Citation: Wanting SHEN, Shaoxuan SUN, Yuting FENG, Fengqi ZHANG, Tingting LU, Yongsheng YANG. Research progress of coordination-driven assembly of single-component white light emission metal-organic complex materials[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 33-53. doi: 10.11862/CJIC.20230380 shu

Research progress of coordination-driven assembly of single-component white light emission metal-organic complex materials

Wanting SHEN ^{1, 2} ,
Shaoxuan SUN ¹ ,
Yuting FENG ^{1, 2} ,
Fengqi ZHANG ^{1, 2} ,
Tingting LU ^{1, 2,,} ,
Yongsheng YANG ^{1, 2,,}

1.
College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China
2.
Institute of Catalysis for Energy and Environment, Shenyang Normal University, Shenyang 110034, China

Corresponding author: Tingting LU, lutt0711@163.com Yongsheng YANG, yangys1990@163.com
Received Date: 13 October 2023
Revised Date: 18 November 2023

Figures(16)

Metal-organic complex materials are widely used in security and anti-counterfeiting, information storage, intelligent sensing, display devices, white light lighting, and other fields based on their structural diversity and controllable luminescence properties. In this review, the research progress of single-component metal-organic complexes in white light luminescence is introduced in detail. According to the five categories of Au (Ⅰ)/Ag(Ⅰ)/Cu(Ⅰ) complexes, Zn(Ⅱ)/Cd(Ⅱ) complexes, Eu(Ⅲ)&Tb(Ⅲ) co-doped Ln(Ⅲ) complexes, dye-doped complexes, other main group elements/ transition elements/lanthanide elements doped/multi-element doped complexes, the structural characteristics, luminescence mechanism, white light luminescence composition and white light performance index of complexes are analyzed. The construction strategies of white light emission materials of different types of complexes are generalized. The advantages of metal-organic complex materials as white light candidate materials are summarized, and the problems to be further solved are put forward from two aspects of theoretical research and practical application, to realize the industrial production and application of metal-organic complex luminescent materials as soon as possible.
- metal-organic complex,
- single-component,
- structural diversity,
- controllable luminescence,
- white light emission
1. [1]
  Wang M S, Guo G C. Inorganic-organic hybrid white light phosphors[J]. Chem. Commun., 2016,52(90):13194-13204. doi: 10.1039/C6CC03184F
2. [2]
  Bergh A, Craford G, Duggal A, Haitz R. The promise and challenge of solid-state lighting[J]. Phys. Today, 2001,54(12):42-47. doi: 10.1063/1.1445547
3. [3]
  Cui Y J, Yue Y F, Qian G D, Chen B L. Luminescent functional metal-organic Frameworks[J]. Chem. Rev., 2012,112(2):1126-1162. doi: 10.1021/cr200101d
4. [4]
  Cui Y J, Chen B L, Qian G D. Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications[J]. Coord. Chem. Rev., 2014,273:76-86.
5. [5]
  Xu L J, Xu G T, Chen Z N. Recent advances in lanthanide luminescence with metal-organic chromophores as sensitizers[J]. Coord. Chem. Rev., 2014,273:47-62.
6. [6]
  Allendorf M D, Bauer C A, Bhakta R K, Houk R J T. Luminescent metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38(5):1330-1352. doi: 10.1039/b802352m
7. [7]
  Hu Z C, Deibert B J, Li J. Luminescent metal-organic frameworks for chemical sensing and explosive detection[J]. Chem. Soc. Rev., 2014,43(16):5815-5840. doi: 10.1039/C4CS00010B
8. [8]
  Meyer L V, Schönfeld F, Müller-Buschbaum K. Lanthanide based tuning of luminescence in MOFs and dense frameworks—From mono- and multimetal systems to sensors and films[J]. Chem. Commun., 2014,50(60):8093-8108. doi: 10.1039/c4cc00848k
9. [9]
  Roy S, Chakraborty A, Maji T K. Lanthanide-organic frameworks for gas storage and as magneto-luminescent materials[J]. Coord. Chem. Rev., 2014,273:139-164.
