Citation: Zhihong LUO, Yan SHI, Jinyu AN, Deyi ZHENG, Long LI, Quansheng OUYANG, Bin SHI, Jiaojing SHAO. Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444 shu

Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries

Zhihong LUO ¹ ,
Yan SHI ¹ ,
Jinyu AN ² ,
Deyi ZHENG ¹ ,
Long LI ¹ ,
Quansheng OUYANG ³ ,
Bin SHI ^4,, ,
Jiaojing SHAO ^1,,

1.
School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
2.
College of Civil Engineering, Guizhou University, Guiyang 550025, China
3.
Advanced Batteries and Materials Engineering Research Center, Guizhou Light Industry Technical College, Guiyang 550025, China
4.
State Key Laboratory of Advanced Chemical Power Sources, Guizhou Meiling Power Supply Co., Ltd., Zunyi, Guizhou 563003, China

Corresponding author: Bin SHI, shibin401@sina.com Jiaojing SHAO, shaojiao_jing@163.com
Received Date: 27 November 2023
Revised Date: 11 March 2024

Figures(6)

Herein, the positively charged two-dimensional (2D) porous silica (PSN⁺) nanosheet was obtained by modifying the 2D silica obtained from acid-etched 2D vermiculite, and then the PSN⁺ was used as the filler of polyethylene oxide (PEO)-based solid polymer electrolytes (SPEs). Given the abundant positive charges, PSN⁺ effectively binds with the anions dissociated from lithium salts, thereby promoting lithium-ion transport and achieving a decent lithium-ion transference number. At 50 ℃, the PSN⁺-based SPEs demonstrated a higher ionic conductivity of 7.5×10^-5 S·cm^-1, lithium-ion transference number of 0.30, and a stable voltage window of 4.41 V. Consequently, the as-assembled LiFePO₄||Li batteries delivered excellent initial discharge specific capacity of 155.7 mAh·g^-1 at 0.2C with 97.1% capacity retention after 100 cycles at 50 ℃.
- lithium-ion battery,
- solid polymer electrolyte,
- filler,
- two-dimensional silica
1. [1]
  Wang Z, Shen L, Deng S G, Cui P, Yao X Y. 10 μm-thick high-strength solid polymer electrolytes with excellent interface compatibility for flexible all-solid-state lithium-metal batteries[J]. Adv. Mater., 2021,33(25)2100353. doi: 10.1002/adma.202100353
2. [2]
  Zhou M H, Liu R L, Jia D Y, Cui Y, Liu Q T, Liu S H, Wu D C. Ultrathin yet robust single lithium-ion conducting quasi-solid-state polymer-brush electrolytes enable ultralong-life and dendrite-free lithium-metal batteries[J]. Adv. Mater., 2021,33(29)2100943. doi: 10.1002/adma.202100943
3. [3]
  TU F F, XIE J, GUO F, ZHAO X B, WANG Y P, CHEN D, XIANG J Y, CHEN J. Preparation and electrochemical performance of Li_6.4La₃Zr_1.4Ta_0.6O₁₂/polymer-based solid composite electrolyte[J]. Chinese J. Inorg. Chem., 2020,36(8):1515-1523.
4. [4]
  Ye L H, Li X. A dynamic stability design strategy for lithium metal solid state batteries[J]. Nature, 2021,593(7858):218-222. doi: 10.1038/s41586-021-03486-3
5. [5]
  Zhang W Q, Nie J H, Li F, Wang Z L, Sun C W. A durable and safe solid-state lithium battery with a hybrid electrolyte membrane[J]. Nano Energy, 2018,45:413-419. doi: 10.1016/j.nanoen.2018.01.028
6. [6]
  Wang Y, Zanelotti C J, Wang X E, Kerr R, Jin L Y, Kan W H, Dingemans T J, Forsyth M, Madsen L A. Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium-ion pathways[J]. Nat. Mater., 2021,20(9):1255-1263. doi: 10.1038/s41563-021-00995-4
7. [7]
  Huo H Y, Gao J, Zhao N, Zhang D X, Holmes N G, Li X N, Sun Y P, Fu J M, Li R Y, Guo X X, Sun X L. A flexible electron-blocking interfacial shield for dendrite-free solid lithium metal batteries[J]. Nat. Commun., 2021,12(1)176. doi: 10.1038/s41467-020-20463-y
8. [8]
  WANG X, YANG J J, SHAO L, LI J J, ZHAO W F, MA A J, ZHANG G, CHEN W X. A facile preparation of composite polymer electrolyte with high ionic conductivity by thermal treatment[J]. Scientia Sinica Chimica, 2019,49(2):360-367.
9. [9]
  Zhang Y F, Wang J Y, Tan C, He Y, Chen Y Z, Huo S K, Zeng D L, Li C, Cheng H S. Fire-retardant sp boron-based single ion conducting polymer electrolyte for safe, high efficiency and dendrite-free Li-metal batteries[J]. J. Membr. Sci., 2021,620118921. doi: 10.1016/j.memsci.2020.118921
10. [10]
