Citation: Lu XU, Chengyu ZHANG, Wenjuan JI, Haiying YANG, Yunlong FU. Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431 shu

Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol

Lu XU ¹ ,
Chengyu ZHANG ¹ ,
Wenjuan JI ^1,, ,
Haiying YANG ^2,, ,
Yunlong FU ^1,,

1.
Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, College of Chemistry and Materials Science, Shanxi Normal University, Taiyuan 030032, China
2.
Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Wenjuan JI, jiwj@sxnu.edu.cn Haiying YANG, hyyang@ycu.edu.cn Yunlong FU, yunlongfu@sxnu.edu.cn
Received Date: 14 November 2023
Revised Date: 30 January 2024

Figures(12)

Based on the rigid benzene polycarboxylic acid H₄BPTC (biphenyl-3, 3′, 5, 5′-tetracarboxylic acid), a 3D rigid zinc-based metal-organic framework with high-density free carboxyl oxygen modified pore walls, {[Zn₂(BPTC) (H₂O) (DMF)₂]·DMF·H₂O}_n (SXNU-5-Zn), has been constructed. SXNU-5-Zn exhibited good acid-base stability within a pH range of 3-8 and excellent thermal stability. An electrochemical sensor, SXNU-5-Zn/GCE, based on a pure MOF material was constructed, which can detect paracetamol (AC) with high sensitivity and selectivity. The linear detection range spans from 0.02 to 765 μmol·L^-1, with a limit of detection as low as 0.013 8 μmol·L^-1 (S/N= 3). Furthermore, the prepared SXNU-5-Zn/GCE sensor has been successfully utilized to determine the AC content in compound acetaminophen tablets as an actual sample.
- metal-organic framework,
- zinc,
- electrochemical sensor,
- paracetamol
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