10. [10]
  Müller-Buschbaum K, Beuerle F, Feldmann C. MOF based luminescence tuning and chemical/physical sensing[J]. Microporous Mesoporous Mat., 2015,216:171-199. doi: 10.1016/j.micromeso.2015.03.036
11. [11]
  Gather M C, Köhnen A, Meerholz K. White organic light-emitting diodes[J]. Adv. Mater., 2011,23(2):233-248. doi: 10.1002/adma.201002636
12. [12]
  Mukherjee S, Thilagar P. Organic white-light emitting materials[J]. Dyes Pigment., 2014,110:2-27. doi: 10.1016/j.dyepig.2014.05.031
13. [13]
  Shang M M, Li C X, Lin J. How to produce white light in a single-phase host?[J]. Chem. Soc. Rev., 2014,43(5):1372-1386. doi: 10.1039/C3CS60314H
14. [14]
  Kamtekar K T, Monkman A P, Bryce M R. Recent advances in white organic light-emitting materials and devices (WOLEDs)[J]. Adv. Mater., 2010,22(5):572-582. doi: 10.1002/adma.200902148
15. [15]
  Wang Q, Ma D G. Management of charges and excitons for high- performance white organic light-emitting diodes[J]. Chem. Soc. Rev., 2010,39(7):2387-2398. doi: 10.1039/b909057f
16. [16]
  Wu H B, Ying L, Yang W, Cao Y. Progress and perspective of polymer white light-emitting devices and materials[J]. Chem. Soc. Rev., 2009,38(12):3391-3400. doi: 10.1039/b816352a
17. [17]
  Abbel R, Grenier C, Pouderoijen M J, Stouwdam J W, Leclère P E L G, Sijbesma R P, Meijer E W, Schenning A P H J. White-light emitting hydrogen-bonded supramolecular copolymers based on π-conjugated oligomers[J]. J. Am. Chem. Soc., 2009,131(2):833-843. doi: 10.1021/ja807996y
18. [18]
  Almeida D A, Santos B, Paolo B, Quicheron M. Solid state lighting review—Potential and challenges in europe[J]. Renew. Sust. Energ. Rev., 2014,34:30-48. doi: 10.1016/j.rser.2014.02.029
19. [19]
  Narukawa Y, Ichikawa M, Sanga D, Sano M, Mukai T. White light emitting diodes with super-high luminous efficacy[J]. J. Phys. D: Appl. Phys., 2010,43(35)354002. doi: 10.1088/0022-3727/43/35/354002
20. [20]
  Pan M, Liao W M, Yin S Y, Sun S S, Su C Y. Single-phase white-light-emitting and photoluminescent color-tuning coordination assemblies[J]. Chem. Rev., 2018,118(18):8889-8935. doi: 10.1021/acs.chemrev.8b00222
21. [21]
  Schubert E F, Kim J K. Solid-state light sources getting smart[J]. Science, 2005,308(5726):1274-1278. doi: 10.1126/science.1108712
22. [22]
  He G J, Guo D, He C, Zhang X L, Zhao X W, Duan C Y. A color- tunable europium complex emitting three primary colors and white light[J]. Angew. Chem. Int. Ed., 2009,121(33):6248-6251. doi: 10.1002/ange.200901266
23. [23]
  Xue P C, Wang P P, Chen P, Yao B Q, Gong P, Sun J B, Zhang Z Q, Lu R. Bright persistent luminescence from pure organic molecules through a moderate intermolecular heavy atom effect[J]. Chem. Sci., 2017,8(9):6060-6065. doi: 10.1039/C5SC03739E
24. [24]
  Osawa M, Soma S, Kobayashi H, Tanaka Y, Hoshino M. Near-white light emission from single crystals of cationic dinuclear gold(Ⅰ) complexes with bridged diphosphine ligands[J]. Dalton Trans., 2023,52(10):2956-2965. doi: 10.1039/D2DT03785H
25. [25]
  Mihaly J J, Wolf S M, Phillips A T, Mam S, Yung Z, Haley J E, Zeller M, de La Harpe K, Holt E, Grusenmeyer T A, Collins S, Gray T G. Synthetically tunable white-, green-, and yellow-green-light emission in dual-luminescent gold(Ⅰ) complexes bearing a diphenylamino-2, 7-fluorenyl moiety[J]. Inorg. Chem., 2022,61(3):1228-1235. doi: 10.1021/acs.inorgchem.1c02405