  Jung S K, Gwon H, Yoon G, Miara L J, Lacivita V, Kim J S. Pliable lithium superionic conductor for all-solid-state batteries[J]. ACS Energy Lett., 2021,6(5):2006-2015. doi: 10.1021/acsenergylett.1c00545
11. [11]
  Lin Y, Wang X M, Liu J, Miller J D. Natural halloysite nano-clay electrolyte for advanced all-solid-state lithium-sulfur batteries[J]. Nano Energy, 2017,31:478-485. doi: 10.1016/j.nanoen.2016.11.045
12. [12]
  ZHAO X, XIONG H M, CHEN J S. Proton-conducting and ionic-conducting polymer electrolytes based on polyethylene oxide (PEO)[J]. Chinese J. Inorg. Chem., 2002,18(1):63-66.
13. [13]
  Jiang Y, Yan X M, Ma Z F, Mei P, Xiao W, You Q L, Zhang Y. Development of the PEO based solid polymer electrolytes for all-solid-state lithium-ion batteries[J]. Polymers, 2018,10(11)10111237.
14. [14]
  Liu Y L, Zhao Y, Lu W, Sun L Q, Lin L, Zheng M, Sun X L, Xie H M. PEO based polymer in plastic crystal electrolytes for room temperature high-voltage lithium metal batteries[J]. Nano Energy, 2021,88106205. doi: 10.1016/j.nanoen.2021.106205
15. [15]
  Liu H B, Sun Q, Cheng J, Zhang H Q, Xu X, Li Y Y, Zeng Z, Zhao Y, Li D P, Lu J Y, Ci L J. Stable operation of polymer electrolyte-solid-state batteries via lone-pair electron fillers[J]. Nano Res., 2023,16(11):12727-12737. doi: 10.1007/s12274-023-6142-8
16. [16]
  Liu W T, Jiang J B, Yang Z H, Liu Y, Yang Z F, Bu M, Liao S X, Wu W Y, Huang T Q, Sang S B, Liu H T. Poly(ethylene oxide)-based composite electrolyte with lithium-doped high-entropy oxide ceramic enabled robust solid-state lithium-metal batteries[J]. Chem. Asian J., 2022,17(22)e202200839. doi: 10.1002/asia.202200839
17. [17]
  Zeng F Y, Sun Y Y, Hui B, Xia Y Z, Zou Y H, Zhang X L, Yang D J. Three-dimensional porous alginate fiber membrane reinforced PEO-based solid polymer electrolyte for safe and high‐performance lithium-ion batteries[J]. ACS Appl. Mater. Interfaces, 2020,12(39):43805-43812. doi: 10.1021/acsami.0c13039
18. [18]
  Revathy C, Sunitha V R, Money B K, Joseph R, Radhakrishnan S. Role of mixed molecular weight PEO-PVDF polymers in improving the ionic conductivity of blended solid polymer electrolytes[J]. Ionics, 2023,29(10):4025-4035. doi: 10.1007/s11581-023-05141-5
19. [19]
  Li L B, Shan Y H, Wang F R, Chen X H, Zhao Y M, Zhou D, Wang H, Cui W J. Improving fast and safe transfer of lithium-ions in solid-state lithium batteries by porosity and channel structure of polymer electrolyte[J]. ACS Appl. Mater. Interfaces, 2021,13(41):48525-48535. doi: 10.1021/acsami.1c11489
20. [20]
  Khan K, Hanif M B, Xin H, Hussain A, Ali H G, Fu B, Fang Z X, Motola M, Xu Z Q, Wu M Q. PEO-based solid composite polymer electrolyte for high capacity retention all-solid-state lithium metal battery[J]. Small, 2023,20(4)2305772.
21. [21]
  Su Y X, Xu F, Zhang X R, Qiu Y Q, Wang H Q. Rational design of high-performance PEO/ceramic composite solid electrolytes for lithium metal batteries[J]. Nano-Micro Lett., 2023,15(1)82. doi: 10.1007/s40820-023-01055-z
22. [22]
  Jeong D, Shim J, Shin H, Lee J C. Sustainable lignin-derived cross-linked graft polymers as electrolyte and binder materials for lithium metal batteries[J]. Chem. Sus. Chem., 2020,13(10):2642-2649. doi: 10.1002/cssc.201903466
23. [23]
  Liu D, Lu Z, Lin Z H, Zhang C X, Dai K, Wei W F. Organoboron- and cyano-grafted solid polymer electrolytes boost the cyclability and safety of high-voltage lithium metal batteries[J]. ACS Appl. Mater. Interfaces, 2023,15(17):21112-21122. doi: 10.1021/acsami.3c01681
24. [24]
  Zhao Z K, Zhang Y M, Li S J, Wang S H, Li Y L, Mi H W, Sun L N, Ren X Z, Zhang P X. A lithium carboxylate grafted dendrite-free polymer electrolyte for an all-solid-state lithium-ion battery[J]. J. Mater. Chem. A, 2019,7(45):25818-25823. doi: 10.1039/C9TA10689H
25. [25]
  Guo Z M, Pang Y P, Xia S X, Xu F, Yang J H, Sun L X, Zheng S Y. Uniform and anisotropic solid electrolyte membrane enables superior solid-state Li metal batteries[J]. Adv. Sci., 2021,8(16)2100899. doi: 10.1002/advs.202100899
26. [26]
