Citation: Jing SU, Bingrong LI, Yiyan BAI, Wenjuan JI, Haiying YANG, Zhefeng Fan. Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414 shu

Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores

Jing SU ¹ ,
Bingrong LI ¹ ,
Yiyan BAI ² ,
Wenjuan JI ^1,, ,
Haiying YANG ^2,, ,
Zhefeng Fan ^1,,

1.
Key Laboratory of Magnetic Molecules and Magnetic Information Materials, College of Chemistry and Materials Science, Shanxi Normal University, Taiyuan 030032, China
2.
Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Wenjuan JI, jiwj@sxnu.edu.cn Haiying YANG, hyyang@ycu.edu.cn Zhefeng Fan, zhefengfan@163.com
Received Date: 31 October 2023
Revised Date: 8 April 2024

Figures(8)

To design a highly stable and sensitive metal-organic framework (MOF) electrochemical sensor for detecting dopamine (DA), we selected indium-based MOF [In(2-NH₃-BDC)(2-NH₂-BDC)]·1.5H₂O (RSMOF-1, RSMOF=resistance switchable metal-organic framework, 2-NH₂-H₂BDC=2-amino terephthalic acid) to modify the glassy carbon electrode (RSMOF-1/GCE). The DPV test results of the prepared electrode RSMOF-1/GCE showed a linear range of 0.990-663 μmol·L^-1 and a detection limit of 0.770 μmol·L^-1. In the presence of various interfering substances (uric acid, urea, glucose, acetaminophen), RSMOF-1/GCE still exhibited high selectivity towards DA. The theoretical simulation results demonstrated that the —NH₂ on the inner wall of the RSMOF-1 pore can enhance interaction with DA molecules through hydrogen bonding, indicating its sensitive electrochemical sensing performance for DA.
- amino-functionalized metal-organic framework,
- indium,
- electrochemical sensor,
- dopamine
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