26. [26]
  Xue Z Z, Meng X D, Li X Y, Han S D, Pan J, Wang G M. Luminescent thermochromism and white-light emission of a 3D[Ag₄Br₆] cluster-based coordination framework with both adamantane-like node and linker[J]. Inorg. Chem., 2021,60(7):4375-4379. doi: 10.1021/acs.inorgchem.1c00280
27. [27]
  Lin F, Liu W, Wang H, Li J. Strongly emissive white-light-emitting silver iodide based inorganic-organic hybrid structures with comparable quantum efficiency to commercial phosphors[J]. Chem. Commun., 2020,56(10):1481-1484. doi: 10.1039/C9CC09260A
28. [28]
  Shao J J, Chen W M, Mensah A, Liu P L, Ni J L, Chen L Z, Wang F M. Realizing near white and warm light emission of cuprous iodide complexes by alkyl-isomerization of ligands[J]. Dalton Trans., 2023,52(11):3254-3259. doi: 10.1039/D2DT02526D
29. [29]
  Yu M X, Liu C P, Zhao Y F, Li S C, Yu Y L, Lv J Q, Chen L, Jiang F L, Hong M C. White-light emission and circularly polarized luminescence from a chiral copper(Ⅰ) coordination polymer through symmetry-breaking crystallization[J]. Angew. Chem. Int. Ed., 2022,134(22)e202201590. doi: 10.1002/ange.202201590
30. [30]
  Yu C F, Wang X L, Wu T, Gu X W, Huang W, Kirillov A M, Wu D Y. Color tuning of intrinsic white-light emission in anthracene-linker coordination networks[J]. Dalton Trans., 2020,49(34):12082-12087. doi: 10.1039/D0DT02033H
31. [31]
  Li J B, Zheng H W, Wu M, Liang Q F, Yang D D, Zheng X J, Tan H W. Multistimulus response of two tautomeric Zn(Ⅱ) complexes and their white-light emission based on different mechanisms[J]. Inorg. Chem., 2021,60(23):17677-17686. doi: 10.1021/acs.inorgchem.1c02286
32. [32]
  Zavaleta A, Lykhin A O, Monteiro J H S K, Uchida S, Bell T W, de Bettencourt-Dias A, Varganov S A, Gallucci J. Full visible spectrum and white light emission with a single, input-tunable organic fluorophore[J]. J. Am. Chem. Soc., 2020,142(48):20306-20312. doi: 10.1021/jacs.0c08182
33. [33]
  Li Q, Wei W J, Xue Z Z, Mu Y, Pan J, Hu J X, Wang G M. Achieving an electron transfer photochromic complex for switchable white-light emission[J]. Chin. Chem. Lett., 2022,33(6):3203-3206. doi: 10.1016/j.cclet.2021.10.015
34. [34]
  Wang X D, Song Y T, Pei W Y, Ma J F. Single-component white light emission from a metal-coordinated cyclotriveratrylene-based coordination polymer[J]. Inorg. Chem., 2022,61(28):10768-10773. doi: 10.1021/acs.inorgchem.2c00974
35. [35]
  Wang C, Yin Z, Cheng Z, Ma W M, Li X Y, Hu X T, Shi R, Chen A W, Ma Y M. A series of anionic MOFs with cluster-based, pillared-layer and rod-spacer motifs: Near-sunlight white-light emission and selective dye capture[J]. CrystEngComm, 2020,22(5):878-887. doi: 10.1039/C9CE01691K
36. [36]
  Liu H, Zhang K, Gao P F, Luo J H, Jiang Y Y, Zhou M S, Li T, Zhu X L, Fu H R. Realization of single-phase white-light-emitting materials with time-evolution ultralong room-temperature phosphorescence by coordination assemblies[J]. Inorg. Chem., 2022,61(3):1636-1643. doi: 10.1021/acs.inorgchem.1c03461
37. [37]
  Wang Z, Mo J T, Pan J J, Pan M. White light and color-tuning long persistent luminescence from metal halide based metal-organic frameworks[J]. Adv. Funct. Mater., 2023,33(21)2300021. doi: 10.1002/adfm.202300021