  Zhang Z, Wang J L, Zhang S L, Ying H G, Zhuang Z H, Ma F, Huang P F, Yang T T, Han G R, Han W Q. Stable all-solid-state lithium metal batteries with Li₃N-LiF-enriched interface induced by lithium nitrate addition[J]. Energy Storage Mater., 2021,43:229-237. doi: 10.1016/j.ensm.2021.09.002
27. [27]
  Merrill L C, Chen X C, Zhang Y M, Ford H O, Lou K, Zhang Y B, Yang G, Wang Y Y, Schaefer J L, Dudney N J. Polymer-ceramic composite electrolytes for lithium batteries: A comparison between the single-ion-conducting polymer matrix and its counterpart[J]. ACS Appl. Energy Mater., 2020,3(9):8871-8881. doi: 10.1021/acsaem.0c01358
28. [28]
  Li S, Zhang S Q, Shen L, Liu Q, Ma J B, Lv W, He Y B, Yang Q H. Progress and perspective of ceramic/polymer composite solid electrolytes for lithium batteries[J]. Adv. Sci., 2020,7(5)1903088. doi: 10.1002/advs.201903088
29. [29]
  Luo Z H, Li W Y, Guo C, Song Y, Zhou M X, Shi Y, Xu J, Li L, Shi B, Ouyang Q S, Shao J J, Zhou G M. Two-dimensional silica enhanced solid polymer electrolyte for lithium metal batteries[J]. Particuology, 2024,85:146-154. doi: 10.1016/j.partic.2023.04.002
30. [30]
  Li W Y, Luo Z H, Long X, Long J Y, Pang C, Li H, Zhi X, Shi B, Shao J J, He Y B. Cation vacancy-boosted Lewis acid-base interactions in a polymer electrolyte for high-performance lithium metal batteries[J]. ACS Appl. Mater. Interfaces, 2021,13(43):51107-51116. doi: 10.1021/acsami.1c17002
31. [31]
  Duluard S, Grondin J, Bruneel J L, Pianet I, Grélard A, Campet G, Delville M H, Lassègues J C. Lithium solvation and diffusion in the 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ionic liquid[J]. J. Raman Spectrosc., 2008,39(5):627-632. doi: 10.1002/jrs.1896
32. [32]
  Chen N, Dai Y J, Xing Y, Wang L L, Guo C, Chen R J, Guo S J, Wu F. Biomimetic ant-nest ionogel electrolyte boosts the performance of dendrite-free lithium batteries[J]. Energy Environ. Sci., 2017,10(7):1660-1667. doi: 10.1039/C7EE00988G
1. [1]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
2. [2]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
3. [3]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
4. [4]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
5. [5]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
6. [6]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
7. [7]
  Mengwen Wang , Qintao Sun , Yue Liu , Zhengan Yan , Qiyu Xu , Yuchen Wu , Tao Cheng . Impact of lithium nitrate additives on the solid electrolyte interphase in lithium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(2): 100203-100203. doi: 10.1016/j.cjsc.2023.100203
8. [8]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
9. [9]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
11. [11]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
12. [12]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
13. [13]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
14. [14]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
15. [15]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
16. [16]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
17. [17]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
18. [18]
  Chang Liu , Zirui Song , Xinglan Deng , Shihong Xu , Renji Zheng , Wentao Deng , Hongshuai Hou , Guoqiang Zou , Xiaobo Ji . Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors. Chinese Chemical Letters, 2024, 35(6): 109081-. doi: 10.1016/j.cclet.2023.109081
19. [19]
  Kezhen Qi , Shu-yuan Liu , Ruchun Li . Selective dissolution for stabilizing solid electrolyte interphase. Chinese Chemical Letters, 2024, 35(5): 109460-. doi: 10.1016/j.cclet.2023.109460
20. [20]
  Changhui Yu , Peng Shang , Huihui Hu , Yuening Zhang , Xujin Qin , Linyu Han , Caihe Liu , Xiaohan Liu , Minghua Liu , Yuan Guo , Zhen Zhang . Evolution of template-assisted two-dimensional porphyrin chiral grating structure by directed self-assembly using chiral second harmonic generation microscopy. Chinese Chemical Letters, 2024, 35(10): 109805-. doi: 10.1016/j.cclet.2024.109805

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(64)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142