41467-020-20582-6
9. [9]
  Cui J Y, Liu Y, Deng Y Z, Lin C, Fang Z S, Xiang C S, Bai P, Du K, Zuo X B, Wen K C, Gong S L, He H P, Ye Z Z, Gao Y N, Tian H, Zhao B D, Wang J P, Jin Y Z. Efficient light-emitting diodes based on oriented perovskite nanoplatelets[J]. Sci. Adv., 2021,7(41)8458. doi: 10.1126/sciadv.abg8458
10. [10]
  Sun Q, Zhao C Y, Yin Z X, Wang S P, Leng J, Tian W M, Jin S Y. Ultrafast and high-yield polaronic exciton dissociation in two-dimensional perovskites[J]. J. Am. Chem. Soc., 2021,143(45):19128-19136. doi: 10.1021/jacs.1c08900
11. [11]
  Zhang H H, Wu C, Xu W B, Fu H B. Compact-type quasi-2D perovskite based on two conventional 3D perovskites[J]. Nano Lett., 2022,23(1):252-258.
12. [12]
  LU X R, ZHAO Y, LIU J, LI C H, YOU X C. Modulation of the structure and property ABX₃ type perovskite photovoltaic material[J]. Chinese J. Inorg. Chem., 2015,31(9):1678-1686.
13. [13]
  ZHANG Y, ZHOU H P. Intrinsic stability of organic-inorganic hybrid perovskite[J]. Acta Phys. Sin., 2019,68(15):137-147.
14. [14]
  Smith I C, Hoke E T, Solis-Ibarra D, McGehee M D, Karunadasa H I. A layered hybrid perovskite solar-cell absorber with enhanced moisture stability[J]. Angew. Chem. Int. Ed., 2014,53(42):11232-11235. doi: 10.1002/anie.201406466
15. [15]
  Zhao C Y, Tian W M, Sun Q, Yin Z X, Leng J, Wang S P, Liu J X, Wu K F, Jin S Y. Trap-enabled long-distance carrier transport in perovskite quantum wells[J]. J. Am. Chem. Soc., 2020,142(35):15091-15097. doi: 10.1021/jacs.0c06572
16. [16]
  Zhang L, Sun C J, He T W, Jiang Y Z, Wei J L, Huang Y M, Yuan M J. High-performance quasi-2D perovskite light-emitting diodes: From materials to devices[J]. Light-Sci. Appl., 2021,10(1)61. doi: 10.1038/s41377-021-00501-0
17. [17]
  Sun C J, Jiang Y Z, Cui M H, Qiao L, Wei J L, Huang Y M, Zhang L, He T W, Li S S, Hsu H Y, Qin C C, Long R, Yuan M J. High-performance large-area quasi-2D perovskite light-emitting diodes[J]. Nat. Commun., 2021,12(1)2207. doi: 10.1038/s41467-021-22529-x
18. [18]
  Qin C J, Matsushima T, Potscavage W J, Sandanayaka A S D, Leyden M R, Bencheikh F, Goushi K, Mathevet F, Heinrich B, Yumoto G, Kanemitsu Y, Adachi C. Triplet management for efficient perovskite light-emitting diodes[J]. Nat. Photonics, 2020,14(2):70-75. doi: 10.1038/s41566-019-0545-9
19. [19]
  Zhang H H, Yao J N, Zhou K G, Yang Y A, Fu H B. Thermally activated charge transfer in dual-emission Mn²⁺-alloyed perovskite quantum wells for luminescent thermometers[J]. Chem. Mater., 2022,34(4):1854-1861. doi: 10.1021/acs.chemmater.1c04118
20. [20]
  Mao L L, Stoumpos C C, Kanatzidis M G. Two-dimensional hybrid halide perovskites: Principles and promises[J]. J. Am. Chem. Soc., 2018,141(3):1171-1190.
21. [21]
  Guo Y X, Yin X T, Liu D, Liu J, Zhang C, Xie H X, Yang Y W, Que W X. Photoinduced self-healing of halide segregation in mixed- halide perovskites[J]. ACS Energy Lett., 2021,6(7):2502-2511. doi: 10.1021/acsenergylett.1c01040
22. [22]
  Zhong Y, Yang J, Wang X Y, Liu Y K, Cai Q Q, Tan L C, Chen Y W. Inhibition of ion migration for highly efficient and stable perovskite solar cells[J]. Adv Mater., 2023,35(52)2302552. doi: 10.1002/adma.202302552
23. [23]
  Yun R, Yang H X, Sun W D, Zhang L B, Liu X W, Zhang X D, Li X Y. Recent advances on Mn²⁺-doping in diverse metal halide perovskites[J]. Laser Photonics Rev., 2023,17(2)2200524. doi: 10.1002/lpor.202200524
24. [24]
  Wang S, Cai P Q, Xu T M, Pu X P, Du P, Wang X F, Tang Y, Yuan X L, Chen H C, Ai Q, Si J J, Yao X, Rabchinskii M K, Brunkov P N, Liu Z G. Self-trapped-induced energy funneling and broadband emission in the Mn²⁺ doped two-dimensional perovskite[J]. J. Lumin., 2020,226117457. doi: 10.1016/j.jlumin.2020.117457
25. [25]
  He Y H, Stoumpos C C, Hadar I, Luo Z Z, McCall K M, Liu Z F, Chung D Y, Wessels B W, Kanatzidis M G. Demonstration of energy-resolved γ‑ray detection at room temperature by the CsPbCl₃ perovskite semiconductor[J]. J. Am. Chem. Soc., 2021,143(4):2068-2077. doi: 10.1021/jacs.0c12254
26. [26]
  Li R J, Chen B B, Ren N Y, Wang P Y, Shi B, Xu Q J, Zhao H, Han W, Zhu Z, Liu J J, Huang Q, Zhang D K, Zhao Y, Zhang X D. CsPbCl₃-cluster-widened bandgap and inhibited phase segregation in a wide-bandgap perovskite and its application to NiO_x-based perovskite/silicon tandem solar cells[J]. Adv. Mater., 2022,34(27)2201451. doi: 10.1002/adma.202201451
27. [27]
  Ji S H, Yuan X, Cao S, Ji W Y, Zhang H Z, Wang Y J, Li H B, Zhao J L, Zou B S. Near-unity red Mn²⁺ photoluminescence quantum yield of doped CsPbCl₃ nanocrystals with Cd incorporation[J]. J. Phys. Chem. Lett., 2020,11(6):2142-2149. doi: 10.1021/acs.jpclett.0c00372
28. [28]
  Cortecchia D, Mróz W, Neutzner S, Borzda T, Folpini G, Brescia R, Petrozza A. Defect engineering in 2D perovskite by Mn(Ⅱ) doping for light-emitting applications[J]. Chem, 2019,5(8):2146-2158. doi: 10.1016/j.chempr.2019.05.018
29. [29]
  Zhang H H, Yao J N, Yang Y A, Fu H B. Tailoring color-tunable dual emissions of Mn²⁺-alloyed two-dimensional perovskite quantum wells[J]. Chem. Mater., 2021,33(8):2847-2854. doi: 10.1021/acs.chemmater.0c04934
30. [30]
  Li C H A, Geng P, Shivarudraiah S B, Ng M, Zhang X F, Xu B M, Guo L, Halpert J E. The multiple roles of metal ion dopants in spectrally stable, efficient quasi-2D perovskite sky-blue light-emitting devices[J]. Adv. Opt. Mater., 2021,9(21)2100860. doi: 10.1002/adom.202100860
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Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4

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通讯作者: 陈斌, bchen63@163.com

Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