38. [38]
  Wang Z, Liu J J, Li M Y, Chen G. White light and long persistent luminescence from metal cluster-based metal-organic frameworks[J]. Chem. Eng. J., 2023,462142154. doi: 10.1016/j.cej.2023.142154
39. [39]
  Yu X L, Ryadun A A, Kovalenko K A, Guselnikova T Y, Ponomareva V G, Potapov A S, Fedin V P. 4 in 1: Multifunctional europium- organic frameworks with luminescence sensing properties, white light emission, proton conductivity and reverse acetylene-carbon dioxide adsorption selectivity[J]. Dalton Trans., 2023,52(25):8695-8703. doi: 10.1039/D3DT01323E
40. [40]
  Manna K, Sutter J P, Natarajan S. Blue-emitting ligand-mediated assembly of rare-earth MOFs toward white-light emission, sensing, magnetic, and catalytic studies[J]. Inorg. Chem., 2022,61(42):16770-16785. doi: 10.1021/acs.inorgchem.2c02611
41. [41]
  Wei M M, Luo L L, Cui R F, Wang X, Chen J Y, Gai Z L, Li X, Wei H B, Wei C, Bian Z Q. Highly luminescent and stable lanthanide coordination polymers based 2-(3', 4'-dicarboxyphenoxy)-benzoic acid: Crystal structure, photoluminescence, white light emission and fluorescence sensing[J]. Dyes Pigment., 2022,206110650. doi: 10.1016/j.dyepig.2022.110650
42. [42]
  Gálico D A, Kitos A A, Ovens J S, Sigoli F A, Murugesu M. Lanthanide-based molecular cluster-aggregates: Optical barcoding and white-light emission with nanosized {Ln₂₀} compounds[J]. Angew. Chem. Int. Ed., 2021,133(11):6195-6201. doi: 10.1002/ange.202013867
43. [43]
  Wang M, Gao H W, Li J X, Bai F Y, Xing Y H, Shi Z. Multifunctional luminescence sensing and white light adjustment of lanthanide metal-organic frameworks constructed from the flexible cyclotriphosphazene-derived hexacarboxylic acid ligand[J]. Dalton Trans., 2021,50(41):14618-14628. doi: 10.1039/D1DT02560K
44. [44]
  Chen H J, Chen L Q, Lin L R, Long L S, Zheng L S. Doped luminescent lanthanide coordination polymers exhibiting both white-light emission and thermal sensitivity[J]. Inorg. Chem., 2021,60(10):6986-6990. doi: 10.1021/acs.inorgchem.1c00740
45. [45]
  Li Q P, Qian J J, Zhou J, Du L, Zhao Q H. Highly chemically and thermally stable lanthanide coordination polymers for luminescent probes and white light emitting diodes[J]. CrystEngComm, 2020,22(15):2667-2674. doi: 10.1039/D0CE00228C
46. [46]
  Wang Y T, Zhang K, Wang X K, Xin X L, Zhang X R, Fan W D, Xu B, Dai F N, Sun D F. Accurate tuning of rare earth metal-organic frameworks with unprecedented topology for white-light emission[J]. J. Mater. Chem. C, 2020,8(4):1374-1379. doi: 10.1039/C9TC05471E
47. [47]
  Zhang Z, Chen Y X, Chang H, Wang Y Y, Li X P, Zhu X J. Aggregation-induced white emission of lanthanide metallopolymer and its coating on cellulose nanopaper for white-light softening[J]. J. Mater. Chem. C, 2020,8(6):2205-2210. doi: 10.1039/C9TC05894J
48. [48]
  Yang Y, Li W L, Sun C Y, Shan G G, Qin C, Shao K Z, Wang J G, Su Z M. Encapsulation of AIEgens within metal-organic framework toward high-performance white light-emitting diodes[J]. Adv. Opt. Mater., 2022,10(16)2200174. doi: 10.1002/adom.202200174
49. [49]
