Citation: Xin LU, Jianlei QIAN, Fayuan GE, Haotian LI, Hegen ZHENG, Chuanlei ZHANG. Modulating metal-organic framework structure by metal ion stimulation for photocatalytic CO₂ reduction reaction[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 209-220. doi: 10.11862/CJIC.20230377 shu

Modulating metal-organic framework structure by metal ion stimulation for photocatalytic CO₂ reduction reaction

Xin LU ^{1, #} ,
Jianlei QIAN ^{1, #} ,
Fayuan GE ² ,
Haotian LI ¹ ,
Hegen ZHENG ^2,, ,
Chuanlei ZHANG ^1,,

1.
Anhui Key Laboratory of Photoelectric-Magnetic Functional Materials, School of Chemistry and Engineering, Anqing Normal University, Anqing, Anhui 246133, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Hegen ZHENG, zhenghg@nju.edu.cn Chuanlei ZHANG, clzhang@nju.edu.cn
Received Date: 11 October 2023
Revised Date: 1 December 2023

Figures(8)

A 2D Cd-based metal-organic framework with moderate coordination bond strength and adequate framework flexibility was obtained by self-assembly, namely {[Cd(HL)(BPY)_0.5(H₂O)]·2H₂O}_n (1), where H₃L=4,4′,4″-(nitrilotris(methylene))tribenzoic acid, BPY=4,4′-bipyridine. Due to the unique structural features, under the stimulation of metal ions (Zn²⁺/Ni²⁺/Co²⁺), 1 gradually transforms into the MOF structures dominated by the corresponding metal ions (2, 3, and 4). During this process, with the exchanges of Cd²⁺→Zn²⁺, Cd²⁺→Ni²⁺, and Cd²⁺→Co²⁺, the free Cd²⁺ and L^3- in the channel of 1 fuse with the backbone, leading to the channel space expansion and secondary building unit (SBU) transformation to form a tunable backbone. The photocatalytic CO₂ reduction results show that the new structures obtained by ion exchange do not have a great improvement in catalytic efficiency, but have a great increase in product selectivity (3 demonstrated 100% CO selectivity).
- metal-organic framework,
- ionic stimulation,
- structural transformation,
- photocatalysis,
- carbon dioxide reduction
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Modulating metal-organic framework structure by metal ion stimulation for photocatalytic CO2 reduction reaction

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通讯作者: 陈斌, bchen63@163.com

Modulating metal-organic framework structure by metal ion stimulation for photocatalytic CO₂ reduction reaction