  Liu H F, Guo C X, Zhang Z Y, Mu C Q, Feng Q, Zhang M M. Hexaphenyltriphenylene-based multicomponent metallacages: Host-guest complexation for white-light emission[J]. Chem.-Eur. J., 2023,29(21)e202203926. doi: 10.1002/chem.202203926
50. [50]
  Gu S F, Xiong X H, Gong L L, Zhang H P, Xu Y, Feng X F, Luo F. Classified encapsulation of an organic dye and metal-organic complex in different molecular compartments for white-light emission and selective adsorption of C₂H₂ over CO₂[J]. Inorg. Chem., 2021,60(11):8211-8217. doi: 10.1021/acs.inorgchem.1c00863
51. [51]
  Wang X B, Li Z Y, Ying W, Chen D K, Li P P, Deng Z, Peng X S. Blue metal-organic framework encapsulated denatured R-phycoerythrin proteins for a white-light-emitting thin film[J]. J. Mater. Chem. C, 2020,8(1):240-246. doi: 10.1039/C9TC05342E
52. [52]
  Fu H M, Jiang C L, Luo C H, Lin H C, Peng H. Manganese halide hybrids with a reversible luminous color and their application for a white light-emitting diode[J]. CrystEngComm, 2022,24(39):6910-6916. doi: 10.1039/D2CE00883A
53. [53]
  Wang Q, Liu Q, Du X M, Zhao B, Li Y, Ruan W J. A white-light-emitting single MOF sensor-based array for berberine homologue discrimination[J]. J. Mater. Chem. C, 2020,8(4):1433-1439. doi: 10.1039/C9TC05180E
54. [54]
  Peedikakkal A M P, Jalilov A S, Shaikh A R, Kalanthoden A N, Al-Saadi A A. Blue- and white-light-emitting 2D-coordination polymers and their solid-state photodimerization reaction[J]. CrystEngComm, 2021,23(43):7663-7670. doi: 10.1039/D1CE00991E
55. [55]
  Song X L, Peng C D, Xu X X, Yin J L, Fei H H. Efficient, broadband self-trapped white-light emission from haloplumbate-based metal- organic frameworks[J]. Chem. Commun., 2020,56(69):10078-10081. doi: 10.1039/D0CC04473C
56. [56]
  Song G M, Li Z Y, Gong P F, Xie R J, Lin Z S. Tunable white light emission in a zero-dimensional organic-inorganic metal halide hybrid with ultra-high color rendering index[J]. Adv. Opt. Mater., 2021,9(11)2002246. doi: 10.1002/adom.202002246
57. [57]
  Feng X, Shang Y P, Zhang K, Hong M Z, Li J F, Xu H D, Wang L Y, Li Z J. In situ ligand-induced Ln-MOFs based on a chromophore moiety: White light emission and turn-on detection of trace antibiotics[J]. CrystEngComm, 2022,24(23):4187-4200. doi: 10.1039/D2CE00613H
58. [58]
  Chen J, Xie Z Y, Meng L Y, Hu Z Y, Kuang X F, Xie Y M, Lu C Z. Luminescence tunable europium and samarium complexes: Reversible on/off switching and white-light emission[J]. Inorg. Chem., 2020,59(10):6963-6977. doi: 10.1021/acs.inorgchem.0c00392
59. [59]
  Mund S, Vaidyanathan S. New isomeric ancillary ligands and their Eu^Ⅲ complexes: A single component white light emissive phosphor and their applications in red/white smart LEDs, electronic noses, and temperature sensing[J]. J. Mater. Chem. C, 2022,10(18):7201-7215. doi: 10.1039/D2TC00664B
60. [60]
  Devi R, Singh K, Vaidyanathan S. Synergy in the energy transfer between ligands and Eu^Ⅲ ions in molecular europium complexes: Single-component white light-emitting luminogens[J]. J. Mater. Chem. C, 2020,8(25):8643-8653. doi: 10.1039/D0TC01360A
61. [61]
  O'Neil A T, Chalard A, Malmström J, Kitchen J A. White light and colour-tunable emission from a single component europium-1, 8-naphthalimide thin film[J]. Dalton Trans., 2023,52(8):2255-2261. doi: 10.1039/D2DT03644D
62. [62]
  Mara D, Pilia L, Van de Steen M, Miletto I, Zeng M, Hecke K V, Serpe A, Deplano P, Deun R V, Artizzu F. Single-component panchromatic white light generation, and tuneable excimer-like visible orange and NIR emission in a Dy quinolinolate complex[J]. J. Mater. Chem. C, 2021,9(43):15641-15648. doi: 10.1039/D1TC04191F
63. [63]
  Zhong L, Chen W B, Ouyang Z J, Yang M, Zhang Y Q, Gao S, Schulze M, Wensdorfer W, Dong W. Unprecedented one-dimensional chain and two-dimensional network dysprosium(Ⅲ) single-molecule toroics with white-light emission[J]. Chem. Commun., 2020,56(17):2590-2593. doi: 10.1039/C9CC08852K
64. [64]
  Cai Z L, Yan W C, Guo R Y, Liu H Y, Huo P H, Yu G, Bian Z Q, Liu Z W. Warm-white-light perdeuterated Dy(Ⅲ) complex with a photoluminescence quantum yield of up to 72% in deuterated chloroform[J]. Inorg. Chem., 2023,62(17):6560-6564. doi: 10.1021/acs.inorgchem.3c00721
65. [65]
  Psalti A E, Andriotou D, Diamantis S A, Chatz-Giachia A, Pournara A, Manos M J, Hatzidimitriou A, Lazarides T. Mixed-metal and mixed-ligand lanthanide metal-organic frameworks based on 2, 6-naphthalenedicarboxylate: Thermally activated sensitization and white-light emission[J]. Inorg. Chem., 2022,61(30):11959-11972. doi: 10.1021/acs.inorgchem.2c01703
66. [66]
  Eliseeva S V, Salerno E V, Lopez Bermudez B A, Petpud S, Pecoraro V L. Dy³⁺ white light emission can be finely controlled by tuning the first coordination sphere of Ga³⁺/Dy³⁺ metallacrown complexes[J]. J. Am. Chem. Soc., 2020,142(38):16173-16176. doi: 10.1021/jacs.0c07198
67. [67]
  Qian J F, Lu H J, Zheng Z F, Xu M M, Qian Y, Zhang Z H, Wang J Q, He M Y, Lin J. Achieving colour tuneable and white-light luminescence in a large family of dual-emission lanthanide coordination polymers[J]. Dalton Trans., 2021,50(40):14325-14331. doi: 10.1039/D1DT01618K
68. [68]
  Zhang G Y, Yin J L, Song X L, Fei H H. A moisture-stable organosulfonate-based metal-organic framework with intrinsic self-trapped white-light emission[J]. Chem. Commun., 2020,56(9):1325-1328. doi: 10.1039/C9CC09486E
69. [69]
  Huang M Y, Liang Z X, Huang J L, Zhang S Y, Wen Y H, Wu X T. Dimensional expansion of 1D zigzag chains to a 2D two-fold interpenetrated metal-organic framework for adsorption of lanthanide cations and white light emission[J]. CrystEngComm, 2023,25(11):1637-1642. doi: 10.1039/D3CE00001J
70. [70]
  Zhang Z, Li Y J, Geng L J, Feng G L, Ren J J, Yu X D. Healable, phase-selective, and white-light-emitting titania based hybrid lanthanide-doped metallogels[J]. Inorg. Chem., 2020,59(6):3974-3982. doi: 10.1021/acs.inorgchem.9b03662
71. [71]
  Qiu Y Q, Feng Y Q, Zhao Q, Wang H W, Guo Y C, Qiu D F. White light emission from a green cyclometalated platinum(Ⅱ) terpyridylphenylacetylide upon titration with Zn(Ⅱ) and Eu(Ⅲ)[J]. Dalton Trans., 2020,49(32):11163-11169. doi: 10.1039/D0DT02336A
72. [72]
  Charytanowicz T, Sieklucka B, Chorazy S. Lanthanide hexacyanidoruthenate frameworks for multicolor to white-light emission realized by the combination of d-d, d-f, and f-f electronic transitions[J]. Inorg. Chem., 2023,62(4):1611-1627. doi: 10.1021/acs.inorgchem.2c03885
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沈阳化工大学材料科学与工程学院沈阳 110142